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Rubidium ion (1+)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Rubidium ion (1+) + Water = (Rubidium ion (1+) bullet Water)

By formula: Rb+ + H2O = (Rb+ bullet H2O)

Quantity Value Units Method Reference Comment
DeltarH°66.5kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
DeltarH°70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
DeltarH°66.9kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
DeltarS°88.7J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
DeltarS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
DeltarS°84.1J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
39.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Rubidium ion (1+) bullet 2Water) + Water = (Rubidium ion (1+) bullet 3Water)

By formula: (Rb+ bullet 2H2O) + H2O = (Rb+ bullet 3H2O)

Quantity Value Units Method Reference Comment
DeltarH°51.0kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
DeltarH°50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
DeltarS°100.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
DeltarS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Rubidium ion (1+) bullet Water) + Water = (Rubidium ion (1+) bullet 2Water)

By formula: (Rb+ bullet H2O) + H2O = (Rb+ bullet 2H2O)

Quantity Value Units Method Reference Comment
DeltarH°56.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
DeltarH°60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
DeltarS°92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
DeltarS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Rubidium ion (1+) bullet 4Acetonitrile) + Acetonitrile = (Rubidium ion (1+) bullet 5Acetonitrile)

By formula: (Rb+ bullet 4C2H3N) + C2H3N = (Rb+ bullet 5C2H3N)

Quantity Value Units Method Reference Comment
DeltarH°46.4kJ/molHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
DeltarS°136.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M

Rubidium ion (1+) + Krypton = (Rubidium ion (1+) bullet Krypton)

By formula: Rb+ + Kr = (Rb+ bullet Kr)

Quantity Value Units Method Reference Comment
DeltarH°11.0kJ/molIMobGatland, 1984gas phase; M
DeltarH°11.2kJ/molIMobViehland, 1984gas phase; M
DeltarH°14.0kJ/molIMobTakebe, 1983gas phase; M

Rubidium ion (1+) + Argon = (Rubidium ion (1+) bullet Argon)

By formula: Rb+ + Ar = (Rb+ bullet Ar)

Quantity Value Units Method Reference Comment
DeltarH°8.49kJ/molIMobGatland, 1984gas phase; M
DeltarH°8.28kJ/molIMobViehland, 1984gas phase; M
DeltarH°11.9kJ/molIMobTakebe, 1983gas phase; M

Rubidium ion (1+) + Xenon = (Rubidium ion (1+) bullet Xenon)

By formula: Rb+ + Xe = (Rb+ bullet Xe)

Quantity Value Units Method Reference Comment
DeltarH°11.9kJ/molIMobGatland, 1984gas phase; M
DeltarH°17.8kJ/molIMobViehland, 1984gas phase; M
DeltarH°15.1kJ/molIMobTakebe, 1983gas phase; M

(Rubidium ion (1+) bullet 3Water) + Water = (Rubidium ion (1+) bullet 4Water)

By formula: (Rb+ bullet 3H2O) + H2O = (Rb+ bullet 4H2O)

Quantity Value Units Method Reference Comment
DeltarH°46.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Rubidium ion (1+) bullet 4Water) + Water = (Rubidium ion (1+) bullet 5Water)

By formula: (Rb+ bullet 4H2O) + H2O = (Rb+ bullet 5H2O)

Quantity Value Units Method Reference Comment
DeltarH°43.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°108.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Rubidium ion (1+) bullet 2Acetonitrile) + Acetonitrile = (Rubidium ion (1+) bullet 3Acetonitrile)

By formula: (Rb+ bullet 2C2H3N) + C2H3N = (Rb+ bullet 3C2H3N)

Quantity Value Units Method Reference Comment
DeltarH°65.7kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°104.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Rubidium ion (1+) bullet 3Acetonitrile) + Acetonitrile = (Rubidium ion (1+) bullet 4Acetonitrile)

By formula: (Rb+ bullet 3C2H3N) + C2H3N = (Rb+ bullet 4C2H3N)

Quantity Value Units Method Reference Comment
DeltarH°52.3kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°108.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Rubidium ion (1+) bullet Acetonitrile) + Acetonitrile = (Rubidium ion (1+) bullet 2Acetonitrile)

