21H,23H-Porphine, 5,10,15,20-tetrakis(4-methoxyphenyl)-
- Formula: C48H38N4O4
- Molecular weight: 734.8397
- CAS Registry Number: 22112-78-3
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -40.9 ± 2.3 | kcal/mol | Ccb | Wu, Xu, et al., 1989 | see Xu, Wu, et al., 1989, and Li, Luo, et al., 1992 |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -5771.6 ± 1.8 | kcal/mol | Ccb | Wu, Xu, et al., 1989 | see Xu, Wu, et al., 1989, and Li, Luo, et al., 1992 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 70.727 | kcal/mol | E | Wu, Xu, et al., 1989 | see Xu, Wu, et al., 1989, and Li, Luo, et al., 1992; ALS |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
50.9 ± 2.9 | 563. | ME | Torres, Campos, et al., 2002 | Based on data from 561. to 565. K.; AC |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wu, Xu, et al., 1989
Wu, D.; Xu, G.; Qu, S.; Xue, R.; Gu, C.; Zhang, F.,
Standard enthalpies of combustion and formation of porphyrin derivatives,
Thermochim. Acta, 1989, 154, 233-245. [all data]
Xu, Wu, et al., 1989
Xu, H.; Wu, D.; Qu, S.,
Thermochemistry of porphyrins. VI. Standard energies of combusiton and standard enthalpies of formation of tetramethoxyphenylporphyrin and tetradimethylaminophenylporphyrin,
Wuli Huaxue Xuebao, 1989, 5, 745-749. [all data]
Li, Luo, et al., 1992
Li, L.; Luo, M.; Qu, S.; Huang, S.; Yan, X.,
Studies on structure and properties of tetraphenylporphyrin and its derivatives. (III). Standard molar enthalpies of sublimation and formation, enthalpies of strain and resonance energy,
Gaodeng Xuexiao Huaxue Xuebao, 1992, 13, 509-512. [all data]
Torres, Campos, et al., 2002
Torres, Luis Alfonso; Campos, Myriam; Enriquez, Esteban; Patiño, Rodrigo,
The enthalpy of sublimation of 5,10,15,20-tetraphenylporphine and 5,10,15,20-tetrakis(4-methoxyphenyl)porphine,
The Journal of Chemical Thermodynamics, 2002, 34, 3, 293-302, https://doi.org/10.1006/jcht.2001.0920
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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