Perhydrophenanthrene, (4aα, 4bβ, 8aα, 10aβ)-

• Formula: C₁₄H₂₀
• Molecular weight: 188.3086
• IUPAC Standard InChI: InChI=1S/C14H24/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h11-14H,1-10H2/t11-,12-,13+,14+/m0/s1 Copy

  
• IUPAC Standard InChIKey: GNMCGMFNBARSIY-IGQOVBAYSA-N Copy
• CAS Registry Number: 2108-89-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Species with the same structure:
  • Perhydrophenanthrene, (4aα, 4bα, 8aα, 10aβ)-
• Stereoisomers:
  • cis,syn,cis-Perhydrophenanthrene
  • Perhydrophenanthrene, (4aα, 4bβ, 8aα, 10a.alpha)-
  • Perhydrophenanthrene, (4aα, 4bβ, 8aβ, 10aα)-
  • Perhydrophenanthrene, (4aα, 4bα, 8aβ, 10a.beta)-
  • Phenanthrene, tetradecahydro-
  • Tricyclo[8.4.0.0(2,7)]dodecane, isomer # 1
  • Tricyclo[8.4.0.0(2,7)]dodecane, isomer # 2
  • Tricyclo[8.4.0.0(2,7)]dodecane, isomer # 3
  • Tricyclo[8.4.0.0(2,7)]dodecane, isomer # 4
• Other names: trans,anti,trans-Perhydrophenanthrene
• Information on this page:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Options:
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Glushko Thermocenter, Russian Academy of Sciences, Moscow

Constant pressure heat capacity of gas

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

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By formula: C₁₄H₂₀ = C₁₄H₂₄

=

By formula: C₁₄H₂₀ = C₁₄H₂₄

=

By formula: C₁₄H₂₀ = C₁₄H₂₄

=

By formula: C₁₄H₂₀ = C₁₄H₂₄

=

By formula: C₁₄H₂₀ = C₁₄H₂₄

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorofeeva O.V., 1988
Dorofeeva O.V., Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons in the Gaseous Phase. Institute for High Temperatures, USSR Academy of Sciences, Preprint No.1-238 (in Russian), Moscow, 1988. [all data]

Dorofeeva O.V., 1986
Dorofeeva O.V., On calculation of thermodynamic properties of polycyclic aromatic hydrocarbons, Thermochim. Acta, 1986, 102, 59-66. [all data]

Frenkel M., 1994
Frenkel M., Thermodynamics of Organic Compounds in the Gas State, Vol. I, II, Thermodynamics Research Center, College Station, Texas, 1994, 1994. [all data]

Nuzzi, 1982
Nuzzi, M., Thermal data and thermodynamic functions of perhydrophenanthrenes, Riv. Combust., 1982, 36, 41. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Honig and Allinger, 1985
Honig, H.; Allinger, N.L., The stereoisomers of perhydrophenanthrene, J. Org. Chem., 1985, 50, 4630-4632. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Cp,gas	Constant pressure heat capacity of gas
  Tfus	Fusion (melting) point
  ΔfusH	Enthalpy of fusion
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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