Pentadecane, 2,6,10,14-tetramethyl-
- Formula: C19H40
- Molecular weight: 268.5209
- IUPAC Standard InChIKey: XOJVVFBFDXDTEG-UHFFFAOYSA-N
- CAS Registry Number: 1921-70-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Bute hydrocarbon; Norphytan; Norphytane; Pristan; Pristane; 2,6,10,14-Tetramethylpentadecane; Norphytane, robuoy; 2,6,10,14-Tetramethylpentadecane (pristane); 2,6,10,10-tetramethylpentadecane
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference |
---|---|---|
569.76 | 298.15 | Trejo, Costas, et al., 1991 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 173.2 | K | N/A | Sorensen and Sorensen, 1949 | Uncertainty assigned by TRC = 10. K; TRC |
Reduced pressure boiling point
Tboil (K) | Pressure (bar) | Reference | Comment |
---|---|---|---|
439.2 | 0.015 | Weast and Grasselli, 1989 | BS |
Gas Chromatography
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | SE-30 | 200. | 1709. | Shlyakhov, 1984 | |
Capillary | n-Dotriacontane | 200. | 1697. | Shlyakhov, 1984 | |
Capillary | Apiezon L | 200. | 1682. | Shlyakhov, 1984 | |
Capillary | Apiezon L | 200. | 1687. | Shlyakhov, 1984 | |
Packed | Apiezon L | 200. | 1681.9 | Fisch, Olácsi, et al., 1980 | |
Packed | SE-30 | 150. | 1708. | Shlyakhov, Anvaer, et al., 1975 | |
Packed | SE-30 | 200. | 1709. | Shlyakhov, Anvaer, et al., 1975 | |
Packed | Apiezon L | 130. | 1687. | Shlyakhov, Anvaer, et al., 1975 | |
Packed | Apiezon L | 150. | 1687. | Shlyakhov, Anvaer, et al., 1975 | |
Capillary | SE-30 | 100. | 1709. | Shlyakhov, Koreshkova, et al., 1975 | |
Capillary | Apiezon L | 100. | 1687. | Shlyakhov, Koreshkova, et al., 1975 |
Kovats' RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | HP-5MS | 1707. | Kenig, Simons, et al., 2005 | 30. m/0.25 mm/0.25 μm, He; Program: 60C(1.5min) => 20C/min => 130C => 4C/min => 315C (90min) |
Capillary | Apiezon L | 1681. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1684. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1685. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1685. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1687. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1687. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1687. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1688. | Shlyakhov, 1984 | Program: not specified |
Capillary | Apiezon L | 1692. | Shlyakhov, 1984 | Program: not specified |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | CP-Sil 8CB-MS | 1703. | Elmore, Cooper, et al., 2005 | 0. m/0.25 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min, 280. C @ 5. min |
Capillary | Cross-Linked Methylsilicone | 1712. | Khorasheh, Gray, et al., 1989 | 5. K/min; Tstart: 40. C; Tend: 300. C |
Capillary | OV-1 | 1710. | Berthou and Friocourt, 1981 | 50. m/0.30 mm/0.15 μm, H2, 0.5 K/min; Tstart: 60. C; Tend: 280. C |
Capillary | OV-1 | 1708. | Berthou and Friocourt, 1981 | 50. m/0.30 mm/0.15 μm, H2, 0.5 K/min; Tstart: 60. C; Tend: 280. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | HP-5MS | 1703.7 | Andriamaharavo, 2014 | 30. m/0.25 mm/0.25 μm, He; Program: 60C (1 min) => 5 C/min => 210C => 10 C/min => 280C (15 min) |
Capillary | DB-5MS | 1703. | Turchini, Giani, et al., 2004 | 30. m/0.25 mm/0.25 μm, He; Program: 35C => 120C/min => 60C1.5C/min => 100C => 5C/min => 280C |
Capillary | CP-Sil 8CB-MS | 1702. | Elmore, Mottram, et al., 2000 | 60. m/0.25 mm/0.25 μm, He; Program: 0C(5min) => 40C/min => 40C (2min) => 4C/min => 280C |
Van Den Dool and Kratz RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-Wax | 1664. | Selli, Rannou, et al., 2006 | 30. m/0.25 mm/0.5 μm, He, 4. K/min, 260. C @ 5. min; Tstart: 50. C |
Capillary | Supelcowax-10 | 1669. | Chung, Yung, et al., 2001 | 60. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min |
Capillary | Supelcowax-10 | 1671. | Chung, 1999 | 60. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min |
Capillary | Supelcowax-10 | 1672. | Chung and Cadwallader, 1993 | 60. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 2. K/min, 195. C @ 40. min |
Capillary | Supelcowax-10 | 1670. | Tanchotikul and Hsieh, 1989 | 60. m/0.25 mm/0.25 μm, 40. C @ 5. min, 2. K/min, 175. C @ 20. min |
