Mercury cation
- Formula: Hg+
- Molecular weight: 200.59
- CAS Registry Number: 22542-11-6
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Gas phase thermochemistry data
Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 224.62 | J/mol*K | Review | Chase, 1998 | Data last reviewed in September, 1984 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (Hg+ • 20Hg) + Hg = (Hg+ • 21Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.7 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 21Hg) + Hg = (Hg+ • 22Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.4 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 22Hg) + Hg = (Hg+ • 23Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 46.4 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 23Hg) + Hg = (Hg+ • 24Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 47.3 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 10Hg) + Hg = (Hg+ • 11Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 11Hg) + Hg = (Hg+ • 12Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 26. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 12Hg) + Hg = (Hg+ • 13Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 27. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 13Hg) + Hg = (Hg+ • 14Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 28. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 14Hg) + Hg = (Hg+ • 15Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 15Hg) + Hg = (Hg+ • 16Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 16Hg) + Hg = (Hg+ • 17Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 33. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 17Hg) + Hg = (Hg+ • 18Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 18Hg) + Hg = (Hg+ • 19Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 37. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 19Hg) + Hg = (Hg+ • 20Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 9Hg) + Hg = (Hg+ • 10Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 5Hg) + Hg = (Hg+ • 6Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 6Hg) + Hg = (Hg+ • 7Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 7Hg) + Hg = (Hg+ • 8Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 8Hg) + Hg = (Hg+ • 9Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 4Hg) + Hg = (Hg+ • 5Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase |
By formula: Hg+ + Hg = (Hg+ • Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 130. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: Hg+ + Ar = (Hg+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22. ± 2. | kJ/mol | PI | Linn, Brom, et al., 1985 | gas phase |
Ion clustering data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Hg+ + Ar = (Hg+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22. ± 2. | kJ/mol | PI | Linn, Brom, et al., 1985 | gas phase |
By formula: Hg+ + Hg = (Hg+ • Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 130. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 4Hg) + Hg = (Hg+ • 5Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase |
By formula: (Hg+ • 5Hg) + Hg = (Hg+ • 6Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 6Hg) + Hg = (Hg+ • 7Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 7Hg) + Hg = (Hg+ • 8Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 8Hg) + Hg = (Hg+ • 9Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 9Hg) + Hg = (Hg+ • 10Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 10Hg) + Hg = (Hg+ • 11Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 22. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 11Hg) + Hg = (Hg+ • 12Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 26. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 12Hg) + Hg = (Hg+ • 13Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 27. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 13Hg) + Hg = (Hg+ • 14Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 28. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 14Hg) + Hg = (Hg+ • 15Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 15Hg) + Hg = (Hg+ • 16Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 16Hg) + Hg = (Hg+ • 17Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 33. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 17Hg) + Hg = (Hg+ • 18Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 18Hg) + Hg = (Hg+ • 19Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 37. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 19Hg) + Hg = (Hg+ • 20Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41. | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 20Hg) + Hg = (Hg+ • 21Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.7 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 21Hg) + Hg = (Hg+ • 22Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.4 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 22Hg) + Hg = (Hg+ • 23Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 46.4 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
By formula: (Hg+ • 23Hg) + Hg = (Hg+ • 24Hg)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 47.3 | kJ/mol | EI | Haberland, Kornmeier, et al., 1990 | gas phase; from graph |
References
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Haberland, Kornmeier, et al., 1990
Haberland, H.; Kornmeier, H.; Langosh, H.; Oschwald, M.; Tanner, G.,
Experimental Study of the Transition from van der Waals, over Covalent to Metallic Bonding in Mercury Clusters,
J. Chem. Soc. Faraday Trans., 1990, 86, 13, 2473, https://doi.org/10.1039/ft9908602473
. [all data]
Linn, Brom, et al., 1985
Linn, S.H.; Brom, J.M., Jr.; Tzeng, W.-B.; Ng, C.Y.,
Photoionization study of HgAr,
J. Chem. Phys., 1985, 82, 648. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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