1,3,5-Hexatriene

• Formula: C₆H₈
• Molecular weight: 80.1277
• IUPAC Standard InChI: InChI=1S/C6H8/c1-3-5-6-4-2/h3-6H,1-2H2 Copy

  
• IUPAC Standard InChIKey: AFVDZBIIBXWASR-UHFFFAOYSA-N Copy
• CAS Registry Number: 2235-12-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Stereoisomers:
  • 1,3,5-Hexatriene, (Z)-
  • 1,3,5-Hexatriene, (E)-
• Other names: Hexa-1,3,5-triene; Hexatriene; Divinylethylene; hexa-1,3,5-triene, mixed isomers
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Normal boiling point
  • References
  • Notes
• Other data available:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Normal boiling point

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Safarov, Bikkulov, et al., 1982
Safarov, M.G.; Bikkulov, R.M.; Safarova, V.G.; Rafikov, S.R., Izv. Akad. Nauk SSSR Ser. Khim., 1982, 31, 896-9. [all data]

Rakhmankulov, Kantor, et al., 1980
Rakhmankulov, I.L.; Kantor, E.A.; Rakhmankulov, D.L., Zh. Prikl. Khim. (Leningrad), 1980, 53, 1367-72. [all data]

Safarov, Bikkulov, et al., 1978
Safarov, M.G.; Bikkulov, R.M.; Nefedov, O.M.; Dolgii, I.E., New Synthesis of 1,3,5-Hexatriene Based On Piperylene and Formaldehyde, Izv. Akad. Nauk SSSR Ser. Khim., 1978, 27, 728-30. [all data]

Moriconi and Hummel, 1976
Moriconi, E.J.; Hummel, C.F., Reaction of Chlorosolfonyl Isocyanate with Triene Systems, J. Org. Chem., 1976, 41, 3583-6. [all data]

Lippincott and Kenney, 1962
Lippincott, E.R.; Kenney, T.E., J. Am. Chem. Soc., 1962, 84, 3641. [all data]

Sondheimer, Ben-Efraim, et al., 1961
Sondheimer, F.; Ben-Efraim, D.A.; Wolovsky, R., Unsaturated Macrocyclic Compounds XVII. The Prototropic Rearrangement of Linear 1,5-Enynes to COnjugated Polyenes. The Synthesis of A Series of Vinylogs of Butadiene, J. Am. Chem. Soc., 1961, 83, 1675-81. [all data]

Srinivasan, 1961
Srinivasan, R., The Photochemistry of cis,trans-1,3,5-Hexatriene, J. Am. Chem. Soc., 1961, 83, 2806-8. [all data]

Hwa, De Benneville, et al., 1960
Hwa, J.C.H.; De Benneville, P.L.; Sims, H.J., A New Preparation of 1,3,5-Hexatriene and the Separation of Its Geometrical Isomers, J. Am. Chem. Soc., 1960, 82, 2537-40. [all data]

Woods, Bolgiano, et al., 1955
Woods, G.F.; Bolgiano, N.C.; Duggan, D.E., The Chemistry of 1,3,5-Hexatriene, J. Am. Chem. Soc., 1955, 77, 1800. [all data]

Woods and Schwartzman, 1948
Woods, G.F.; Schwartzman, L.H., 1,3,5-Hexatriene, J. Am. Chem. Soc., 1948, 70, 3394. [all data]

Kharasch and Sternfeld, 1939
Kharasch, M.S.; Sternfeld, E., Synthesis of Polyenes I. Hexatriene and its Polymers, J. Am. Chem. Soc., 1939, 61, 2318. [all data]

Perkin, 1907
Perkin, W.H., The Magnetic Rotation of Hexatriene, CH2:CHCH:CHCH:CH2 and Its Relationship to Benzene and Other Aromatic Compounds. Also Its Refractive Power, J. Chem. Soc., 1907, 91, 800-16. [all data]

Notes

Go To: Top, Normal boiling point, References

• Symbols used in this document:
  

  Tboil

  Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.