Silane, triethoxymethyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil414. to 416.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Δvap10.8 ± 0.2kcal/molCVoronkov, Baryshok, et al., 1988AC
Δvap10.8 ± 0.1kcal/molEBKlyuchnikov, Danilova, et al., 1985AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
10.8287.Stull, 1947Based on data from 272. to 416. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
271.7 to 416.74.577271712.654-42.26Stull, 1947Coefficents calculated by NIST from author's data.

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-5022
NIST MS number 230161

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon M160.772.Peetre, Ellren, et al., 1985Chromosorb G; Column length: 3. m

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApieson M160.772.Ellren, Peetre, et al., 1974Chromosorb G AW DMCS (80-100 mesh)

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Voronkov, Baryshok, et al., 1988
Voronkov, M.G.; Baryshok, V.P.; Klyuchnikov, V.A.; Danilova, T.F.; Pepekin, V.I.; Korchagina, A.N.; Khudobin, Yu.I., Thermochemistry of organosilicon compounds, Journal of Organometallic Chemistry, 1988, 345, 1-2, 27-38, https://doi.org/10.1016/0022-328X(88)80231-6 . [all data]

Klyuchnikov, Danilova, et al., 1985
Klyuchnikov, V.A.; Danilova, T.F.; Voronkov, M.G.; D'yakov, V.M., Dokl. Phys. Chem., 1985, 281, 373. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Peetre, Ellren, et al., 1985
Peetre, I.-B.; Ellren, O.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. VI. Determination, calculation and correlation of Kováts retention indices for alkylalkoxysilanes, J. Chromatogr., 1985, 318, 41-55, https://doi.org/10.1016/S0021-9673(01)90662-4 . [all data]

Ellren, Peetre, et al., 1974
Ellren, O.; Peetre, I.B.; Smith, B.E.F., Gas chromatographic investigation of organometallic compounds and their carbon analogues. V. Use of refractive index in conjunction with Kovats retention index for the identification of organosilicon compounds, J. Chromatogr., 1974, 93, 2, 383-392, https://doi.org/10.1016/S0021-9673(01)85402-9 . [all data]


Notes

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