Tricosane, 2-methyl-
- Formula: C24H50
- Molecular weight: 338.6538
- IUPAC Standard InChIKey: JNHSEDRFFJZMLH-UHFFFAOYSA-N
- CAS Registry Number: 1928-30-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: 2-Methyltricosane
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Phase change data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 311.55 | K | N/A | Anonymous, 1968 | TRC |
Tfus | 311.6 | K | N/A | Anonymous, 1955 | Uncertainty assigned by TRC = 0.6 K; TRC |
Tfus | 310.9 | K | N/A | McKittrick, Henriques, et al., 1937 | Uncertainty assigned by TRC = 3. K; TRC |
Tfus | 311.4 | K | N/A | Strating, Backer, et al., 1936 | Uncertainty assigned by TRC = 1.5 K; TRC |
Tfus | 315. | K | N/A | Landa and Riedl, 1930 | Uncertainty assigned by TRC = 4. K; TRC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
21.3 | 465. | A | Stephenson and Malanowski, 1987 | Based on data from 450. to 664. K.; AC |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Dexsil 300 | 210. | 2361. | Szafranek, Kusmierz, et al., 1982 | He; Column length: 30. m; Column diameter: 0.30 mm |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Cross-Linked Methylsilicone | 2363. | Khorasheh, Gray, et al., 1989 | 5. K/min; Tstart: 40. C; Tend: 300. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5 | 2365. | Zaikin and Borisov, 2002 | He; Column length: 30. m; Column diameter: 0.25 mm; Program: 30C => 5K/min=120C => 10C/min => 270C |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-1 | 2365.0 | Krkosova, Kubinec, et al., 2007 | 100. m/0.32 mm/0.25 μm, Helium, 5. K/min, 310. C @ 5. min; Tstart: 30. C |
Capillary | DB-1 | 2364. | Katritzky, Chen, et al., 2000 | 30. m/0.32 mm/0.25 μm; Tstart: 60. C; Tend: 320. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Polydimethyl siloxane | 2364. | Junkes, Castanho, et al., 2003 | Program: not specified |
References
Go To: Top, Phase change data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Anonymous, 1968
Anonymous, R.,
Properties of hydrocarbon of high molecular weight, Am. Pet. Inst. Res. Proj. 42, Penn. State Univ., 1968. [all data]
Anonymous, 1955
Anonymous, R.,
, Am. Pet. Inst. Res. Proj. 45, Tech. Rep. 14, No. 1, Ohio State Univ., 1955. [all data]
McKittrick, Henriques, et al., 1937
McKittrick, D.S.; Henriques, H.J.; Wolff, H.T.,
J. Inst. Pet. Technol., 1937, 23, 630. [all data]
Strating, Backer, et al., 1936
Strating, J.; Backer, H.J.; Lolkema, J.; Benninga, N.,
Prep. of Several Crystalline Aliphatic Hydrocarbons in the Pure State,
Recl. Trav. Chim. Pays-Bas, 1936, 55, 903-14. [all data]
Landa and Riedl, 1930
Landa, S.; Riedl, R.,
Synthesis of some higher isoparaffins,
Collect. Czech. Chem. Commun., 1930, 2, 520. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Szafranek, Kusmierz, et al., 1982
Szafranek, J.; Kusmierz, J.; Czerwiec, W.,
Gas chromatographic-mass spectrometric investigations of high-boiling crude oil alkane fractions,
J. Chromatogr., 1982, 245, 2, 219-228, https://doi.org/10.1016/S0021-9673(00)88591-X
. [all data]
Khorasheh, Gray, et al., 1989
Khorasheh, F.; Gray, M.R.; Selucky, M.L.,
Correlation for Kováts retention index of C9-C26 monoalkyl and polymethyl alkanes and alkenes,
J. Chromatogr., 1989, 481, 1-16, https://doi.org/10.1016/S0021-9673(01)96747-0
. [all data]
Zaikin and Borisov, 2002
Zaikin, V.G.; Borisov, R.S.,
Chromatographic-mass spectrometric analysis of Fishcer-Tropsch synthesis products,
J. Anal. Chem. USSR (Engl. Transl.), 2002, 57, 6, 544-551. [all data]
Krkosova, Kubinec, et al., 2007
Krkosova, Z.; Kubinec, R.; Addova, G.; Jurdakova, H.; Blasko, J.; Ostrovsky, I.; Sojak, L.,
Gas chromatographic - mass spectrometric characterization of monomethylalkanes from fuel diesel,
Petroleum Coal, 2007, 49, 3, 51-62. [all data]
Katritzky, Chen, et al., 2000
Katritzky, A.R.; Chen, K.; Maran, U.; Carlson, D.A.,
QSPR Correlation and predictions of GC retention indexes for methyl-branched hydrocarbons produced by insects,
Anal. Chem., 2000, 72, 1, 101-109, https://doi.org/10.1021/ac990800w
. [all data]
Junkes, Castanho, et al., 2003
Junkes, B.S.; Castanho, R.D.M.; Amboni, C.; Yunes, R.A.; Heinzen, V.E.F.,
Semiempirical Topological Index: A Novel Molecular Descriptor for Quantitative Structure-Retention Relationship Studies,
Internet Electronic Journal of Molecular Design, 2003, 2, 1, 33-49. [all data]
Notes
Go To: Top, Phase change data, Gas Chromatography, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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