D-Fructose, 5TMS derivative
- Formula: C21H52O6Si5
- Molecular weight: 541.0615
- IUPAC Standard InChI: InChI=1S/C21H52O6Si5/c1-28(2,3)23-16-18(22)20(26-31(10,11)12)21(27-32(13,14)15)19(25-30(7,8)9)17-24-29(4,5)6/h19-21H,16-17H2,1-15H3/t19-,20-,21-/m1/s1
- IUPAC Standard InChIKey: LDUCAYFXHYLHLP-NJDAHSKKSA-N
- CAS Registry Number: 19126-98-8
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: D-Fructose, 1,3,4,5,6-pentakis-O-(trimethylsilyl)-; 1,3,4,5,6-Pentakis-O-(trimethylsilyl)fructose, (D)-; Fructose, acyclic, pentakis-TMS; D-Fructose, pentakis-TMS ether; Fructose, (5TMS); D-Fructose, penta-TMS; D-(-)-Fructose, pentakis(trimethylsilyl) ether; B-Fructopyranose, TMS; Fructose, acyclic, TMS; Fructose TMS; Fructose, TMS, # 1; Fructose, TMS, # 2; Fructose, pentakis-TMS; Fructose TMS #3; D-Fructose, TMS
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary |
|---|---|---|---|
| Active phase | OV-1 | SE-54 | SE-54 |
| Column length (m) | 25. | 40. | 40. |
| Carrier gas | |||
| Substrate | |||
| Column diameter (mm) | 0.22 | 0.18 | 0.18 |
| Phase thickness (μm) | |||
| Temperature (C) | 180. | 180. | 180. |
| I | 1867. | 1867. | 1875. |
| Reference | Garcia-Raso, Fernandez-Diaz, et al., 1989 | García-Raso, Martínez-Castro, et al., 1987 | García-Raso, Martínez-Castro, et al., 1987 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Garcia-Raso, Fernandez-Diaz, et al., 1989
Garcia-Raso, A.; Fernandez-Diaz, M.; Paez, M.I.; Sanz, J.; Martinez-Castro, I.,
Gas Chromatographic Retention of Carbohydrate Trimethylsilyl Ethers. III. Ketohexoses,
J. Chromatogr., 1989, 471, 205-216, https://doi.org/10.1016/S0021-9673(00)94168-2
. [all data]
García-Raso, Martínez-Castro, et al., 1987
García-Raso, A.; Martínez-Castro, I.; Páez, M.I.; Sanz, J.; García-Raso, J.; Saura-Calixto, F.,
Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. I. Aldopentoses,
J. Chromatogr., 1987, 398, 9-20, https://doi.org/10.1016/S0021-9673(01)96491-X
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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