Benzoyl(cyclohexyloxy)-carbonylperoxide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-645.3 ± 9.4kJ/molCcbKiparisova and Rabinovich, 1971Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -644. ± 10. kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-741.5 ± 8.4kJ/molCcbKiparisova and Rabinovich, 1971Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -740.6 ± 8.4 kJ/mol
Quantity Value Units Method Reference Comment
Δcsolid-7054.2 ± 8.4kJ/molCcbKiparisova and Rabinovich, 1971Corresponding Δfsolid = -741.4 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub96.2kJ/molN/AKiparisova and Rabinovich, 1971DRB

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
96.2 ± 4.2303.MEKiparisova and Rabinovich, 1971, 2Based on data from 293. to 313. K. See also Pedley and Rylance, 1977.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kiparisova and Rabinovich, 1971
Kiparisova, E.G.; Rabinovich, I.B., Thermochemistry of a series of acyl peroxides, Dokl. Phys. Chem. (Engl. Transl.), 1971, 199, 675-677, In original 1075. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Kiparisova and Rabinovich, 1971, 2
Kiparisova, E.G.; Rabinovich, I.B., Dokl. Akad. Nauk SSSR, 1971, 199, 5, 1075. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]


Notes

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