Copper ion (1+)

• Formula: Cu⁺
• Molecular weight: 63.545
• IUPAC Standard InChI: InChI=1S/Cu/q+1 Copy

  
• IUPAC Standard InChIKey: VMQMZMRVKUZKQL-UHFFFAOYSA-N Copy
• CAS Registry Number: 17493-86-6
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Copper cation
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Ion clustering data
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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = ( • )

By formula: Cu⁺ + H₂O = (Cu⁺ • H₂O)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Cu⁺ • H₂O) + H₂O = (Cu⁺ • 2H₂O)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Cu⁺ • C₃H₆O) + C₃H₆O = (Cu⁺ • 2C₃H₆O)

 +  = ( • )

By formula: Cu⁺ + C₃H₆O = (Cu⁺ • C₃H₆O)

( • ) +  = ( • 2)

By formula: (Cu⁺ • CH₄O) + CH₄O = (Cu⁺ • 2CH₄O)

 +  = ( • )

By formula: Cu⁺ + CH₄O = (Cu⁺ • CH₄O)

( • 2) +  = ( • 3)

By formula: (Cu⁺ • 2H₂O) + H₂O = (Cu⁺ • 3H₂O)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Cu⁺ • 3H₂O) + H₂O = (Cu⁺ • 4H₂O)

Enthalpy of reaction

 +  = ( • )

By formula: Cu⁺ + N₂ = (Cu⁺ • N₂)

( • 2) +  = ( • 3)

By formula: (Cu⁺ • 2H₃N) + H₃N = (Cu⁺ • 3H₃N)

( • 3) +  = ( • 4)

By formula: (Cu⁺ • 3H₃N) + H₃N = (Cu⁺ • 4H₃N)

 +  = ( • )

By formula: Cu⁺ + Kr = (Cu⁺ • Kr)

 +  = ( • )

By formula: Cu⁺ + C₂H₄ = (Cu⁺ • C₂H₄)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Cu⁺ • C₆H₆) + C₆H₆ = (Cu⁺ • 2C₆H₆)

Enthalpy of reaction

 +  = ( • )

By formula: Cu⁺ + C₆H₆ = (Cu⁺ • C₆H₆)

Enthalpy of reaction

( • 4) +  = ( • 5)

By formula: (Cu⁺ • 4H₃N) + H₃N = (Cu⁺ • 5H₃N)

( • 4) +  = ( • 5)

By formula: (Cu⁺ • 4H₂O) + H₂O = (Cu⁺ • 5H₂O)

( • ) +  = ( • 2)

By formula: (Cu⁺ • N₂) + N₂ = (Cu⁺ • 2N₂)

( • 2) +  = ( • 3)

By formula: (Cu⁺ • 2CO) + CO = (Cu⁺ • 3CO)

Enthalpy of reaction

( • 3) +  = ( • 4)

By formula: (Cu⁺ • 3CO) + CO = (Cu⁺ • 4CO)

Enthalpy of reaction

( • ) +  = ( • 2)

By formula: (Cu⁺ • CO) + CO = (Cu⁺ • 2CO)

Enthalpy of reaction

 +  = ( • )

By formula: Cu⁺ + C₂H₂ = (Cu⁺ • C₂H₂)

Enthalpy of reaction

( • 2) +  = ( • 3)

By formula: (Cu⁺ • 2N₂) + N₂ = (Cu⁺ • 3N₂)

 +  = ( • )

By formula: Cu⁺ + CO = (Cu⁺ • CO)

Enthalpy of reaction

 +  = ( • )

By formula: Cu⁺ + C₂H₃N = (Cu⁺ • C₂H₃N)

( • ) +  = ( • 2)

By formula: (Cu⁺ • H₃N) + H₃N = (Cu⁺ • 2H₃N)

( • 2) +  = ( • 3)

By formula: (Cu⁺ • 2C₂H₆O) + C₂H₆O = (Cu⁺ • 3C₂H₆O)

( • 3) +  = ( • 4)

By formula: (Cu⁺ • 3C₂H₆O) + C₂H₆O = (Cu⁺ • 4C₂H₆O)

( • ) +  = ( • 2)

By formula: (Cu⁺ • C₂H₄) + C₂H₄ = (Cu⁺ • 2C₂H₄)

( • ) +  = ( • 2)

By formula: (Cu⁺ • C₂H₆O) + C₂H₆O = (Cu⁺ • 2C₂H₆O)

( • 2) +  = ( • 3)

By formula: (Cu⁺ • 2C₂H₃N) + C₂H₃N = (Cu⁺ • 3C₂H₃N)

( • 3) +  = ( • 4)

By formula: (Cu⁺ • 3C₂H₃N) + C₂H₃N = (Cu⁺ • 4C₂H₃N)

