Sucrose, 8TMS derivative
- Formula: C36H86O11Si8
- Molecular weight: 919.7454
- IUPAC Standard InChI: InChI=1S/C36H86O11Si8/c1-48(2,3)37-25-28-30(43-51(10,11)12)32(45-53(16,17)18)33(46-54(19,20)21)35(40-28)42-36(27-39-50(7,8)9)34(47-55(22,23)24)31(44-52(13,14)15)29(41-36)26-38-49(4,5)6/h28-35H,25-27H2,1-24H3/t28-,29+,30-,31+,32+,33-,34-,35+,36-/m1/s1
- IUPAC Standard InChIKey: JDAONBLATRVCRV-JURUKNGCSA-N
- CAS Registry Number: 19159-25-2
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: α-D-Glucopyranoside, 1,3,4,6-tetrakis-O-(trimethylsilyl)-β-D-fructofuranosyl 2,3,4,6-tetrakis-O-(trimethylsilyl)-; Sucrose, octakis-O-(trimethylsilyl)-; Octa-O-(trimethylsilyl)sucrose; D(+)-Sucrose, TMS
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | WASHINGTON UNIVERSITY MEDICAL SCHOOL W.R. SHERMAN |
| NIST MS number | 24810 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5MS | 2712. | Medeiros and Simoneit, 2007 | 30. m/0.25 mm/0.25 μm, He, 65. C @ 2. min, 6. K/min, 300. C @ 15. min |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 2610.7 | Tretyakov, 2011 | 30. m/0.25 mm/0.25 μm, He; Tstart: 60. C; Tend: 270. C |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Medeiros and Simoneit, 2007
Medeiros, P.M.; Simoneit, B.R.T.,
Analysis of sugars in environmental samples by gas chromatography-mass spectrometry,
J. Chromatogr. A, 2007, 1141, 2, 271-278, https://doi.org/10.1016/j.chroma.2006.12.017
. [all data]
Tretyakov, 2011
Tretyakov, K.V.,
Retention Data (March 2011). NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
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