4-Pyrimidinamine, N-(trimethylsilyl)-2-[(trimethylsilyl)oxy]-


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
NIST MS number 332817

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Gas Chromatography

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedOV-101160.1509.6Miller, Pacáková, et al., 1976Ar, AW-DMCS Chromosorb W HP; Column length: 2. m
PackedSE-30150.1546.Pacakova, Miller, et al., 1971 
PackedOV-101150.1500.Pacakova, Miller, et al., 1971 

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
PackedOV-11504.Yamaji, Kimura, et al., 1978Gas Chrom Q; Column length: 1. m; Program: not specified
PackedOV-11502.Yamaji, Kimura, et al., 1978Gas Chrom Q; Column length: 1. m; Program: not specified
PackedOV-11504.Yamaji, Kimura, et al., 1978Gas Chrom Q; Column length: 1. m; Program: not specified
PackedOV-11504.Yamaji, Kimura, et al., 1978Gas Chrom Q; Column length: 1. m; Program: not specified
PackedOV-11504.Yamaji, Kimura, et al., 1978Gas Chrom Q; Column length: 1. m; Program: not specified
PackedOV-11504.Yamaji, Kimura, et al., 1978Gas Chrom Q; Column length: 1. m; Program: not specified
PackedOV-11505.Yamaji, Kimura, et al., 1978Gas Chrom Q; Column length: 1. m; Program: not specified

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
PackedOV-11512.Butts, 1972He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; Tstart: 100. C; Tend: 325. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryVF-5MS1518.9Tret'yakov, 200730. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C
PackedSE-301518.Butts, 1970He, Chromosorb W; Column length: 2. m; Program: not specified

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Pacáková, et al., 1976
Miller, V.; Pacáková, V.; Smolková, E., Gas-liquid chromatographic analysis of trimethylsilyl derivatives of pyrimidine and purine bases and nucleosides, J. Chromatogr., 1976, 119, 355-367, https://doi.org/10.1016/S0021-9673(00)86799-0 . [all data]

Pacakova, Miller, et al., 1971
Pacakova, V.; Miller, V.; Cernohorsky, I.J., Gas-Liquid Chromatography of Some Pyrimidine Derivatives, Anal. Biochemistry, 1971, 42, 2, 549-554, https://doi.org/10.1016/0003-2697(71)90071-6 . [all data]

Yamaji, Kimura, et al., 1978
Yamaji, A.; Kimura, S.; Kawasaki, H.; Yuki, H., Gas chromatographic analysis of pyrimidine and purine bases by retention indices, Yakugaku Zasshi, 1978, 98, 1, 1536-1541. [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]

Tret'yakov, 2007
Tret'yakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]

Butts, 1970
Butts, W.C., Gas chromatographic separation of trimethylsilyl (TMS)-nucleosides: TMS-methoxime derivatives of cytidine and deoxycytidine, J. Chromatogr. Sci., 1970, 8, 8, 474-476, https://doi.org/10.1093/chromsci/8.8.474 . [all data]


Notes

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