Capillary | Supelcowax-10 | 1672. | Tanchotikul and Hsieh, 1989 | 60. m/0.25 mm/0.25 μm, 40. C @ 5. min, 2. K/min, 175. C @ 20. min |
Van Den Dool and Kratz RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-Wax | 1655. | Pennarun, Prost, et al., 2002 | 30. m/0.32 mm/0.5 μm, He; Program: 50C => 6C/min => 70C => 4C/min => 150C => 10C/min => 250C |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-1 | 1712. | Hu, Liang, et al., 2010 | 30. m/0.25 mm/0.25 μm, Helium, 50. C @ 3. min, 5. K/min, 250. C @ 2. min |
Capillary | VF-5 | 1701. | Li and Zhao, 2009 | 30. m/0.25 mm/0.25 μm, Helium, 60. C @ 2. min, 10. K/min, 300. C @ 10. min |
Capillary | HP-101 | 1696. | Mastelic, Jerkovic, et al., 2006 | 25. m/0.2 mm/0.2 μm, He, 70. C @ 2. min, 3. K/min, 200. C @ 15. min |
Capillary | Ultra-2 | 1704. | King, Hamilton, et al., 1993 | 50. m/0.32 mm/0.52 μm, He, 40. C @ 3. min, 4. K/min, 250. C @ 30. min |
Capillary | Apieson L | 1685. | Albaigès, Borbón, et al., 1981 | He, Gas-Chrom Q, 6. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 120. C; Tend: 280. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | RTX-5 MS | 1649. | Nadaf, Halimi, et al., 2012 | 15. m/0.25 mm/0.25 μm, Helium; Program: 35 0C (6 min) 5 0C/min -> 150 0C 10 0C/min -> 280 0C (3 min) |
Capillary | RTX-5 MS | 1705. | Nadaf, Halimi, et al., 2012 | 15. m/0.25 mm/0.25 μm, Helium; Program: 35 0C (6 min) 5 0C/min -> 150 0C 10 0C/min -> 280 0C (3 min) |
Capillary | HP-5 | 1703. | Pugliese, Sirtori, et al., 2009 | 50. m/0.32 mm/1.05 μm, Helium; Program: not specified |
Capillary | 1710. | Cripps, 1995 | Program: not specified | |
Capillary | Squalane | 1684. | Petrov, 1984 | Program: not specified |
Capillary | Apiezon L | 1692. | Shlyakhov, 1984 | Program: not specified |
Capillary | OV-1 | 1709. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | OV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc. | 1709. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | Apiezon L | 1687. | Douglas, Blumer, et al., 1971 | Program: not specified |
Capillary | RTV-502 | 1712. | Blumer and Thomas, 1965 | Program: not specified |
Normal alkane RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-Wax | 1668. | Peng, Yang, et al., 1991 | Program: not specified |
Capillary | Superox 0.6; Carbowax 20M | 1664. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | Superox 0.6; Carbowax 20M | 1675. | Waggott and Davies, 1984 | Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified |
Capillary | Carbowax 20M | 1675. | Blumer and Thomas, 1965 | Program: not specified |
Lee's RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5MS | 283.84 | Chen, Keeran, et al., 2002 | 30. m/0.25 mm/0.5 μm, 40. C @ 1. min, 10. K/min; Tend: 310. C |
Capillary | DB-5MS | 288.01 | Chen, Keeran, et al., 2002 | 30. m/0.25 mm/0.5 μm, 40. C @ 1. min, 4. K/min; Tend: 310. C |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Trejo, Costas, et al., 1991
Trejo, L.M.; Costas, M.; Patterson, D.,
Excess heat capacity of organic mixtures, Internat. DATA Series,
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Gas chromatography in organic geochemistry, Nedra, Moscow, 1984, 221. [all data]
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Pyrolysis and gas chromatographic examination of phytol and isoprenoid hydrocarbons. Pre-calculation of retention indices by computer,
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On the possibility of group indentification of hydrocarbons by gas chromatography from temperature coefficients of retention indices,
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Gas Chromatography of Isoprenoid Alkanes,
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Correlation for Kováts retention index of C9-C26 monoalkyl and polymethyl alkanes and alkenes,
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Gas Chromatographic Separation of Diastereomeric Isoprenoids as Molecular Markers of Oil Pollution,
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Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Tboil Boiling point Tfus Fusion (melting) point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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