By formula: (Rb+ bullet C2H3N) + C2H3N = (Rb+ bullet 2C2H3N)

Quantity Value Units Method Reference Comment
DeltarH°74.1kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°87.4J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Rubidium ion (1+) bullet 2Ammonia) + Ammonia = (Rubidium ion (1+) bullet 3Ammonia)

By formula: (Rb+ bullet 2H3N) + H3N = (Rb+ bullet 3H3N)

Quantity Value Units Method Reference Comment
DeltarH°54.8kJ/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°105.J/mol*KHPMSCastleman, 1978gas phase; M

(Rubidium ion (1+) bullet 3Ammonia) + Ammonia = (Rubidium ion (1+) bullet 4Ammonia)

By formula: (Rb+ bullet 3H3N) + H3N = (Rb+ bullet 4H3N)

Quantity Value Units Method Reference Comment
DeltarH°47.7kJ/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°159.J/mol*KHPMSCastleman, 1978gas phase; M

(Rubidium ion (1+) bullet Ammonia) + Ammonia = (Rubidium ion (1+) bullet 2Ammonia)

By formula: (Rb+ bullet H3N) + H3N = (Rb+ bullet 2H3N)

Quantity Value Units Method Reference Comment
DeltarH°63.6kJ/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°98.7J/mol*KHPMSCastleman, 1978gas phase; M

Rubidium ion (1+) + Acetonitrile = (Rubidium ion (1+) bullet Acetonitrile)

By formula: Rb+ + C2H3N = (Rb+ bullet C2H3N)

Quantity Value Units Method Reference Comment
DeltarH°86.6kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°75.7J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

Rubidium ion (1+) + Ammonia = (Rubidium ion (1+) bullet Ammonia)

By formula: Rb+ + H3N = (Rb+ bullet H3N)

Quantity Value Units Method Reference Comment
DeltarH°78.2kJ/molHPMSCastleman, 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°102.J/mol*KHPMSCastleman, 1978gas phase; M

Rubidium ion (1+) + neon = (Rubidium ion (1+) bullet neon)

By formula: Rb+ + Ne = (Rb+ bullet Ne)

Quantity Value Units Method Reference Comment
DeltarH°3.2kJ/molIMobViehland, 1984gas phase; M
DeltarH°3.3kJ/molIMobTakebe, 1983gas phase; M

(Rubidium ion (1+) bullet 4Ammonia) + Ammonia = (Rubidium ion (1+) bullet 5Ammonia)

By formula: (Rb+ bullet 4H3N) + H3N = (Rb+ bullet 5H3N)

Quantity Value Units Method Reference Comment
DeltarH°42.7kJ/molHPMSCastleman, 1978gas phase; M

(Rubidium ion (1+) bullet Toluene) + Toluene = (Rubidium ion (1+) bullet 2Toluene)

By formula: (Rb+ bullet C7H8) + C7H8 = (Rb+ bullet 2C7H8)

Quantity Value Units Method Reference Comment
DeltarH°67.8 ± 4.2kJ/molCIDTAmunugama and Rodgers, 2002RCD

(Rubidium ion (1+) bullet Phenol) + Phenol = (Rubidium ion (1+) bullet 2Phenol)

By formula: (Rb+ bullet C6H6O) + C6H6O = (Rb+ bullet 2C6H6O)

Quantity Value Units Method Reference Comment
DeltarH°64. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Rubidium ion (1+) bullet Benzene, fluoro-) + Benzene, fluoro- = (Rubidium ion (1+) bullet 2Benzene, fluoro-)

By formula: (Rb+ bullet C6H5F) + C6H5F = (Rb+ bullet 2C6H5F)

Quantity Value Units Method Reference Comment
DeltarH°47.3 ± 5.0kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Rubidium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) bullet 3Dimethyl ether)

By formula: (Rb+ bullet 2C2H6O) + C2H6O = (Rb+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°37. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet Anisole) + Anisole = (Rubidium ion (1+) bullet 2Anisole)

By formula: (Rb+ bullet C7H8O) + C7H8O = (Rb+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
DeltarH°64. ± 3.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Rb+ bullet C4H10O2) + C4H10O2 = (Rb+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
DeltarH°49. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) bullet 2Dimethyl ether)

