2-Butene, 2-chloro-, (E)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil334.65KN/AGardenier, 1946Uncertainty assigned by TRC = 2.5 K
Tboil335.75KN/AKinney, 1942Uncertainty assigned by TRC = 1. K; uncertain whether this was measured
Tboil338.15KN/ACharpentier, 1934Uncertainty assigned by TRC = 1.5 K
Tboil335.75KN/ANavez, 1930Uncertainty assigned by TRC = 1. K

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Butane, 2,2-dichloro- = 2-Butene, 2-chloro-, (E)- + Hydrogen chloride

By formula: C4H8Cl2 = C4H7Cl + HCl

Quantity Value Units Method Reference Comment
Δr-3.3 ± 0.02kcal/molEqkLevanova, Rozhnov, et al., 1972gas phase; At 568 K
Δr1.2 ± 0.06kcal/molEqkLevanova, Rozhnov, et al., 1972gas phase; At 404.5 K

Butane, 2,3-dichloro- = 2-Butene, 2-chloro-, (E)- + Hydrogen chloride

By formula: C4H8Cl2 = C4H7Cl + HCl

Quantity Value Units Method Reference Comment
Δr14.70 ± 0.22kcal/molEqkRodova, Levanova, et al., 1973gas phase; At 454 K

(E)-1-chlorobut-2-ene = 2-Butene, 2-chloro-, (E)-

By formula: C4H7Cl = C4H7Cl

Quantity Value Units Method Reference Comment
Δr-1.2 ± 0.01kcal/molEqkLevanova, Rozhnov, et al., 1972gas phase; At 568 K

2-Chloro-1-butene = 2-Butene, 2-chloro-, (E)-

By formula: C4H7Cl = C4H7Cl

Quantity Value Units Method Reference Comment
Δr-3.3kcal/molEqkLevanova, Rodova, et al., 1975gas phase

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin W.T. BOLLETER
Source reference COBLENTZ NO. 4509
Date Not specified, most likely prior to 1970
Name(s) (2Z)-2-chloro-2-butene
Instrument Not specified, most likely a prism, grating, or hybrid spectrometer.
Path length 0.0025 CM
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gardenier, 1946
Gardenier, , 1946. [all data]

Kinney, 1942
Kinney, C.R., A System Correlating Molecular Structure of Organic Compounds with Their Boiling Points VI. The Monohalogen Derivatives of the Various Hydrocarbons, J. Org. Chem., 1942, 7, 111. [all data]

Charpentier, 1934
Charpentier, P., Bull. Soc. Chim. Fr., 1934, 1, 1407. [all data]

Navez, 1930
Navez, L., Bull. Soc. Chim. Belg., 1930, 39, 435. [all data]

Levanova, Rozhnov, et al., 1972
Levanova, S.V.; Rozhnov, A.M.; Bortnik, O.K., Isomerization of dibromoethylenes, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1972, 15, 1821-1823. [all data]

Rodova, Levanova, et al., 1973
Rodova, R.M.; Levanova, S.V.; Shevtsova, L.A.; Rozhnov, A.M.; Porfir'eva, E.I., Reversible reactions of 2,3-dichlorobutane, Russ. J. Phys. Chem. (Engl. Transl.), 1973, 47, 607. [all data]

Levanova, Rodova, et al., 1975
Levanova, S.V.; Rodova, R.M.; Shevtsova, L.A.; Rozhnov, A.M., Isomerisation of chlorobutenes, Russ. J. Phys. Chem. (Engl. Transl.), 1975, 49, 41-43. [all data]


Notes

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