Cyclodecasiloxane, eicosamethyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus270.KN/AAlvik and Dale, 1971Uncertainty assigned by TRC = 0.1 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
71.3495.AStephenson and Malanowski, 1987Based on data from 480. to 603. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
39.76265.8Alvik, Dale, et al., 1971AC

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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 161274

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryMethyl Silicone2029.Fujimoto, Ohtani, et al., 199025. m/0.25 mm/0.1 μm, He, 5. K/min; Tstart: 40. C; Tend: 350. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryUltra-12023.Kazuyoshi, Seiichi, et al., 200030. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min)
CapillaryUltra-12025.Kazuyoshi, Seiichi, et al., 200030. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min)
CapillaryUltra-12030.Kazuyoshi, Seiichi, et al., 200030. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min)
CapillaryUltra-12033.Kazuyoshi, Seiichi, et al., 200030. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min)
CapillaryUltra-12033.Kazuyoshi, Seiichi, et al., 200030. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min)
CapillaryUltra-12037.Kazuyoshi, Seiichi, et al., 200030. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Alvik and Dale, 1971
Alvik, T.; Dale, J., On the Lack of Conformational Preferences for Cyclic Dimethylsiloxane Oligomers., Acta Chem. Scand., 1971, 25, 2131, https://doi.org/10.3891/acta.chem.scand.25-2131 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Alvik, Dale, et al., 1971
Alvik, Thor; Dale, Johannes; Fernholt, L.; Hedberg, Kenneth; Schaumburg, Kjeld; Ehrenberg, L., On the Lack of Conformational Preferences for Cyclic Dimethylsiloxane Oligomers., Acta Chem. Scand., 1971, 25, 2131-2141, https://doi.org/10.3891/acta.chem.scand.25-2131 . [all data]

Fujimoto, Ohtani, et al., 1990
Fujimoto, S.; Ohtani, H.; Yamagiwa, K.; Tsuge, S., Study on retention behavior of cyclic siloxanes by high resolution pyrolysis-gas chromatography with a fused silica capillary column, J. Hi. Res. Chromatogr., 1990, 13, 6, 397-404, https://doi.org/10.1002/jhrc.1240130603 . [all data]

Kazuyoshi, Seiichi, et al., 2000
Kazuyoshi, N.; Seiichi, Y.; Kazuo, K.; Katsumi, I.; Okihiko, S., Polymer analysis by improved pyrolysis gas chromatography hyphenated with four specific detectors, J. Soc. Cosmet. Chem. Jpn., 2000, 34, 2, 142-151, https://doi.org/10.5107/sccj.34.142 . [all data]


Notes

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