Decanenitrile

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-21.9 ± 0.43kcal/molCcrStridh, Sunner, et al., 1977Possible typo error corrected

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-37.86 ± 0.43kcal/molCcrStridh, Sunner, et al., 1977Possible typo error corrected
Quantity Value Units Method Reference Comment
Δcliquid-1551.6 ± 0.29kcal/molCcrStridh, Sunner, et al., 1977Possible typo error corrected

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil516.9KN/ADeffet, 1931Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus258.69KN/ADorinson and Ralston, 1944Uncertainty assigned by TRC = 0.3 K; TRC
Tfus258.69KN/AHoerr, Binkerd, et al., 1944Uncertainty assigned by TRC = 0.3 K; TRC
Tfus255.25KN/ADeffet, 1931Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δvap15.98kcal/molN/AMajer and Svoboda, 1985 
Δvap15.8 ± 0.1kcal/molGSEmel'yanenko, Verevkin, et al., 2005Based on data from 295. to 326. K.; AC
Δvap15.98 ± 0.088kcal/molCStridh, Sunner, et al., 1977Possible typo error corrected; ALS
Δvap16.0kcal/molN/AStridh, Sunner, et al., 1977DRB
Δvap16.0 ± 0.1kcal/molCStridh, Sunner, et al., 1977AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
13.9396.AStephenson and Malanowski, 1987Based on data from 381. to 519. K.; AC
13.8396.EBMeyer, Renner, et al., 1971Based on data from 381. to 431. K.; AC
13.0446.EBMeyer, Renner, et al., 1971Based on data from 431. to 518. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner SRD/NIST
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin EPA-IR VAPOR PHASE LIBRARY
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1994
NIST MS number 133239

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stridh, Sunner, et al., 1977
Stridh, G.; Sunner, S.; Svensson, C., Enthalpies of combustion, vaporization, and formation of some alkanenitriles, and the CH2-increment in the alkanenitrile series, J. Chem. Thermodyn., 1977, 9, 1005-1010. [all data]

Deffet, 1931
Deffet, L., The Freezing Points of Organic Compounds XIII. Compounds With Seven Eight, Nine or Ten Carbon Atoms, Bull. Soc. Chim. Belg., 1931, 40, 385-402. [all data]

Dorinson and Ralston, 1944
Dorinson, A.; Ralston, A.W., Refractive Indices of the Normal Saturated Aliphatic Nitriles. ammonia, J. Am. Chem. Soc., 1944, 66, 361. [all data]

Hoerr, Binkerd, et al., 1944
Hoerr, C.W.; Binkerd, E.F.; Pool, W.O.; Ralston, A.W., Solubilities of High-Molecular-Weight Normal Aliphatic Nitriles., J. Org. Chem., 1944, 9, 68-80. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Emel'yanenko, Verevkin, et al., 2005
Emel'yanenko, Vladimir N.; Verevkin, Sergey P.; Koutek, Bohumir; Doubsky, Jan, Vapour pressures and enthalpies of vapourization of a series of the linear aliphatic nitriles, The Journal of Chemical Thermodynamics, 2005, 37, 1, 73-81, https://doi.org/10.1016/j.jct.2004.08.004 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Meyer, Renner, et al., 1971
Meyer, Edwin F.; Renner, Terrence A.; Stec, Kenneth S., Cohesive energies in polar organic liquids. II. n-Alkane nitriles and the 1-chloro alkanes, J. Phys. Chem., 1971, 75, 5, 642-648, https://doi.org/10.1021/j100675a008 . [all data]


Notes

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