F-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(F- • 4294967295F2Fe) + F2Fe = F-

By formula: (F- • 4294967295F2Fe) + F2Fe = F-

Quantity Value Units Method Reference Comment
Δr367. ± 15.kJ/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention
Δr359. ± 11.kJ/molTDEqBorshchevskii, Boltalina, et al., 1988gas phase; Fluoride Affinity: FeF2 < FeF3 by 22.6±2.6 kcal/mol.; value altered from reference due to conversion from electron convention to ion convention
Δr374. ± 17.kJ/molTDEqKuznetsov, Korobov, et al., 1986gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr359. ± 8.8kJ/molTDEqSidirov, Borshchevsky, et al., 1986gas phase; Corrections to Sorokin, Sidorov, et al., 1981, better neutral pressure determination; value altered from reference due to conversion from electron convention to ion convention
Δr441. ± 14.kJ/molTDEqSorokin, Sidorov, et al., 1981gas phase; Fluoride Affinity: 15.3±1.2 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(F- • 4294967295F2Fe) + F2Fe = F-

By formula: (F- • 4294967295F2Fe) + F2Fe = F-

Quantity Value Units Method Reference Comment
Δr367. ± 15.kJ/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention
Δr359. ± 11.kJ/molTDEqBorshchevskii, Boltalina, et al., 1988gas phase; Fluoride Affinity: FeF2 < FeF3 by 22.6±2.6 kcal/mol.; value altered from reference due to conversion from electron convention to ion convention
Δr374. ± 17.kJ/molTDEqKuznetsov, Korobov, et al., 1986gas phase; value altered from reference due to conversion from electron convention to ion convention
Δr359. ± 8.8kJ/molTDEqSidirov, Borshchevsky, et al., 1986gas phase; Corrections to Sorokin, Sidorov, et al., 1981, better neutral pressure determination; value altered from reference due to conversion from electron convention to ion convention
Δr441. ± 14.kJ/molTDEqSorokin, Sidorov, et al., 1981gas phase; Fluoride Affinity: 15.3±1.2 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N., Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions., J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8 . [all data]

Kuznetsov, Korobov, et al., 1986
Kuznetsov, S.V.; Korobov, M.V.; Savinova, L.N.; Sidirov, L.N., Enthalpy of the addition of the F- ion to copper and iron difluorides, Russ. J. Phys. Chem., 1986, 60, 766. [all data]

Sidirov, Borshchevsky, et al., 1986
Sidirov, L.N.; Borshchevsky, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Skokan, E.V., Electron affinities of gaseous iron fluorides and dimers, Int. J. Mass Spectrom. Ion Processes, 1986, 73, 1. [all data]

Sorokin, Sidorov, et al., 1981
Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I.; Skokan, E.V., Mass-spectrometric determination of the enthalpies of dissociation of gaseous complex fluorides into neutral and charged particles. V. Heats of formation of FeF3- and FeF4-, Int. J. Mass Spectrom. Ion Phys., 1981, 41, 45. [all data]


Notes

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