Iodide

Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar169.26J/mol*KReviewChase, 1998Data last reviewed in June, 1982

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Iodide + Water = (Iodide • Water)

By formula: I- + H2O = (I- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°43. ± 3.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°64.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°80.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
ΔrS°68.2J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°23. ± 1.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • Water) + Water = (Iodide • 2Water)

By formula: (I- • H2O) + H2O = (I- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°41.4 ± 0.84kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
ΔrH°39.7kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
ΔrH°39.7 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°41. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
ΔrH°41. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°73.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°84.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
ΔrS°79.5J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°17. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Iodide + Carbon dioxide = (Iodide • Carbon dioxide)

By formula: I- + CO2 = (I- • CO2)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 7.5kJ/molN/APiani, Becucci, et al., 2008gas phase; Stated electron affinity is the Vertical Detachment Energy; B
ΔrH°17. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°20. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
ΔrH°13.4kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°23.4 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°56.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
ΔrS°76.1J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
ΔrG°3.3 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B,M
ΔrG°1.7 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Iodide • 2Water) + Water = (Iodide • 3Water)

By formula: (I- • 2H2O) + H2O = (I- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°38.9 ± 1.3kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
ΔrH°36. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
ΔrH°38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°39. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
ΔrH°39. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°85.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°87.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
ΔrS°89.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°12.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
ΔrG°13.0 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Iodide + Acetonitrile = (Iodide • Acetonitrile)

By formula: I- + C2H3N = (I- • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°49.8 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
ΔrH°46.4 ± 1.7kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°46.4 ± 4.6kJ/molLPESDessent, Bailey, et al., 1995gas phase; B
ΔrH°46.02 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°50.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°57.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°76.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°27. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B
ΔrG°28. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B
ΔrG°28.9 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Methyl Alcohol = (Iodide • Methyl Alcohol)

By formula: I- + CH4O = (I- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°49.79 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°47.3 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
ΔrH°46.9kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrH°46.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°71.5J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrS°74.5J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°24.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°25. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B
ΔrG°24. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

Iodide + Methane, iodo- = (Iodide • Methane, iodo-)

By formula: I- + CH3I = (I- • CH3I)

Quantity Value Units Method Reference Comment
ΔrH°35.7 ± 0.84kJ/molN/AVan Duzor, Wei, et al., 2010gas phase; B
ΔrH°32.6 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
ΔrH°35.1 ± 2.1kJ/molN/AArnold, Neumark, et al., 1995gas phase; ZEKE data, shift relative to bare I-; B
ΔrH°34.7 ± 2.1kJ/molPDisCyr, Bishea, et al., 1992gas phase; B
ΔrH°38. ± 8.4kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°68.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°11.4 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
ΔrG°17.2 ± 1.3kJ/molTDAsDougherty and Roberts, 1974gas phase; B

(Iodide • Acetonitrile) + Acetonitrile = (Iodide • 2Acetonitrile)

By formula: (I- • C2H3N) + C2H3N = (I- • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°43.51 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°46.4 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°46.4 ± 1.7kJ/molN/ADessent, Bailey, et al., 1995gas phase; Vertical Detachment Energy: 2.25±0.08 eV.; B
ΔrH°43.93kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°77.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°87.0J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°20.5 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°18.0kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Iodide + Sulfur dioxide = (Iodide • Sulfur dioxide)

By formula: I- + O2S = (I- • O2S)

Quantity Value Units Method Reference Comment
ΔrH°59.8 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
ΔrH°53.97 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°73.6J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
ΔrS°84.5J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°38. ± 11.kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B
ΔrG°7.11 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
ΔrG°28.5 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • 2Carbon dioxide) + Carbon dioxide = (Iodide • 3Carbon dioxide)

By formula: (I- • 2CO2) + CO2 = (I- • 3CO2)

Quantity Value Units Method Reference Comment
ΔrH°9.20kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°19. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°77.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide • 4Carbon dioxide) + Carbon dioxide = (Iodide • 5Carbon dioxide)

By formula: (I- • 4CO2) + CO2 = (I- • 5CO2)

Quantity Value Units Method Reference Comment
ΔrH°7.11kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°18. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-5.9 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide • Carbon dioxide) + Carbon dioxide = (Iodide • 2Carbon dioxide)

By formula: (I- • CO2) + CO2 = (I- • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°20. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B,M
ΔrH°10.9kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
Quantity Value Units Method Reference Comment
ΔrS°72.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

