Spiro[5.5]undec-2-ene, 3,7,7-trimethyl-11-methylene-, (-)-
- Formula: C15H24
- Molecular weight: 204.3511
- IUPAC Standard InChI: InChI=1S/C15H24/c1-12-7-10-15(11-8-12)13(2)6-5-9-14(15,3)4/h7H,2,5-6,8-11H2,1,3-4H3
- IUPAC Standard InChIKey: WLNGPDPILFYWKF-UHFFFAOYSA-N
- CAS Registry Number: 18431-82-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: β-Chamigrene; Chamigren; Chamigrene; Spiro[5.5]undec-2-ene, 3,7,7-trimethyl-11-methylene-, (R)-; (R)-3,7,7-Trimethyl-11-methylenespiro[5.5]undec-2-ene; 3,7,7-Trimethyl-11-methylenespiro[5.5]undec-2-ene
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | DB-5 MS | DB-5 MS | DB-1 | CP-Sil 5 CB |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | Helium | Helium | Nitrogen |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 60. | 50. | 50. |
| Tend (C) | 240. | 270. | 240. | 220. | 200. |
| Heat rate (K/min) | 3. | 3. | 3. | 4. | 5. |
| Initial hold (min) | 2. | ||||
| Final hold (min) | 2. | ||||
| I | 1475. | 1488. | 1475. | 1487. | 1500. |
| Reference | Rodriques, Amorim, et al., 2013 | Cui, Yang, et al., 2011 | Silva, Pott, et al., 2010 | Xu, Tang, et al., 2010 | Hnawia, Menut, et al., 2009 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | DB-5 MS | CP Sil 5 CB | DB-1 | DB-5 |
| Column length (m) | 30. | 30. | 25. | 30. | 30. |
| Carrier gas | Helium | Helium | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 50. | 50. | 80. | 50. | 60. |
| Tend (C) | 250. | 300. | 270. | 265. | 220. |
| Heat rate (K/min) | 5. | 5. | 10. | 2.5 | 4. |
| Initial hold (min) | 2. | 5. | 1. | ||
| Final hold (min) | 5. | 20. | |||
| I | 1478. | 1484. | 1474. | 1450. | 1479. |
| Reference | Ho, Wang, et al., 2009 | Noudogbessi, Yedomonhan, et al., 2008 | Ayoub, Al-Azizi, et al., 2006 | Iranshahi, Amin, et al., 2006 | Morteza-Semnani, Akbarzadeh, et al., 2006 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | HP-5 | DB-5 | DB-1 | CP Sil 5 CB |
| Column length (m) | 30. | 30. | 30. | 50. | 30. |
| Carrier gas | H2 | He | N2 | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 50. | 60. | 95. | 40. |
| Tend (C) | 265. | 280. | 210. | 240. | 220. |
| Heat rate (K/min) | 2.5 | 4. | 3. | 4. | 4. |
| Initial hold (min) | 0.5 | 2. | 5. | 1. | |
| Final hold (min) | 10. | ||||
| I | 1474. | 1475. | 1473. | 1470. | 1478. |
| Reference | Nickavar B., Kamalinejad M., et al., 2006 | Pino, Sauri-Duch, et al., 2006 | Askari and Sefidkon, 2005 | Palá-Paúl, Pérez-Alonso, et al., 2005 | Rohloff and Bones, 2005 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | CP Sil 5 CB | HP-5 | HP-5 | HP-5MS | DB-5MS |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | He | Helium | Helium | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.32 | 0.32 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 40. | 40. | 40. | 50. | 60. |
| Tend (C) | 220. | 300. | 300. | 230. | 240. |
| Heat rate (K/min) | 4. | 4. | 4. | 5. | 3. |
| Initial hold (min) | 1. | 2. | |||
| Final hold (min) | 5. | 5. | 10. | ||
| I | 1478. | 1466. | 1477. | 1482. | 1477. |
| Reference | Rohloff and Bones, 2005 | Utsunomia, Kawata, et al., 2005 | Utsunomia, Kawata, et al., 2005 | Li and Jiang, 2004 | paz Lima, Silva, et al., 2004 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | DB-5 | DB-5 | DB-5 | DB-5 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.25 | 0.249 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 70. | 60. | 60. | 35. | 60. |
| Tend (C) | 210. | 240. | 300. | 280. | 240. |
| Heat rate (K/min) | 2. | 3. | 3. | 4. | 3. |
| Initial hold (min) | 2. | ||||
| Final hold (min) | 60. | 5. | 15. | ||
| I | 1474. | 1477. | 1475. | 1486. | 1475. |
| Reference | Mookdasanit, Tamura, et al., 2003 | da Silva, Luz, et al., 2003 | Bos, Koulman, et al., 2002 | Krauze-Baranowska, Mardarowicz, et al., 2002 | Zoghbi, Andrade, et al., 2002 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | SPB-5 | OV-101 | DB-1 | DB-5MS | OV-101 |
| Column length (m) | 60. | 50. | 25. | 30. | 50. |
| Carrier gas | He | Nitrogen | He | He | N2 |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | |||
| Tstart (C) | 40. | 40. | 50. | 60. | 80. |
| Tend (C) | 220. | 200. | 290. | 240. | 200. |
| Heat rate (K/min) | 3. | 2. | 4. | 3. | 2. |
| Initial hold (min) | 5. | 10. | |||
| Final hold (min) | 15. | ||||
| I | 1478. | 1495. | 1475. | 1481. | 1495. |
| Reference | Cornu, Carnat, et al., 2001 | Tamura, Boonbumrung, et al., 2000 | Koulman, 1999 | Zoghbi, Andrade, et al., 1999 | Sugisawa, Yang, et al., 1989 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary |
|---|---|
| Active phase | OV-101 |
| Column length (m) | 50. |
| Carrier gas | N2 |
| Substrate | |
| Column diameter (mm) | 0.25 |
| Phase thickness (μm) | |
| Tstart (C) | 80. |
| Tend (C) | 200. |
| Heat rate (K/min) | 2. |
| Initial hold (min) | |
| Final hold (min) | |
| I | 1495. |
| Reference | Sugisawa, Yang, et al., 1989 |
| Comment | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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