Acenaphthylene
- Formula: C12H8
- Molecular weight: 152.1919
- IUPAC Standard InChIKey: HXGDTGSAIMULJN-UHFFFAOYSA-N
- CAS Registry Number: 208-96-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Cyclopenta[de]naphthalene; Acenaphthalene
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Lee's RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | PE-5 | 5 % Phenyl methyl siloxane | 5 % Phenyl methyl siloxane | HP-5 | DB-5MS |
Column length (m) | 20. | 30. | 30. | ||
Carrier gas | Helium | ||||
Substrate | |||||
Column diameter (mm) | 0.18 | 0.25 | 0.25 | ||
Phase thickness (μm) | 0.18 | 0.25 | 0.5 | ||
Tstart (C) | 50. | 50. | 80. | 50. | 40. |
Tend (C) | 345. | 250. | 300. | 310. | 310. |
Heat rate (K/min) | 8. | 2. | 8. | 6. | 10. |
Initial hold (min) | 1.5 | 2. | 1.5 | 1. | |
Final hold (min) | 10. | 10. | |||
I | 247.8 | 244.63 | 247.40 | 248.47 | 248.88 |
Reference | Jamoussi, Kanzari, et al., 2007 | Skrbic and Onjia, 2006 | Skrbic and Onjia, 2006 | Pedersen, Durant, et al., 2005 | Chen, Keeran, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5MS | PTE-5 | HP-5 | DB-5 | DB-5 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.5 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 40. | 60. | 50. | 50. | 50. |
Tend (C) | 310. | 300. | 280. | 300. | 300. |
Heat rate (K/min) | 4. | 8. | 4. | 15. | 15. |
Initial hold (min) | 1. | 1.5 | 2. | ||
Final hold (min) | 12.5 | 20. | |||
I | 248.48 | 248.29 | 247.93 | 245.4 | 245.4 |
Reference | Chen, Keeran, et al., 2002 | Wang, Jia, et al., 2000 | Piao, Chu, et al., 1999 | Durlak, Biswas, et al., 1998 | Durlak, Biswas, et al., 1998 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | HT-5 | SE-52 | SE-54 | DB-5 |
Column length (m) | 30. | 25. | 30. | 30. | 30. |
Carrier gas | H2 | ||||
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.30 | 0.25 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | |||
Tstart (C) | 50. | 40. | 40. | 50. | 80. |
Tend (C) | 300. | 400. | 250. | 300. | 270. |
Heat rate (K/min) | 15. | 5. | 4. | 4. | 4. |
Initial hold (min) | 8. | 2. | |||
Final hold (min) | 20. | 5. | |||
I | 249.0 | 249.04 | 245.83 | 245.36 | 249.19 |
Reference | Durlak, Biswas, et al., 1998 | Williams and Williams, 1998 | Wang, Peng, et al., 1997 | Chen, 1996 | Andersson and Weis, 1994 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | SE-54 | DB-5 | DB-5 | SE-52 |
Column length (m) | 30. | 20. | 30. | 30. | 12. |
Carrier gas | He | He | Hydrogen | ||
Substrate | |||||
Column diameter (mm) | 0.32 | 0.22 | 0.32 | 0.25 | |
Phase thickness (μm) | 0.25 | 0.20 | 0.25 | 0.25 | |
Tstart (C) | 40. | 50. | 80. | 40. | 120. |
Tend (C) | 285. | 300. | 290. | 280. | 285. |
Heat rate (K/min) | 8. | 4. | 3. | 4. | 3. |
Initial hold (min) | 3. | 1. | 2. | ||
Final hold (min) | 29.5 | 5. | |||
I | 248.9 | 247.82 | 244.79 | 247.65 | 244.63 |
Reference | Donnelly, Abdel-Hamid, et al., 1993 | Guillén, Blanco, et al., 1989 | Sye, Lin, et al., 1988 | Wise, Benner, et al., 1988 | Boenke and Ballschmiter, 1987 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | DB-5 | DB-5 | SE-52 | SE-52 |
Column length (m) | 30. | 30. | 30. | 20. | 12. |
Carrier gas | He | He | He | H2 | He |
Substrate | |||||
Column diameter (mm) | 0.26 | 0.25 | 0.32 | 0.30 | 0.3 |
