Benzenecarbothioamide
- Formula: C7H7NS
- Molecular weight: 137.202
- IUPAC Standard InChI: InChI=1S/C7H7NS/c8-7(9)6-4-2-1-3-5-6/h1-5H,(H2,8,9)
- IUPAC Standard InChIKey: QIOZLISABUUKJY-UHFFFAOYSA-N
- CAS Registry Number: 2227-79-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Benzamide, thio-; Benzothiamide; Benzothioamide; Thiobenzamide; Phenylthioamide; Tiobenzamide
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Condensed phase thermochemistry data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | 44.4 ± 1.5 | kJ/mol | Ccr | Ribeiro Da Silva, Souza, et al., 1989 | ALS |
| ΔfH°solid | 33.8 ± 1.1 | kJ/mol | Ccr | Sabbah and Gomez, 1982 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -4401.4 ± 1.1 | kJ/mol | Ccr | Ribeiro Da Silva, Souza, et al., 1989 | ALS |
| ΔcH°solid | -4390.78 ± 0.99 | kJ/mol | Ccr | Sabbah and Gomez, 1982 | ALS |
Constant pressure heat capacity of solid
| Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 152.8 | 298. | Sabbah and Torres-Gomez, 1982 | Cp given as 1.114 J K-1 g-1.; DH |
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.
Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | Japan AIST/NIMC Database- Spectrum MS-NW-8131 |
| NIST MS number | 231440 |
References
Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ribeiro Da Silva, Souza, et al., 1989
Ribeiro Da Silva, M.D.M.C.; Souza, P.; Pilcher, G.,
Enthalpies of combustion of thiobenzamide, N,N-dimethylthiobenzamide, and N,N-diethylthiobenzamide,
J. Chem. Thermodyn., 1989, 21, 173-178. [all data]
Sabbah and Gomez, 1982
Sabbah, R.; Gomez, L.A.T.,
Thermodynamique de substances soufrees. III. Etude thermochimique de la thioacetamide et de la thiobenzamide,
Thermochim. Acta, 1982, 52, 285-295. [all data]
Sabbah and Torres-Gomez, 1982
Sabbah, R.; Torres-Gomez, L.A.,
Thermodynamics of sulfur-containing compounds. III. Thermochemical study of thioacetamide and thiobenzamide,
Thermochim. Acta, 1982, 52, 285-295. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.