5-Methyltricosane
- Formula: C24H50
- Molecular weight: 338.6538
- IUPAC Standard InChIKey: MWORWWXTNWRHAD-UHFFFAOYSA-N
- CAS Registry Number: 22331-09-5
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Tricosane, 5-methyl
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Gas Chromatography
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | OV-101 | 190. | 2352. | Kusmierz, Malinski, et al., 1985 | Column length: 22. m; Column diameter: 0.3 mm |
Capillary | Apiezon L | 190. | 2346.3 | Kusmierz, Malinski, et al., 1985 | He; Column length: 20. m; Column diameter: 0.3 mm |
Capillary | SE-52 | 190. | 2350. | Kusmierz, Malinski, et al., 1985 | He; Column length: 40. m; Column diameter: 0.3 mm |
Capillary | Dexsil 300 | 210. | 2348. | Szafranek, Kusmierz, et al., 1982 | He; Column length: 30. m; Column diameter: 0.30 mm |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Carbowax 20M | 150. | 2348.7 | Kusmierz, Malinski, et al., 1985 | He; Column length: 30. m; Column diameter: 0.25 mm |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5MS | 2349. | Steinmetz, Schmolz, et al., 2003 | 30. m/0.32 mm/0.25 μm, He, 3. K/min; Tstart: 150. C; Tend: 280. C |
Capillary | Cross-Linked Methylsilicone | 2352. | Khorasheh, Gray, et al., 1989 | 5. K/min; Tstart: 40. C; Tend: 300. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5 | 2347. | Zaikin and Borisov, 2002 | He; Column length: 30. m; Column diameter: 0.25 mm; Program: 30C => 5K/min=120C => 10C/min => 270C |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-1 | 2352. | Strohm, Herner, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium, 6. K/min, 300. C @ 20. min; Tstart: 100. C |
Capillary | OV-1 | 2352.9 | Krkosova, Kubinec, et al., 2007 | 100. m/0.32 mm/0.25 μm, Helium, 5. K/min, 310. C @ 5. min; Tstart: 30. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | 2351. | Steiger, Peschke, et al., 2007 | Program: not specified | |
Capillary | HP-5 | 2354. | Juárez, Carlson, et al., 2002 | H2; Column length: 30. m; Column diameter: 0.32 mm; Program: 60C (2min) => 20C/min => 180C => 3C/min => 310 C (10min) |
Capillary | CP Sil 5 CB | 2346. | Kenig, Sinninghe Damsté, et al., 1995 | 25. m/0.32 mm/0.2 μm, He; Program: 50C => 20C/min => 130C => 4C/min => 300C (20min) |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kusmierz, Malinski, et al., 1985
Kusmierz, J.; Malinski, E.; Czerwiec, W.; Szafranek, J.,
Kováts retention indices of high-molecular-weight monomethyl-, cyclopentyl-, cyclohexyl- and phenylalkanes,
J. Chromatogr., 1985, 331, 219-228, https://doi.org/10.1016/0021-9673(85)80027-3
. [all data]
Szafranek, Kusmierz, et al., 1982
Szafranek, J.; Kusmierz, J.; Czerwiec, W.,
Gas chromatographic-mass spectrometric investigations of high-boiling crude oil alkane fractions,
J. Chromatogr., 1982, 245, 2, 219-228, https://doi.org/10.1016/S0021-9673(00)88591-X
. [all data]
Steinmetz, Schmolz, et al., 2003
Steinmetz, I.; Schmolz, E.; Ruther, J.,
Cuticular lipids as trail pheromone in a social wasp,
Proc. R. Soc. London B:, 2003, 270, 1513, 385-391, https://doi.org/10.1098/rspb.2002.2256
. [all data]
Khorasheh, Gray, et al., 1989
Khorasheh, F.; Gray, M.R.; Selucky, M.L.,
Correlation for Kováts retention index of C9-C26 monoalkyl and polymethyl alkanes and alkenes,
J. Chromatogr., 1989, 481, 1-16, https://doi.org/10.1016/S0021-9673(01)96747-0
. [all data]
Zaikin and Borisov, 2002
Zaikin, V.G.; Borisov, R.S.,
Chromatographic-mass spectrometric analysis of Fishcer-Tropsch synthesis products,
J. Anal. Chem. USSR (Engl. Transl.), 2002, 57, 6, 544-551. [all data]
Strohm, Herner, et al., 2008
Strohm, E.; Herner, G.; Kaltenpoth, M.; Boland, W.; Schreier, P.; Geiselhardt, S.; Peschke, K.; Schmitt, T.,
The chemistry of the postpharyngeal gland of female European beewolves,
J. Chem. Ecol., 2008, 34, 5, 575-583, https://doi.org/10.1007/s10886-008-9447-x
. [all data]
Krkosova, Kubinec, et al., 2007
Krkosova, Z.; Kubinec, R.; Addova, G.; Jurdakova, H.; Blasko, J.; Ostrovsky, I.; Sojak, L.,
Gas chromatographic - mass spectrometric characterization of monomethylalkanes from fuel diesel,
Petroleum Coal, 2007, 49, 3, 51-62. [all data]
Steiger, Peschke, et al., 2007
Steiger, S.; Peschke, K.; Francke, W.; Muller, J.K.,
The smell of parents: breeding status influences cuticular hydrocarbon pattern in the burying beetle Nicrophorus vespilloides,
Proc. Roy. Soc. B, 2007, 274, 1622, 2211-2220, https://doi.org/10.1098/rspb.2007.0656
. [all data]
Juárez, Carlson, et al., 2002
Juárez, M.P.; Carlson, D.A.; Schettino, P.M.S.; Mijailovsky, S.; Rojas, G.,
Cuticular hydrocarbons of Chagas disease vectors in Mexico,
Mem. Inst. Oswaldo Cruz., 2002, 97, 6, 819-827, https://doi.org/10.1590/S0074-02762002000600012
. [all data]
Kenig, Sinninghe Damsté, et al., 1995
Kenig, F.; Sinninghe Damsté, J.S.; Kock-van Dalen, A.C.; Rijpstra, W.I.C.; Huc, A.Y.; de Leeuw, J.W.,
Occurrence and origin of mono-, di-, and trimethylalkanes in modern and holocene cyanobacterial mats from Abu Dhabi, United Arab Emirates,
Geochim. Cosmochim. Acta, 1995, 59, 14, 2999-3015, https://doi.org/10.1016/0016-7037(95)00190-5
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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