Aluminum hydroxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-179.91kJ/molReviewChase, 1998Data last reviewed in December, 1967
Quantity Value Units Method Reference Comment
gas,1 bar216.43J/mol*KReviewChase, 1998Data last reviewed in December, 1967

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1000.1000. to 3000.3000. to 6000.
A 2.98719142.9641060.36120
B 107.087013.923900.705341
C -89.55760-3.941531-0.096709
D 29.032200.4080480.004812
E 0.372525-3.542960-16.71250
F -183.5790-202.2650-225.8000
G 193.9360251.8820258.0200
H -179.9120-179.9120-179.9120
ReferenceChase, 1998Chase, 1998Chase, 1998
Comment Data last reviewed in December, 1967 Data last reviewed in December, 1967 Data last reviewed in December, 1967

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

AlO- + Hydrogen cation = HAlO

By formula: AlO- + H+ = HAlO

Quantity Value Units Method Reference Comment
Δr1539. ± 40.kJ/molD-EADesai, Wu, et al., 1996gas phase
Δr1505. ± 17.kJ/molG+TSDamrauer, Krempp, et al., 1991gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO
Quantity Value Units Method Reference Comment
Δr1509. ± 41.kJ/molH-TSDesai, Wu, et al., 1996gas phase
Δr1475. ± 17.kJ/molIMRBDamrauer, Krempp, et al., 1991gas phase; Between CF3CH2OH, pyrrole. Calculations imply that the acid is AlOH, not HAlO

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Desai, Wu, et al., 1996
Desai, S.R.; Wu, H.; Wang, L.-S., Vibrationally Resolved Photoelectron Spectroscopy of AlO- and AlO2-, Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 75, https://doi.org/10.1016/S0168-1176(96)04443-6 . [all data]

Damrauer, Krempp, et al., 1991
Damrauer, R.; Krempp, M.; Schmidt, M.W.; Gordon, M.S., Gas-Phase Chemistry of the Dimethylaluminum Oxide Ion and Related Aluminum Oxide Ions - Comparison of Reactivity with Siloxide Ions, J. Am. Chem. Soc., 1991, 113, 7, 2393, https://doi.org/10.1021/ja00007a007 . [all data]


Notes

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