(Iodide • 3Water) + Water = (Iodide • 4Water)

By formula: (I- • 3H2O) + H2O = (I- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°29. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
ΔrS°98.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.8 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°9.2 ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Iodide • 5Carbon dioxide) + Carbon dioxide = (Iodide • 6Carbon dioxide)

By formula: (I- • 5CO2) + CO2 = (I- • 6CO2)

Quantity Value Units Method Reference Comment
ΔrH°13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°7.53kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°18.kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°79.J/mol*KN/AHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M

(Iodide • 2Acetonitrile) + Acetonitrile = (Iodide • 3Acetonitrile)

By formula: (I- • 2C2H3N) + C2H3N = (I- • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°40.6 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
ΔrH°38.9kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°83.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
ΔrS°92.5J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°13.4 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
ΔrG°11.3kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Iodide • 4Water) + Water = (Iodide • 5Water)

By formula: (I- • 4H2O) + H2O = (I- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°37.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
ΔrH°17.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°6.28kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

Iodide + Ethanol = (Iodide • Ethanol)

By formula: I- + C2H6O = (I- • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°54.39 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°50.6 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°25.6kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B
ΔrG°25. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

(Iodide • 3Carbon dioxide) + Carbon dioxide = (Iodide • 4Carbon dioxide)

By formula: (I- • 3CO2) + CO2 = (I- • 4CO2)

Quantity Value Units Method Reference Comment
ΔrH°7.53kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B
ΔrH°15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°19. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°-4.2 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B

Iodide + Iodine = I3-

By formula: I- + I2 = I3-

Quantity Value Units Method Reference Comment
ΔrH°136. ± 10.kJ/molN/ATaylor, Asmis, et al., 1999gas phase; B
ΔrH°126. ± 5.9kJ/molCIDTDo, Klein, et al., 1997gas phase; B
ΔrH°356.1kJ/molTherFinch, Gates, et al., 1977gas phase; This value is far more bound than expected from other studies; B
ΔrH°136.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; ΔS(EA)=2.8; B
Quantity Value Units Method Reference Comment
ΔrG°94.14kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; ΔS(EA)=2.8; B

Iodide + Phenol, 4-chloro- = (Iodide • Phenol, 4-chloro-)

By formula: I- + C6H5ClO = (I- • C6H5ClO)

Quantity Value Units Method Reference Comment
ΔrH°85.8 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°48.5 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
48.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-chloro- = (Iodide • Phenol, 3-chloro-)

By formula: I- + C6H5ClO = (I- • C6H5ClO)

Quantity Value Units Method Reference Comment
ΔrH°88.3 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°51.0 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
51.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 4-fluoro- = (Iodide • Phenol, 4-fluoro-)

By formula: I- + C6H5FO = (I- • C6H5FO)

Quantity Value Units Method Reference Comment
ΔrH°82.0 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°44.8 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
43.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-fluoro- = (Iodide • Phenol, 3-fluoro-)

By formula: I- + C6H5FO = (I- • C6H5FO)

Quantity Value Units Method Reference Comment
ΔrH°81.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°43.9 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
44.8423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol, 3-nitro- = (Iodide • Phenol, 3-nitro-)

By formula: I- + C6H5NO3 = (I- • C6H5NO3)

Quantity Value Units Method Reference Comment
ΔrH°97.1 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°59.8 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
59.8423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 4-hydroxy- = (Iodide • Benzonitrile, 4-hydroxy-)

By formula: I- + C7H5NO = (I- • C7H5NO)

Quantity Value Units Method Reference Comment
ΔrH°99.6 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°62.3 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
62.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Benzonitrile, 3-hydroxy- = (Iodide • Benzonitrile, 3-hydroxy-)

By formula: I- + C7H5NO = (I- • C7H5NO)

Quantity Value Units Method Reference Comment
ΔrH°96.2 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°59.0 ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
59.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + p-Cresol = (Iodide • p-Cresol)

By formula: I- + C7H8O = (I- • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°68.6 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°31. ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Phenol = (Iodide • Phenol)

By formula: I- + C6H6O = (I- • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°72.4 ± 7.5kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B,M
Quantity Value Units Method Reference Comment
ΔrS°88.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°35. ± 4.2kJ/molIMREPaul and Kebarle, 1990gas phase; ΔGaff at 423 K; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Iodide + Hydrogen bromide = (Iodide • Hydrogen bromide)

