mercury monoxide


Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through February, 1975

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for (202)Hg16O ?
StateTeωeωexeωeyeBeαeγeDeβereTrans.ν00
Absorption bands in the region 33900 - 36500 cm-1, usually ascribed to Hg2 ("wing" bands), were tentatively assigned to HgO by Walter and Barratt, 1929.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Walter and Barratt, 1929
Walter, J.M.; Barratt, S., The band spectra associated with zinc, cadmium, and mercury, Proc. R. Soc. London A, 1929, 122, 201. [all data]


Notes

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