( • 4) +  = ( • 5)

By formula: (Cu⁺ • 4C₂H₃N) + C₂H₃N = (Cu⁺ • 5C₂H₃N)

( • ) +  = ( • 2)

By formula: (Cu⁺ • C₄H₁₀O₂) + C₄H₁₀O₂ = (Cu⁺ • 2C₄H₁₀O₂)

( • ) +  = ( • 2)

By formula: (Cu⁺ • C₂H₃N) + C₂H₃N = (Cu⁺ • 2C₂H₃N)

( • 2) +  = ( • 3)

By formula: (Cu⁺ • 2C₃H₆O) + C₃H₆O = (Cu⁺ • 3C₃H₆O)

( • 3) +  = ( • 4)

By formula: (Cu⁺ • 3C₃H₆O) + C₃H₆O = (Cu⁺ • 4C₃H₆O)

( • ) +  = ( • 2)

By formula: (Cu⁺ • C₄H₅N) + C₄H₅N = (Cu⁺ • 2C₄H₅N)

 +  = ( • )

By formula: Cu⁺ + CH₃ = (Cu⁺ • CH₃)

 +  = ( • )

By formula: Cu⁺ + H₃N = (Cu⁺ • H₃N)

 +  = ( • )

By formula: Cu⁺ + C₅H₅N = (Cu⁺ • C₅H₅N)

 +  = ( • )

By formula: Cu⁺ + CS = (Cu⁺ • CS)

 +  = ( • )

By formula: Cu⁺ + C₄H₄N₂ = (Cu⁺ • C₄H₄N₂)

 +  = ( • )

By formula: Cu⁺ + C₅H₅N₅ = (Cu⁺ • C₅H₅N₅)

 +  = ( • )

By formula: Cu⁺ + C₂H₆O = (Cu⁺ • C₂H₆O)

 +  = ( • )

By formula: Cu⁺ + C₄H₁₀O₂ = (Cu⁺ • C₄H₁₀O₂)

 +  = ( • )

By formula: Cu⁺ + C₄H₅N = (Cu⁺ • C₄H₅N)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

El-Shall, Schriver, et al., 1989
El-Shall, M.S.; Schriver, K.E.; Whetten, R.L.; Meot-Ner (Mautner), M., Ion/Molecule Clustering Thermochemistry by Laser Ionization High - Pressure Mass Spectrometry, J. Phys. Chem., 1989, 93, 24, 7969, https://doi.org/10.1021/j100361a002 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Magnera, David, et al., 1989, 2
Magnera, T.F.; David, D.E.; Stulik, D.; Orth, R.G.; Jorikman, H.T.; Michl, J., Production of Hydrated Metal Ions by Fast Ion or Atom Beam Sputtering. Collision - Induced Dissociation and Successive Hydration Energies of Gaseous Cu+ with 1 - 4 Water Molecules, J. Am. Chem. Soc., 1989, 111, 14, 5036, https://doi.org/10.1021/ja00196a003 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Chu, 2002
Chu, Y., Solvation of Copper Ions by Acetone. Structures and Sequential Binding Energies of Cu+(acetone)x, x=1-4 From Collision-Induced Dissociation and Theoretical Studies, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 453, https://doi.org/10.1016/S1044-0305(02)00355-0 . [all data]

Holland and Castleman, 1982
Holland, P.M.; Castleman, A.W., The Thermochemical Properties of Gas - Phase Transition Metal Ion Complexes, J. Chem. Phys., 1982, 76, 8, 4195, https://doi.org/10.1063/1.443497 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Meyer, Chen, et al., 1995
Meyer, F.; Chen, Y.M.; Armentrout, P.B., Sequential Bond Energies of Cu(CO)x+ and Ag(CO)x+ (x = 1-4), J. Am. Chem. Soc., 1995, 117, 14, 4071, https://doi.org/10.1021/ja00119a023 . [all data]

Vitale, 2001
Vitale, G., Solvation of Copper Ions by Acetonitrile. Structures and Sequential Binding Energies of Cu+(CH3CN)x, x=1-5 From Collision-Induced Dissociation and Theoretical Studies, J. Phys. Chem. A, 2001, 105, 50, 11351, https://doi.org/10.1021/jp0132432 . [all data]

Koizumi, 2001
Koizumi, H., Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethyl Ether Complexes, J.Phys. Chem. A, 2001, 105, 11, 2444, https://doi.org/10.1021/jp003509p . [all data]

Koizumi, 2001, 2
Koizumi, H., Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethoxyethane Complexes, J. Am. Soc. Mass Spectrom., 2001, 12, 5, 480, https://doi.org/10.1016/S1044-0305(01)00242-2 . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B., Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane, J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016 . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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