By formula: (Rb+ bullet C2H6O) + C2H6O = (Rb+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°54.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet Benzene) + Benzene = (Rubidium ion (1+) bullet 2Benzene)

By formula: (Rb+ bullet C6H6) + C6H6 = (Rb+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
DeltarH°62.8 ± 7.9kJ/molCIDTAmicangelo and Armentrout, 2000RCD

Rubidium ion (1+) + 1,4,7,10,13,16-Hexaoxacyclooctadecane = (Rubidium ion (1+) bullet 1,4,7,10,13,16-Hexaoxacyclooctadecane)

By formula: Rb+ + C12H24O6 = (Rb+ bullet C12H24O6)

Quantity Value Units Method Reference Comment
DeltarH°191. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + 15-Crown-5 = (Rubidium ion (1+) bullet 15-Crown-5)

By formula: Rb+ + C10H20O5 = (Rb+ bullet C10H20O5)

Quantity Value Units Method Reference Comment
DeltarH°114. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + Toluene = (Rubidium ion (1+) bullet Toluene)

By formula: Rb+ + C7H8 = (Rb+ bullet C7H8)

Quantity Value Units Method Reference Comment
DeltarH°71.1 ± 4.2kJ/molCIDTAmunugama and Rodgers, 2002RCD

Rubidium ion (1+) + Phenol = (Rubidium ion (1+) bullet Phenol)

By formula: Rb+ + C6H6O = (Rb+ bullet C6H6O)

Quantity Value Units Method Reference Comment
DeltarH°69. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

Rubidium ion (1+) + Benzene, fluoro- = (Rubidium ion (1+) bullet Benzene, fluoro-)

By formula: Rb+ + C6H5F = (Rb+ bullet C6H5F)

Quantity Value Units Method Reference Comment
DeltarH°53.6 ± 5.4kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

Rubidium ion (1+) + Anisole = (Rubidium ion (1+) bullet Anisole)

By formula: Rb+ + C7H8O = (Rb+ bullet C7H8O)

Quantity Value Units Method Reference Comment
DeltarH°72.4 ± 4.2kJ/molCIDTAmunugama and Rodgers, 2003RCD

Rubidium ion (1+) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Rb+ + C4H10O2 = (Rb+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
DeltarH°94.1 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + Dimethyl ether = (Rubidium ion (1+) bullet Dimethyl ether)

By formula: Rb+ + C2H6O = (Rb+ bullet C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°61.9 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + 12-Crown-4 = (Rubidium ion (1+) bullet 12-Crown-4)

By formula: Rb+ + C8H16O4 = (Rb+ bullet C8H16O4)

Quantity Value Units Method Reference Comment
DeltarH°93. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + Benzene = (Rubidium ion (1+) bullet Benzene)

By formula: Rb+ + C6H6 = (Rb+ bullet C6H6)

Quantity Value Units Method Reference Comment
DeltarH°69. ± 4.kJ/molCIDTAmicangelo and Armentrout, 2000RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P., Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry, J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360 . [all data]

Burdett and Hayhurst, 1982
Burdett, N.A.; Hayhurst, A.N., Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer., J. Chem. Soc. Faraday Trans. 1, 1982, 78, 2997. [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Ionic Solvation by Aprotic Solvents. Gas Phase Solvation of the Alkali Ions by Acetonitrile, J. Am. Chem. Soc., 1976, 98, 20, 6125, https://doi.org/10.1021/ja00436a010 . [all data]

Gatland, 1984
Gatland, I.R., Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Viehland, 1984
Viehland, L.A., Interaction Potentials for Li+ - Rare - Gas Systems, Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3 . [all data]

Takebe, 1983
Takebe, M., The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves, J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763 . [all data]

Castleman, 1978
Castleman, A.W., The Properties of Clusters in the Gas Phase: Ammonia about Bi+, Rb+, and K+, Chem. Phys. Lett., 1978, 53, 3, 560, https://doi.org/10.1016/0009-2614(78)80069-4 . [all data]

Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b . [all data]

Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T., The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584 . [all data]

Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Notes

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