Cyclotrisiloxane, hexaethyl-

• Formula: C₁₂H₃₀O₃Si₃
• Molecular weight: 306.6213
• IUPAC Standard InChI: InChI=1S/C12H30O3Si3/c1-7-16(8-2)13-17(9-3,10-4)15-18(11-5,12-6)14-16/h7-12H2,1-6H3 Copy

  
• IUPAC Standard InChIKey: KMPBCFZCRNKXSA-UHFFFAOYSA-N Copy
• CAS Registry Number: 2031-79-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Hexaethylcyclotrisiloxane; 1,1,3,3,5,5-Hexaethylcyclotrisiloxane
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• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Enthalpy of fusion

Enthalpy of phase transition

Entropy of phase transition

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Kulagina, et al., 1988
Lebedev, B.V.; Kulagina, T.G.; Smirnova, N.N., Thermodynamics of 4-methylcyclo-hexene, glycollide, and 1,1,3,3,5,5-hexaethylcyclotrisiloxane from 13.4 to 400 K, J. Chem. Thermodyn., 1988, 20, 1383-1396. [all data]

Dzhafarov and Kuliev, 1985
Dzhafarov, O.I.; Kuliev, A.M., Specific heat, phase transitions and thermodynamic properties of 1,1,3,3,5,5-hexaethylcyclotrisiloxane in the range 5-300 K, Zhur. Fiz. Khim., 1985, 59, 308-312. [all data]

Kulagina and Lebedev, 1982
Kulagina, T.G.; Lebedev, B.V., Thermodynamics of 2,2,4,4,6,6-hexaethylcyclotrisiloxane, its polymerization, and the resulting poly(diethylsiloxane) in the 0-330 K range, 1982, Termodin. [all data]

Lebedev, Kulagina, et al., 1988, 2
Lebedev, B.V.; Kulagina, T.G.; Smirnova, N.N., Thermodynamics of 4-methylcyclohexene, glycollide, and 1,1,3,3,5,5-hexaethylcyclotrisiloxane from 13.4 to 400 K, J. Chem. Thermodyn., 1988, 20, 1383. [all data]

Dzhafarov and Kuliev, 1985, 2
Dzhafarov, O.I.; Kuliev, A.M., Specific heat, phase transitions and thermodynamic properties of 1,1,3,3,5,5-hexaethylcyclotrisiloxane in the range 5-300 K, Zh. Fiz. Khim., 1985, 59, 308-12. [all data]

Lebedev, Kulagina, et al., 1984
Lebedev, B.V.; Kulagina, T.G.; Svistunov, V.S.; Papkov, V.S.; Zhdanov, A.A., Calorimetric study of 1,1,3,3,5,5-hexaethylcyclotrisiloxane and polydi-ethylsiloxane and the process of polymerization of 1,1,3,3,5,5-hexaethyl- cyclotrisiloxane in the range 13-330 K., Vysokomol. Soedin., Ser. A, 1984, 26, 2476-82. [all data]

Kulagina and Lebedev, 1982, 2
Kulagina, T.G.; Lebedev, B.V., Thermodynamics of 2,2,4,4,6,6-hexaethylcyclotrisiloxane, its polymerization and resulting poly(diethylsiloxane) in the 0-300 K range, Termodin. Org. Soedin., 1982, 1982, 18-26. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Jenkins and Chambers, 1954
Jenkins, Arthur C.; Chambers, George F., Vapor Pressures of Silicon Compounds, Ind. Eng. Chem., 1954, 46, 11, 2367-2369, https://doi.org/10.1021/ie50539a043 . [all data]

Domalski and Hearing, 1990
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase Volume II, J. Phys. Chem. Ref. Data, 1990, 19, 4, 881, https://doi.org/10.1063/1.555876 . [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Cp,liquid	Constant pressure heat capacity of liquid
  S°liquid	Entropy of liquid at standard conditions
  Ttriple	Triple point temperature
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔfusH	Enthalpy of fusion
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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