Cyclodecasiloxane, eicosamethyl-
- Formula: C20H60O10Si10
- Molecular weight: 741.5394
- IUPAC Standard InChIKey: CDNNKGWZSNSADW-UHFFFAOYSA-N
- CAS Registry Number: 18772-36-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Eicosamethyl-cyclodecasiloxane
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Phase change data
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 270. | K | N/A | Alvik and Dale, 1971 | Uncertainty assigned by TRC = 0.1 K; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
71.3 | 495. | A | Stephenson and Malanowski, 1987 | Based on data from 480. to 603. K.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
39.76 | 265.8 | Alvik, Dale, et al., 1971 | AC |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Chemical Concepts |
NIST MS number | 161274 |
Gas Chromatography
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Methyl Silicone | 2029. | Fujimoto, Ohtani, et al., 1990 | 25. m/0.25 mm/0.1 μm, He, 5. K/min; Tstart: 40. C; Tend: 350. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Ultra-1 | 2023. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 2025. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 2030. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 2033. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 2033. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
Capillary | Ultra-1 | 2037. | Kazuyoshi, Seiichi, et al., 2000 | 30. m/0.25 mm/0.50 μm; Program: 40 0C (5 min) 10 0C/min -> 200 0C 20 0C/min -> 320 0C (13 min) |
References
Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Alvik and Dale, 1971
Alvik, T.; Dale, J.,
On the Lack of Conformational Preferences for Cyclic Dimethylsiloxane Oligomers.,
Acta Chem. Scand., 1971, 25, 2131, https://doi.org/10.3891/acta.chem.scand.25-2131
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Alvik, Dale, et al., 1971
Alvik, Thor; Dale, Johannes; Fernholt, L.; Hedberg, Kenneth; Schaumburg, Kjeld; Ehrenberg, L.,
On the Lack of Conformational Preferences for Cyclic Dimethylsiloxane Oligomers.,
Acta Chem. Scand., 1971, 25, 2131-2141, https://doi.org/10.3891/acta.chem.scand.25-2131
. [all data]
Fujimoto, Ohtani, et al., 1990
Fujimoto, S.; Ohtani, H.; Yamagiwa, K.; Tsuge, S.,
Study on retention behavior of cyclic siloxanes by high resolution pyrolysis-gas chromatography with a fused silica capillary column,
J. Hi. Res. Chromatogr., 1990, 13, 6, 397-404, https://doi.org/10.1002/jhrc.1240130603
. [all data]
Kazuyoshi, Seiichi, et al., 2000
Kazuyoshi, N.; Seiichi, Y.; Kazuo, K.; Katsumi, I.; Okihiko, S.,
Polymer analysis by improved pyrolysis gas chromatography hyphenated with four specific detectors,
J. Soc. Cosmet. Chem. Jpn., 2000, 34, 2, 142-151, https://doi.org/10.5107/sccj.34.142
. [all data]
Notes
Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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