By formula: I- + HBr = (I- • HBr)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°67.4 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
ΔrG°43. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
42.7300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen iodide = (Iodide • Hydrogen iodide)

By formula: I- + HI = (I- • HI)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°71.1 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°102.J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M
Quantity Value Units Method Reference Comment
ΔrG°41. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.300.PHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(I-)SO2; M

Iodide + Hydrogen cation = Hydrogen iodide

By formula: I- + H+ = HI

Quantity Value Units Method Reference Comment
ΔrH°1315.24 ± 0.084kJ/molD-EAPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
ΔrH°1312.1kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; ΔS(EA)=5.0; B
Quantity Value Units Method Reference Comment
ΔrG°1294.03 ± 0.25kJ/molH-TSPelaez, Blondel, et al., 2009gas phase; Given: 3.0590463(38) eV; B
ΔrG°1290.8kJ/molN/ACheck, Faust, et al., 2001gas phase; Fe(CO)2-(q); ; ΔS(EA)=5.0; B

Iodide + Hydrogen chloride = (Iodide • Hydrogen chloride)

By formula: I- + HCl = (I- • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°61.9 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
ΔrH°59.4kJ/molHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°83.7J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
ΔrS°95.0J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°37. ± 11.kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B

(Iodide • 2Nitrous oxide) + Nitrous oxide = (Iodide • 3Nitrous oxide)

By formula: (I- • 2N2O) + N2O = (I- • 3N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°13.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°63.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

(Iodide • 2Methyl Alcohol) + Methyl Alcohol = (Iodide • 3Methyl Alcohol)

By formula: (I- • 2CH4O) + CH4O = (I- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°32.2 ± 2.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°93.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°14.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°13. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide • Methyl Alcohol) + Methyl Alcohol = (Iodide • 2Methyl Alcohol)

By formula: (I- • CH4O) + CH4O = (I- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°39.7 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°46.4 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°94.6J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°17.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°18. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

Iodide + Formic acid = (Iodide • Formic acid)

By formula: I- + CH2O2 = (I- • CH2O2)

Quantity Value Units Method Reference Comment
ΔrH°79.1 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
ΔrH°54.0 ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; Authors suggest real value somewhere between this and Caldwell and Kebarle, 1984; B
Quantity Value Units Method Reference Comment
ΔrS°86.6J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°53.1 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Isopropyl Alcohol = (Iodide • Isopropyl Alcohol)

By formula: I- + C3H8O = (I- • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°54.81 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°51.0 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°79.9J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°26.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + 2-Propanol, 2-methyl- = (Iodide • 2-Propanol, 2-methyl-)

By formula: I- + C4H10O = (I- • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°54.8 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°50.6 ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°78.2J/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°25.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°27. ± 4.2kJ/molTDAsCaldwell and Kebarle, 1984gas phase; B

Iodide + Ammonia = (Iodide • Ammonia)

By formula: I- + H3N = (I- • H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°31.0 ± 1.3kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
ΔrH°31. ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.0 ± 2.5kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B

(Iodide • 6Carbon dioxide) + Carbon dioxide = (Iodide • 7Carbon dioxide)

By formula: (I- • 6CO2) + CO2 = (I- • 7CO2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°7.95kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide • 7Carbon dioxide) + Carbon dioxide = (Iodide • 8Carbon dioxide)

By formula: (I- • 7CO2) + CO2 = (I- • 8CO2)

Quantity Value Units Method Reference Comment
ΔrH°13. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°7.95kJ/molN/AGomez, Taylor, et al., 2002gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B

(Iodide • Nitrous oxide) + Nitrous oxide = (Iodide • 2Nitrous oxide)

By formula: (I- • N2O) + N2O = (I- • 2N2O)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°14. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.4J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

(Iodide • 7Methyl Alcohol) + Methyl Alcohol = (Iodide • 8Methyl Alcohol)

By formula: (I- • 7CH4O) + CH4O = (I- • 8CH4O)

Quantity Value Units Method Reference Comment
ΔrH°38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°3. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Iodide • 3Acetonitrile) + Acetonitrile = (Iodide • 4Acetonitrile)

By formula: (I- • 3C2H3N) + C2H3N = (I- • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°32.6 ± 0.42kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°31.0 ± 3.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°80.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.4 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Iodide • 4Acetonitrile) + Acetonitrile = (Iodide • 5Acetonitrile)

