Spiro[5.5]undecane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas-188.3 ± 3.1kJ/molCcbSubach and Zwolinski, 1975ALS
Δfgas-191.8kJ/molN/AKozin, Mirzaeva, et al., 1964Value computed using ΔfHliquid° value of -248.0±2.0 kj/mol from Kozin, Mirzaeva, et al., 1964 and ΔvapH° value of 56.2 kj/mol from Subach and Zwolinski, 1975.; DRB

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-244.5 ± 3.0kJ/molCcbSubach and Zwolinski, 1975 
Δfliquid-248. ± 2.kJ/molCcbKozin, Mirzaeva, et al., 1964 
Quantity Value Units Method Reference Comment
Δcliquid-6942.4 ± 2.8kJ/molCcbSubach and Zwolinski, 1975Corresponding Δfliquid = -244.5 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-6939. ± 2.kJ/molCcbKozin, Mirzaeva, et al., 1964Corresponding Δfliquid = -248. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus248.65KN/AAnonymous, 1968Uncertainty assigned by TRC = 0.5 K; TRC
Tfus248.7KN/AHogenboon, Webb, et al., 1967Uncertainty assigned by TRC = 0.5 K; TRC
Tfus248.7KN/ANaro, 1960Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Δvap56.1 ± 0.1kJ/molVSubach and Zwolinski, 1975ALS
Δvap56.2kJ/molN/ASubach and Zwolinski, 1975DRB
Δvap56.1kJ/molCSubach and Zwolinski, 1975AC
Quantity Value Units Method Reference Comment
Δsub63.6 ± 0.8kJ/molCParker, Steele, et al., 1975See also Pedley and Rylance, 1977.; AC

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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 4794

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Subach and Zwolinski, 1975
Subach, D.J.; Zwolinski, B.J., Enthalpies of combustion, formation, and vaporization of spiro[4,5]decane, spiro[5,5]undecane, and 7-n-Hexadecylspiro[4,5]decane, J. Chem. Eng. Data, 1975, 20, 232-235. [all data]

Kozin, Mirzaeva, et al., 1964
Kozin, M.P.; Mirzaeva, A.K.; Sosina, I.E.; Elagina, N.V.; Skuratov, S.M., The heats of formation of spiro hydrocarbons, Dokl. Phys. Chem. (Engl. Transl.), 1964, 155, 375-377. [all data]

Anonymous, 1968
Anonymous, R., Properties of hydrocarbon of high molecular weight, Am. Pet. Inst. Res. Proj. 42, Penn. State Univ., 1968. [all data]

Hogenboon, Webb, et al., 1967
Hogenboon, D.L.; Webb, W.; Dixon, J.A., J. Chem. Phys., 1967, 46, 2586. [all data]

Naro, 1960
Naro, P.A., , PhD Thesis, 1960. [all data]

Parker, Steele, et al., 1975
Parker, W.; Steele, W.V.; Stirling, W.; Watt, I., A high-precision aneroid static-bomb combustion calorimeter for samples of about 20 mg. The standard enthalpy of formation of bicyclo[3.3.3]undecane, J. Chem. Thermodyn., 1975, 7, 795-802. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References