Potassium anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar154.58J/mol*KReviewChase, 1998Data last reviewed in December, 1983

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

K- + Hydrogen cation = potassium hydride

By formula: K- + H+ = HK

Quantity Value Units Method Reference Comment
Δr1439.840 ± 0.042kJ/molD-EAAndersson, Sandstrom, et al., 2000gas phase; Given: 0.501459(12) eV
Quantity Value Units Method Reference Comment
Δr1420.4 ± 1.3kJ/molH-TSAndersson, Sandstrom, et al., 2000gas phase; Given: 0.501459(12) eV

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity of neutral species

EAneutral (eV) Method Reference Comment
0.501463LPDAndersson, Sandstrom, et al., 2000Given: 0.501459(12) eV
0.501463 ± 0.000087LPDSlater, Read, et al., 1978 

Protonation reactions

K- + Hydrogen cation = potassium hydride

By formula: K- + H+ = HK

Quantity Value Units Method Reference Comment
Δr1439.840 ± 0.042kJ/molD-EAAndersson, Sandstrom, et al., 2000gas phase; Given: 0.501459(12) eV
Quantity Value Units Method Reference Comment
Δr1420.4 ± 1.3kJ/molH-TSAndersson, Sandstrom, et al., 2000gas phase; Given: 0.501459(12) eV

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Andersson, Sandstrom, et al., 2000
Andersson, K.T.; Sandstrom, J.; Kiyan, I.Y.; Hanstorp, D.; Pegg, D.J., Measurement of the electron affinity of potassium - art. no. 022503, Phys. Rev. A, 2000, 62, 2, 22503, https://doi.org/10.1103/PhysRevA.62.022503 . [all data]

Slater, Read, et al., 1978
Slater, J.; Read, F.H.; Novick, S.E.; Lineberger, W.C., Alkali Negative Ions. III. Multichannel Photodetachment of Cs- and K-, Phys. Rev. A, 1978, 17, 1, 201, https://doi.org/10.1103/PhysRevA.17.201 . [all data]


Notes

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