Methanesulfinic acid


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH3O2S- + Hydrogen cation = Methanesulfinic acid

By formula: CH3O2S- + H+ = CH4O2S

Quantity Value Units Method Reference Comment
Δr327.7 ± 5.3kcal/molG+TSSorensengas phase; Between CF2HCO2H and CF3CO2H.
Quantity Value Units Method Reference Comment
Δr320.6 ± 5.2kcal/molIMRBSorensengas phase; Between CF2HCO2H and CF3CO2H.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

CH3O2S- + Hydrogen cation = Methanesulfinic acid

By formula: CH3O2S- + H+ = CH4O2S

Quantity Value Units Method Reference Comment
Δr327.7 ± 5.3kcal/molG+TSSorensengas phase; Between CF2HCO2H and CF3CO2H.
Quantity Value Units Method Reference Comment
Δr320.6 ± 5.2kcal/molIMRBSorensengas phase; Between CF2HCO2H and CF3CO2H.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sorensen
Sorensen, D., , Thesis, Univ. of Tennessee. [all data]


Notes

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