Phase thickness (μm) | 0.25 | 0.25 | 0.34 | ||
Tstart (C) | 50. | 90. | 80. | 40. | 50. |
Tend (C) | 300. | 325. | 300. | 265. | 250. |
Heat rate (K/min) | 6. | 4. | 3. | 4. | 2. |
Initial hold (min) | 4. | 1. | 2. | ||
Final hold (min) | 20. | 10. | |||
I | 248.75 | 243.59 | 242.459 | 246.92 | 244.63 |
Reference | Rostad and Pereira, 1986 | Tong, Centen, et al., 1985 | Tong, Shore, et al., 1984 | Vassilaros, Kong, et al., 1982 | Lee, Vassilaros, et al., 1979 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Lee's RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Jamoussi, Kanzari, et al., 2007
Jamoussi, B.; Kanzari, F.; Hassine, B.B.; Abderrabba, A.,
Using Bezier curves for the calculation of retention indices of polycyclic aromatic hydrocarbons in the so-called Lee's scale in temperature-programmed gas chromatography with mass spectrometry detection,
J. Chromatogr. Sci., 2007, 45, 1, 22-27, https://doi.org/10.1093/chromsci/45.1.22
. [all data]
Skrbic and Onjia, 2006
Skrbic, B.; Onjia, A.,
Prediction of Lee Retention Indices of Polycyclic Aromatic Hydrocarbons by Artificial Neural Networks,
J. Chromatorg. A, 2006, 1108, 2, 279-284, https://doi.org/10.1016/j.chroma.2006.01.080
. [all data]
Pedersen, Durant, et al., 2005
Pedersen, D.U.; Durant, J.L.; Taghizadeh, K.; Hemond, H.F.; Lafleur, A.L.; Cass, G.R.,
Human cell mutagenes in respirable airborne particles from the Northeastern United States. 2. Quantification of mutagenes and other organic compounds.,
Environ. Sci. Technol., 2005, 39, 24, 9547-9560, https://doi.org/10.1021/es050886c
. [all data]
Chen, Keeran, et al., 2002
Chen, P.H.; Keeran, W.S.; Van Ausdale, W.A.; Schindler, D.R.; Roberts, D.W.,
Application of Lee retention indices to the confirmation of tentatively identified compounds from GC/MS analysis of environmental samples, Technical paper, Analytical Services Division, Environmental ScienceEngineering, Inc, PO Box 1703, Gainesville, FL 32602, 2002, 11. [all data]
Wang, Jia, et al., 2000
Wang, J.; Jia, C.R.; Wong, C.K.; Wong, P.K.,
Characterization of polycyclic aromatic hydrocarbons created in lubricating oils,
Water Air Soil Poll., 2000, 120, 3/4, 381-396, https://doi.org/10.1023/A:1005251618062
. [all data]
Piao, Chu, et al., 1999
Piao, M.; Chu, S.; Zheng, M.; Xu, X.,
Characterization of the combustion products of polyethylene,
Chemosphere, 1999, 39, 9, 1497-1512, https://doi.org/10.1016/S0045-6535(99)00054-5
. [all data]
Durlak, Biswas, et al., 1998
Durlak, S.K.; Biswas, P.; Shi, J.; Bernhard, M.J.,
Characterization of polycyclic aromatic hydrocarbon particulate and gaseous emissions from polystyrene combustion,
Environ. Sci. Technol., 1998, 32, 15, 2301-2307, https://doi.org/10.1021/es9709031
. [all data]
Williams and Williams, 1998
Williams, P.T.; Williams, E.A.,
Recycling plastic waste by pyrolysis,
J. Inst. Energy, 1998, 71, 81-93. [all data]
Wang, Peng, et al., 1997
Wang, Y.; Peng, P.; Cui, S.; Zhang, Y.,
Identification of PAH in the Suzhou River bed sediments by GC/MS and PAH retention index system,
J. Nanjing Norm. Univ. (Nat. Sci.), 1997, 20, 2, 47-68. [all data]
Chen, 1996
Chen, J.,
GC and GC/MS methods for the analysis of polycyclic aromatic hydrocarbon (PAH) in sediment of the grand canal of China,
