9H-Purin-6-ol, 2TMS derivative
- Formula: C11H20N4OSi2
- Molecular weight: 280.4737
- IUPAC Standard InChI: InChI=1S/C11H20N4OSi2/c1-17(2,3)15-8-14-9-10(15)12-7-13-11(9)16-18(4,5)6/h7-8H,1-6H3
- IUPAC Standard InChIKey: GQQMYRBRLIEVPC-UHFFFAOYSA-N
- CAS Registry Number: 17962-89-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 9H-Purine, 9-(trimethylsilyl)-6-[(trimethylsilyl)oxy]-; 9H-Purine, 6-(trimethylsiloxy)-9-(trimethylsilyl)-; O6,9-Bis(trimethylsilyl)hypoxanthine; Hypoxanthine di-TMS; 9-(Trimethylsilyl)-6-[(trimethylsilyl)oxy]-9H-purine; Hypoxanthine, bis-TMS; Hypoxanthine, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | OV-101 | 160. | 1798. | Miller, Pacáková, et al., 1976 | Ar, AW-DMCS Chromosorb W HP; Column length: 2. m |
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | OV-1 | 1793. | Yamaji, Kimura, et al., 1978 | Gas Chrom Q; Column length: 1. m; Program: not specified |
| Packed | OV-1 | 1796. | Yamaji, Kimura, et al., 1978 | Gas Chrom Q; Column length: 1. m; Program: not specified |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | OV-1 | 1794. | Butts, 1972 | He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; Tstart: 100. C; Tend: 325. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1812.2 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
| Capillary | VF-5MS | 1809.6 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
| Packed | SE-30 | 1792. | Butts, 1970 | He, Chromosorb W; Column length: 2. m; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Miller, Pacáková, et al., 1976
Miller, V.; Pacáková, V.; Smolková, E.,
Gas-liquid chromatographic analysis of trimethylsilyl derivatives of pyrimidine and purine bases and nucleosides,
J. Chromatogr., 1976, 119, 355-367, https://doi.org/10.1016/S0021-9673(00)86799-0
. [all data]
Yamaji, Kimura, et al., 1978
Yamaji, A.; Kimura, S.; Kawasaki, H.; Yuki, H.,
Gas chromatographic analysis of pyrimidine and purine bases by retention indices,
Yakugaku Zasshi, 1978, 98, 1, 1536-1541. [all data]
Butts, 1972
Butts, W.C.,
Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds,
Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3
. [all data]
Tret'yakov, 2007
Tret'yakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2007. [all data]
Butts, 1970
Butts, W.C.,
Gas chromatographic separation of trimethylsilyl (TMS)-nucleosides: TMS-methoxime derivatives of cytidine and deoxycytidine,
J. Chromatogr. Sci., 1970, 8, 8, 474-476, https://doi.org/10.1093/chromsci/8.8.474
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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