1,1'-Biphenyl, 2-(1-methylethyl)-
- Formula: C15H16
- Molecular weight: 196.2875
- IUPAC Standard InChI: InChI=1S/C15H16/c1-12(2)14-10-6-7-11-15(14)13-8-4-3-5-9-13/h3-12H,1-2H3
- IUPAC Standard InChIKey: HKTCLPBBJDIBGF-UHFFFAOYSA-N
- CAS Registry Number: 19486-60-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 1,1'-Biphenyl,2-isopropyl-
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔcH°liquid | -1885. | kcal/mol | Ccb | Goodman and Wise, 1950 | Corresponding ΔfHºliquid = -72. kcal/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 542.92 | K | N/A | Goodman and Wise, 1951 | Uncertainty assigned by TRC = 0.3 K |
| Tboil | 542.92 | K | N/A | Goodman and Wise, 1950, 2 | Uncertainty assigned by TRC = 0.15 K |
| Quantity | Value | Units | Method | Reference | Comment |
| Tfus | 297.61 | K | N/A | Goodman and Wise, 1951 | Uncertainty assigned by TRC = 0.1 K |
| Tfus | 297.61 | K | N/A | Goodman and Wise, 1950, 2 | Uncertainty assigned by TRC = 0.15 K |
Gas Chromatography
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | Apiezon L | 170. | 1500. | Kríz, Popl, et al., 1974 | |
| Packed | Apiezon L | 185. | 1512. | Kríz, Popl, et al., 1974 |
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | SP-1000 | 185. | 2015. | Kríz, Popl, et al., 1974 | N2; Column length: 50. m; Column diameter: 0.25 mm |
| Capillary | SP-1000 | 200. | 1980. | Kríz, Popl, et al., 1974 | N2; Column length: 50. m; Column diameter: 0.25 mm |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Goodman and Wise, 1950
Goodman, I.A.; Wise, P.H.,
Dicyclic hydrocarbons. I. 2-Aklylbiphenyls,
J. Am. Chem. Soc., 1950, 72, 3076-3078. [all data]
Goodman and Wise, 1951
Goodman, I.A.; Wise, P.H.,
Synthesis & purification of some alkylbiphenyls & alkylbicyclohexyls., Natl. Advis. Comm. Aeronaut., Tech. Note NACA TN 2260, Lewis Flight Propulsion Lab., Cleveland, Ohio, 1951. [all data]
Goodman and Wise, 1950, 2
Goodman, I.A.; Wise, P.H.,
Dicycloic Hydrocarbons I. 2-Alkylbiphenyls,
J. Am. Chem. Soc., 1950, 72, 3076. [all data]
Kríz, Popl, et al., 1974
Kríz, J.; Popl, M.; Mostecký, J.,
Retention indices of biphenyls and diphenylalkanes,
J. Chromatogr., 1974, 97, 1, 3-13, https://doi.org/10.1016/S0021-9673(01)97577-6
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔcH°liquid Enthalpy of combustion of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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