Toxicol. Environ. Chem., 1996, 54, 1-4, 69-73, https://doi.org/10.1080/02772249609358297
. [all data]
Andersson and Weis, 1994
Andersson, J.T.; Weis, U.,
Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards,
J. Chromatogr. A, 1994, 659, 1, 151-161, https://doi.org/10.1016/0021-9673(94)85017-8
. [all data]
Donnelly, Abdel-Hamid, et al., 1993
Donnelly, J.R.; Abdel-Hamid, M.S.; Jeter, J.L.; Gurka, D.F.,
Application of gas chromatographic retention properties to the identification of environmental contaminants,
J. Chromatogr., 1993, 642, 1-2, 409-415, https://doi.org/10.1016/0021-9673(93)80106-I
. [all data]
Guillén, Blanco, et al., 1989
Guillén, M.D.; Blanco, J.; Bermejo, J.; Blanco, C.G.,
Temperature programmed retention indices of some PAHs on Capillary columns coated with OV-1701 and SE-54,
J. Hi. Res. Chromatogr., 1989, 12, 8, 552-554, https://doi.org/10.1002/jhrc.1240120816
. [all data]
Sye, Lin, et al., 1988
Sye, W.-F.; Lin, C.-L.; Yen, D.-P.; Tsai, C.-S.,
Polycyclic aromatic-hydrocarbons formation from luel and additives combustion,
J. Chinese Chem. Soc., 1988, 35, 1, 1-11. [all data]
Wise, Benner, et al., 1988
Wise, S.A.; Benner, B.A.; Byrd, G.D.; Chesler, S.N.; Rebbert, R.E.; Schantz, M.M.,
Determination of polycyclic aromatic hydrocarbons in a coal tar standard reference material,
Anal. Chem., 1988, 60, 9, 887-894, https://doi.org/10.1021/ac00160a012
. [all data]
Boenke and Ballschmiter, 1987
Boenke, A.; Ballschmiter, K.,
Fused quinones as retention index marker in high resolution gas chromatography with electron-capture detection (HRGC/ECD) of oxidized aromatic compounds,
Fresenius J. Anal. Chem., 1987, 327, 1, 44-45, https://doi.org/10.1007/BF00474554
. [all data]
Rostad and Pereira, 1986
Rostad, C.E.; Pereira, W.E.,
Kovats and Lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 6, 328-334, https://doi.org/10.1002/jhrc.1240090603
. [all data]
Tong, Centen, et al., 1985
Tong, H.Y.; Centen, J.D.; Karasek, F.W.; Jellum, E.; Helland, P.,
Identification of Trace Organic Compounds in Dimethyl Sulphoxide Solution Using High-Performance Liquid Chromatography and Gas Chromatography-Mass Spectrometry,
J. Chromatogr., 1985, 324, 373-383, https://doi.org/10.1016/S0021-9673(01)81336-4
. [all data]
Tong, Shore, et al., 1984
Tong, H.Y.; Shore, D.L.; Karasek, F.W.; Helland, P.; Jellum, E.,
Identification of organic compounds obtained from incineration of municipal waste by high-performance liquid chromatographic fractionation and gas chromatography-mass spectrometry,
J. Chromatogr., 1984, 285, 423-441, https://doi.org/10.1016/S0021-9673(01)87784-0
. [all data]
Vassilaros, Kong, et al., 1982
Vassilaros, D.L.; Kong, R.C.; Later, D.W.; Lee, M.L.,
Linear retention index system for polycyclic aromatic compounds. Critical evaluation and additional indices,
J. Chromatogr., 1982, 252, 1-20, https://doi.org/10.1016/S0021-9673(01)88394-1
. [all data]
Lee, Vassilaros, et al., 1979
Lee, M.L.; Vassilaros, D.L.; White, C.M.; Novotny, M.,
Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons,
Anal. Chem., 1979, 51, 6, 768-773, https://doi.org/10.1021/ac50042a043
. [all data]
Notes
Go To: Top, Lee's RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.