Benzoyl(cyclohexyloxy)-carbonylperoxide
- Formula: C14H16O5
- Molecular weight: 264.2738
- IUPAC Standard InChI: InChI=1S/C14H16O5/c15-13(11-7-3-1-4-8-11)18-19-14(16)17-12-9-5-2-6-10-12/h1,3-4,7-8,12H,2,5-6,9-10H2
- IUPAC Standard InChIKey: XHRPWCKLJGNVSL-UHFFFAOYSA-N
- CAS Registry Number: 20666-86-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -645.3 ± 9.4 | kJ/mol | Ccb | Kiparisova and Rabinovich, 1971 | Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -644. ± 10. kJ/mol |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -741.5 ± 8.4 | kJ/mol | Ccb | Kiparisova and Rabinovich, 1971 | Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -740.6 ± 8.4 kJ/mol |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -7054.2 ± 8.4 | kJ/mol | Ccb | Kiparisova and Rabinovich, 1971 | Corresponding ΔfHºsolid = -741.4 kJ/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 96.2 | kJ/mol | N/A | Kiparisova and Rabinovich, 1971 | DRB |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 96.2 ± 4.2 | 303. | ME | Kiparisova and Rabinovich, 1971, 2 | Based on data from 293. to 313. K. See also Pedley and Rylance, 1977.; AC |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kiparisova and Rabinovich, 1971
Kiparisova, E.G.; Rabinovich, I.B.,
Thermochemistry of a series of acyl peroxides,
Dokl. Phys. Chem. (Engl. Transl.), 1971, 199, 675-677, In original 1075. [all data]
Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P.,
Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]
Kiparisova and Rabinovich, 1971, 2
Kiparisova, E.G.; Rabinovich, I.B.,
Dokl. Akad. Nauk SSSR, 1971, 199, 5, 1075. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
, Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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