By formula: (I- • 4C2H3N) + C2H3N = (I- • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°29.7 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
ΔrH°44.4 ± 3.8kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.9 ± 5.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Iodide + Nitrous oxide = (Iodide • Nitrous oxide)

By formula: I- + N2O = (I- • N2O)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B
ΔrH°16. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.0J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Iodide + Benzene = (Iodide • Benzene)

By formula: I- + C6H6 = (I- • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°26. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
ΔrH°38. ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°59.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

Iodide + Dimethyl Sulfoxide = (Iodide • Dimethyl Sulfoxide)

By formula: I- + C2H6OS = (I- • C2H6OS)

Quantity Value Units Method Reference Comment
ΔrH°65.69kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
ΔrH°67.kJ/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°38.5kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

Iodide = BrI2-

By formula: I- = BrI2-

Quantity Value Units Method Reference Comment
ΔrH°141.8 ± 0.96kJ/molPDisCrider, Harrison, et al., 2011gas phase; B
ΔrH°149.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; ΔS(EA)=4.5; B
Quantity Value Units Method Reference Comment
ΔrG°107.9kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF2-(q); ; ΔS(EA)=4.5; B

Iodide + Xenon = IXe-

By formula: I- + Xe = IXe-

Quantity Value Units Method Reference Comment
ΔrH°6.69kJ/molN/ALenzer, Furlanetto, et al., 1998gas phase; B
ΔrH°11.7kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
ΔrG°-8.24kJ/molTDAsWada, Kikkawa, et al., 2007gas phase; Entropy estimated; B

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr., Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase, Chem. Phys. Lett., 1980, 74, 139. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Piani, Becucci, et al., 2008
Piani, G.; Becucci, M.; Bowen, M.S.; Oakman, J.; Hu, Q.; Continetti, R.E., Photodetachment and dissociation dynamics of microsolvated iodide clusters, Phys. Scripta, 2008, 78, 5, 058110, https://doi.org/10.1088/0031-8949/78/05/058110 . [all data]

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of I-(CO2)n, Br-(CO2)n, and I-(N2O)n clusters by anion photoelectron spectroscopy, J. Chem. Phys., 1995, 102, 9, 3510, https://doi.org/10.1063/1.468576 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Gomez, Taylor, et al., 2002
Gomez, H.; Taylor, T.R.; Neumark, D.M., Anion photoelectron spectroscopy of I-2(-)(CO2)(n)(n=1-8) clusters, J. Chem. Phys., 2002, 116, 14, 6111-6117, https://doi.org/10.1063/1.1458246 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Yamdagni and Kebarle, 1972
Yamdagni, R.; Kebarle, P., Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules, J. Am. Chem. Soc., 1972, 94, 2940. [all data]

Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O., The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations., J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131 . [all data]

Dessent, Bailey, et al., 1995
Dessent, C.E.H.; Bailey, C.G.; Johnson, M.A., Dipole-bound excited states of the I-center dot CH3CN and I-center dot(CH3CN)2 ion-molecule complexes: Evidence for asymmetric solvation, J. Chem. Phys., 1995, 103, 6, 2006, https://doi.org/10.1063/1.469727 . [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P., Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements, J. Am. Chem. Soc., 1984, 106, 967. [all data]

Bogdanov, Peschke, et al., 1999
Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Van Duzor, Wei, et al., 2010
Van Duzor, M.; Wei, J.; Mbaiwa, F.; Mabbs, R., I-center dot CH3X (X=Cl, Br, I) photodetachment: The effect of electron-molecule interactions in cluster anion photodetachment spectra and angular distributions, J. Chem. Phys., 2010, 133, 14, 144303, https://doi.org/10.1063/1.3487739 . [all data]

Hiraoka, Fujita, et al., 1905
Hiraoka, K.; Fujita, K.; Ishida, M.; Ichikawa, T.; Okada, H.; Hiizumi, K.; Wada, A.; Takao, K.; Yamabe, S.; Tsuchida, N., Gas-phase Ion/Molecule Reactions in C5F8, J. Phys. Chem. A (2005), 1905, 109, 6, 1049-1056., https://doi.org/10.1021/jp040251k . [all data]

Arnold, Neumark, et al., 1995
Arnold, C.C.; Neumark, D.M.; Cyr, D.M.; Johnson, M.A., Negative ion zero electron kinetic energy spectroscopy of I-center dot CH3I, J. Phys. Chem., 1995, 99, 6, 1633, https://doi.org/10.1021/j100006a002 . [all data]

