1,1'-Biphenyl, 4,4'-dichloro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid16.5kJ/molCcrSmith, Gorin, et al., 1964 
Quantity Value Units Method Reference Comment
Δcsolid-5927.10 ± 0.63kJ/molCcrSmith, Gorin, et al., 1964 
Δcsolid-5813.54kJ/molCcbBrull, 1935 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil590.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus422.5KN/ASangster and Irvine, 1956Uncertainty assigned by TRC = 2. K; TRC
Tfus420.KN/AKaluszyner and Reuter, 1953Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δvap81.4 ± 0.3kJ/molCGCPuri, Chickos, et al., 2001AC
Quantity Value Units Method Reference Comment
Δsub104. ± 4.2kJ/molVSmith, Gorin, et al., 1964ALS
Δsub103.8 ± 4.2kJ/molMESmith, Gorin, et al., 1964Based on data from 303. to 360. K. See also Cox and Pilcher, 1970.; AC
Δsub91.2 ± 4.2kJ/molMESmith, Gorin, et al., 1964Based on data from 294. to 318. K. See also Cox and Pilcher, 1970.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
76.0368.GCFalconer and Bidleman, 1994Based on data from 343. to 393. K.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
95.3 ± 1.3283.GSWania, Shiu, et al., 1994Based on data from 263. to 303. K.; AC
103.7331.MESmith, Gorin, et al., 1964Based on data from 303. to 360. K. See also Stephenson and Malanowski, 1987.; AC
91.4306.MESmith, Gorin, et al., 1964Based on data from 294. to 318. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Smith, Gorin, et al., 1964
Smith, N.K.; Gorin, G.; Good, W.D.; McCullough, J.P., The heats of combustion, sublimation, and formation of four dihalobiphenyls, J. Phys. Chem., 1964, 68, 940-946. [all data]

Brull, 1935
Brull, L., Sui calori di combustione di alcuni derivati del bifenil, Gazz. Chim. Ital., 1935, 65, 19-28. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Sangster and Irvine, 1956
Sangster, R.C.; Irvine, J.W., Study of Organic Scintillators, J. Chem. Phys., 1956, 24, 670. [all data]

Kaluszyner and Reuter, 1953
Kaluszyner, A.; Reuter, S., The Reaction of Ethyl Trichloroacette with Aromatic Grignard Compounds, J. Am. Chem. Soc., 1953, 75, 5126. [all data]

Puri, Chickos, et al., 2001
Puri, Swati; Chickos, James S.; Welsh, William J., Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography, Anal. Chem., 2001, 73, 7, 1480-1484, https://doi.org/10.1021/ac001246p . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

Falconer and Bidleman, 1994
Falconer, Renee L.; Bidleman, Terry F., Vapor pressures and predicted particle/gas distributions of polychlorinated biphenyl congeners as functions of temperature and ortho-chlorine substitution, Atmospheric Environment, 1994, 28, 3, 547-554, https://doi.org/10.1016/1352-2310(94)90130-9 . [all data]

Wania, Shiu, et al., 1994
Wania, Frank; Shiu, Wan-Ying; Mackay, Donald, Measurement of the Vapor Pressure of Several Low-Volatility Organochlorine Chemicals at Low Temperatures with a Gas Saturation Method, J. Chem. Eng. Data, 1994, 39, 3, 572-577, https://doi.org/10.1021/je00015a039 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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