N-Nitrobis-(2,2,2-trinitroethyl)amine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas21.42 ± 0.52kcal/molCcbPepekin, Gafurov, et al., 1973Reanalyzed by Cox and Pilcher, 1970, Original value = 21.6 ± 0.8 kcal/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-6.69 ± 0.41kcal/molCcbKustova, Kirpichev, et al., 1981 
Δfsolid-6.5kcal/molCcbPepekin, Gafurov, et al., 1973 
Quantity Value Units Method Reference Comment
Δcsolid-506.09kcal/molCcbKustova, Kirpichev, et al., 1981 
Δcsolid-506.3 ± 0.68kcal/molCcbPepekin, Gafurov, et al., 1973 
Δcsolid-486.0kcal/molCcbYoung, Keith, et al., 1956 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
28.1 ± 0.2348.MEde Kruif and Oonk, 1973Based on data from 340. to 356. K.; AC
28.1 ± 0.2340.VPepekin, Gafurov, et al., 1973ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pepekin, Gafurov, et al., 1973
Pepekin, V.I.; Gafurov, R.G.; Lebedev, Yu.A.; Eremenko, L.T.; Sogomonyan, E.M.; Apin, A.Ya., Thermochemistry of N-Nitrosoamines, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1973, 304-307. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Kustova, Kirpichev, et al., 1981
Kustova, L.V.; Kirpichev, E.P.; Rubtsov, Yu.I.; Avdonin, V.V.; Korepin, A.G.; Eremenko, L.T., Standard enthalpies of formation of certain nitro compounds, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981, 1830-1836. [all data]

Young, Keith, et al., 1956
Young, J.A.; Keith, J.E.; Stehle, P.; Dzombak, W.C.; Hunt, H., Heats of combustion of some organic nitrogen compounds, Ind. Eng. Chem., 1956, 48, 1375-1378. [all data]

de Kruif and Oonk, 1973
de Kruif, C.G.; Oonk, H.A.J., The determination of enthalpies of sublimation by means of thermal conductivity manometers, Chemie Ing. Techn., 1973, 45, 7, 455-461, https://doi.org/10.1002/cite.330450705 . [all data]


Notes

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