peroxyacetyl nitrate
- Formula: C2H3NO5
- Molecular weight: 121.0489
- IUPAC Standard InChI: InChI=1S/C2H3NO5/c1-2(4)7-8-3(5)6/h1H3
- IUPAC Standard InChIKey: VGQXTTSVLMQFHM-UHFFFAOYSA-N
- CAS Registry Number: 2278-22-0
- Chemical structure:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 8.27 | 292. | A | Stephenson and Malanowski, 1987 | Based on data from 277. to 330. K. |
Henry's Law data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
| k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 4.1 | M | N/A | Value at T = 293. K. | |
| 2.8 | 6500. | M | N/A | |
| 2.9 | 5900. | C | N/A | |
| 3.6 | X | N/A | Value given here as quoted by missing citation. | |
| 5.0 | M | N/A | Value at T = 283. K. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner)
Gas basicity at 298K
| Gas basicity (review) (kcal/mol) | Reference | Comment |
|---|---|---|
| 214. ± 1. | Shen and Brodbelt, 1998 | Triglyme; Tetraglyme. From PT bracketing at nominal 300 K, but ion energies are undefined. Reference GBs readjusted to Hunter and Lias, 1998 |
References
Go To: Top, Phase change data, Henry's Law data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Shen and Brodbelt, 1998
Shen, J.; Brodbelt, J.,
Evaluation of proton-binding capabilities of polyether and pyridyl ligands,
J. Mass Spectrom., 1998, 33, 118. [all data]
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Notes
Go To: Top, Phase change data, Henry's Law data, Gas phase ion energetics data, References
- Symbols used in this document:
d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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