Cyr, Bishea, et al., 1992
Cyr, D.M.; Bishea, G.A.; Scarton, M.G.; Johnson, M.A., Observation of Charge-Transfer Excited States in the I-.CH3I, I-.CH3Br, and I-.CH2Br2 S(N)2 Reaction Intermediates Using Photofragmentation, J. Chem. Phys., 1992, 97, 8, 5911, https://doi.org/10.1063/1.463752 . [all data]

Dougherty and Roberts, 1974
Dougherty, R.C.; Roberts, J.D., SN2 reactions in the gas phase. Nucleophilicity effects, Org. Mass Spectrom., 1974, 8, 81. [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Taylor, Asmis, et al., 1999
Taylor, T.R.; Asmis, K.R.; Zanni, M.T.; Neumark, D.M., Characterization of the I-3 radical by anion photoelectron spectroscopy, J. Chem. Phys., 1999, 110, 16, 7607-7609, https://doi.org/10.1063/1.478672 . [all data]

Do, Klein, et al., 1997
Do, K.; Klein, T.P.; Pommerening, C.A.; Sunderlin, L.S., A New Flowing Afterglow-Guided Ion Beam Tandem Mass Spectrometer. Applications to the Thermochemistry of Polyiodide Ions, J. Am. Soc. Mass Spectrom., 1997, 8, 7, 688, https://doi.org/10.1016/S1044-0305(97)00116-5 . [all data]

Finch, Gates, et al., 1977
Finch, A.; Gates, P.N.; Peake, S.J., Thermochemistry of polyhalides. III. Cesium and rubidium tetrachloroiodates, J. Inorg. Nucl. Chem., 1977, 39, 2135. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-), Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316 . [all data]

Pelaez, Blondel, et al., 2009
Pelaez, R.J.; Blondel, C.; Delsart, C.; Drag, C., Pulsed photodetachment microscopy and the electron affinity of iodine, J. Phys. B: Atom. Mol. Opt. Phys., 2009, 42, 12, 125001, https://doi.org/10.1088/0953-4075/42/12/125001 . [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Walker and Sunderlin, 1999
Walker, B.W.; Sunderlin, L.S., The thermochemistry of formic acid halide anion clusters, Int. J. Mass Spectrom., 1999, 184, 2-3, 183-189, https://doi.org/10.1016/S1387-3806(99)00008-1 . [all data]

Evans, Keesee, et al., 1987
Evans, D.H.; Keesee, R.G.; Castleman Jr., The Association of Ammonia with Halide Ions in the Gas Phase, J. Chem. Phys., 1987, 86, 5, 2927, https://doi.org/10.1063/1.452043 . [all data]

Hiraoka, Mizuse, et al., 1988, 2
Hiraoka, K.; Mizuse, S.; Yamabe, S., Determination of the Stabilities and Structures of X-(C6H6) Clusters (X = Cl, Br, and I), Chem. Phys. Lett., 1988, 147, 2-3, 174, https://doi.org/10.1016/0009-2614(88)85078-4 . [all data]

Magnera, Caldwell, et al., 1984
Magnera, T.F.; Caldwell, G.; Sumner, J.; Ikuta, S.; Kebarle, P., Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents, J. Am. Chem. Soc., 1984, 106, 6140. [all data]

Crider, Harrison, et al., 2011
Crider, P.E.; Harrison, A.W.; Neumark, D.M., Two- and three-body photodissociation dynamics of diiodobromide (I2Br-) anion, J. Chem. Phys., 2011, 134, 13, 134306, https://doi.org/10.1063/1.3571474 . [all data]

Lenzer, Furlanetto, et al., 1998
Lenzer, T.; Furlanetto, M.R.; Asmis, K.R.; Neumark, D.M., Zero electron kinetic energy and photoelectron spectroscopy of the XeI- anion, J. Chem. Phys., 1998, 109, 24, 10754-10766, https://doi.org/10.1063/1.477774 . [all data]

Wada, Kikkawa, et al., 2007
Wada, A.; Kikkawa, A.; Sugiyama, T.; Hiraoka, K., Thermochemical Stabilities of the Gas-phase Cluster Ions of Halide Ions with Rare Gas Atoms, Int. J. Mass Spectrom.., 2007, 267, 1-3, 284-287, https://doi.org/10.1016/j.ijms.2007.02.053 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References

Copyright for NIST Standard Reference Data is governed by the Standard Reference Data Act.