Borane, tris(1-methylethyl)-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference
40.0273. to 393.BGBamford, Levi, et al., 1946

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + Borane, tris(1-methylethyl)- = (Fluorine anion • Borane, tris(1-methylethyl)-)

By formula: F- + C9H21B = (F- • C9H21B)

Quantity Value Units Method Reference Comment
Δr272.0kJ/molIMRBMurphy and Beauchamp, 1977gas phase; Fluoride Affinity: iPr2BF > iPr3B > Et2BF > Et3B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., 91. Physical and chemical properties of organo-metallic compounds. Part I. The vapour pressures and freezing points of simple metal alkyls of Groups II, III, and V, J. Chem. Soc., 1946, 468, https://doi.org/10.1039/jr9460000468 . [all data]

Murphy and Beauchamp, 1977
Murphy, M.K.; Beauchamp, J.L., Fluorine and Alkyl Substituent Effects on Gas-Phase Lewis Acidities of Boranes by ICR Spectroscopy, Inorg. Chem., 1977, 16, 2437. [all data]


Notes

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