Sodium ion (1+)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(Sodium ion (1+) • 3Water) + Water = (Sodium ion (1+) • 4Water)

By formula: (Na+ • 3H2O) + H2O = (Na+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 0.9kcal/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°24. ± 3.cal/mol*KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrG°6.1kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
13.1 (+1.4,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.6293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
6.4300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • Water) + Water = (Sodium ion (1+) • 2Water)

By formula: (Na+ • H2O) + H2O = (Na+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 2.kcal/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°22.2cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
19.6 (+1.4,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.0300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 2Water) + Water = (Sodium ion (1+) • 3Water)

By formula: (Na+ • 2H2O) + H2O = (Na+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°14.9kcal/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°15.8kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°16.7 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°16.1kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrH°16. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°20.8cal/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°21.9cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°22.0cal/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrS°23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°9.5kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.8 (+1.4,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
9.4300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Sodium ion (1+) + Water = (Sodium ion (1+) • Water)

By formula: Na+ + H2O = (Na+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°24.0kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°21.0 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°19.6 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°22.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°26.5kcal/molMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M
Quantity Value Units Method Reference Comment
ΔrS°21.5cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°22.cal/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.6 (+1.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
15.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • 4Water) + Water = (Sodium ion (1+) • 5Water)

By formula: (Na+ • 4H2O) + H2O = (Na+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°10.7kcal/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°11.6kcal/molHPMSTang and Castleman, 1972gas phase; M
ΔrH°12.3kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.9cal/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°26.5cal/mol*KHPMSTang and Castleman, 1972gas phase; M
ΔrS°28.1cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.7293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Sodium ion (1+) • Carbon dioxide) + Water = (Sodium ion (1+) • Water • Carbon dioxide)

By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°20.7kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrH°22.9kcal/molFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M
Quantity Value Units Method Reference Comment
ΔrS°25.3cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrS°25.6cal/mol*KFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M

(Sodium ion (1+) • Ammonia) + Ammonia = (Sodium ion (1+) • 2Ammonia)

By formula: (Na+ • H3N) + H3N = (Na+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°22. ± 1.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°25.1cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • Benzene) + Benzene = (Sodium ion (1+) • 2Benzene)

By formula: (Na+ • C6H6) + C6H6 = (Na+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 1.kcal/molAVGN/AAverage of 7 values; Individual data points

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points

Sodium ion (1+) + Acetone = (Sodium ion (1+) • Acetone)

By formula: Na+ + C3H6O = (Na+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°31.2 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°30.8 ± 0.5kcal/molHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrH°24.4kcal/molCIDTKlassen, Anderson, et al., 1996RCD
ΔrH°33.4 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21000.cal/mol*KHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrS°26.1cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
24.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Methyl Alcohol = (Sodium ion (1+) • Methyl Alcohol)

By formula: Na+ + CH4O = (Na+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°23.2 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.9 ± 1.4kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°24.0 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°26.6 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20500.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°24.3cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Ammonia = (Sodium ion (1+) • Ammonia)

By formula: Na+ + H3N = (Na+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°24.4 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°24.4 ± 1.3kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°25.6 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°29.1kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21800.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°25.7cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
18.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Benzene = (Sodium ion (1+) • Benzene)

By formula: Na+ + C6H6 = (Na+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°22.8 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.1 ± 1.2kcal/molCIDTAmicangelo and Armentrout, 2000RCD
ΔrH°21.1 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°28.0kcal/molHPMSGuo, Purnell, et al., 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°31.2cal/mol*KHPMSGuo, Purnell, et al., 1990gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
15.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • Ethane, 1,2-dimethoxy-)

By formula: Na+ + C4H10O2 = (Na+ • C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°37.8 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000glyme; RCD
ΔrH°57.6 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°38.5 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD
ΔrH°47.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°34.6cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
31.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°24.0 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.9 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°22.0 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°22.2 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
17.6298.CIDCMcMahon and Ohanessian, 2000RCD

(Sodium ion (1+) • 2Water • Carbon dioxide) + Water = (Sodium ion (1+) • 3Water • Carbon dioxide)

By formula: (Na+ • 2H2O • CO2) + H2O = (Na+ • 3H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°12.4kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°23.cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrG°5.5kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 2Methyl Alcohol)

By formula: (Na+ • CH4O) + CH4O = (Na+ • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°20.5 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.4 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°20.5 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°20.2 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.7cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 3Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • 3Water)

By formula: (Na+ • 3H2O) + CO2 = (Na+ • CO2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°7.2kcal/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°-0.3kcal/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • 3Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 4Sulfur dioxide)

By formula: (Na+ • 3O2S) + O2S = (Na+ • 4O2S)

Quantity Value Units Method Reference Comment
ΔrH°12.3kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°27.cal/mol*KN/ACastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.2328.HPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • 3Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 4Carbon dioxide)

By formula: (Na+ • 3CO2) + CO2 = (Na+ • 4CO2)

Quantity Value Units Method Reference Comment
ΔrH°8.4kcal/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.7310.HPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

Sodium ion (1+) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide)

By formula: Na+ + CO2 = (Na+ • CO2)

Quantity Value Units Method Reference Comment
ΔrH°15.9kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrH°13.7kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.1cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrS°19.8cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.6310.DTKeller and Beyer, 1971gas phase; low E/N; M

Sodium ion (1+) + Ethanol = (Sodium ion (1+) • Ethanol)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°26.3 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°24.4 ± 0.9kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°24.4 ± 0.9kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + Methylamine = (Sodium ion (1+) • Methylamine)

By formula: Na+ + CH5N = (Na+ • CH5N)

Quantity Value Units Method Reference Comment
ΔrH°26.3 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°32.1kcal/molHPMSGuo and Castleman, 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22600.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°30.3cal/mol*KHPMSGuo and Castleman, 1990gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide)

By formula: Na+ + O2S = (Na+ • O2S)

Quantity Value Units Method Reference Comment
ΔrH°18.9kcal/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°20.3cal/mol*KN/APerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°12.8kcal/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M

Sodium ion (1+) + Krypton = (Sodium ion (1+) • Krypton)

By formula: Na+ + Kr = (Na+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°4.84kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°5.08kcal/molIMobViehland, 1984gas phase; M
ΔrH°5.8kcal/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°6.57kcal/molIMobTakebe, 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.5cal/mol*KDTMcKnight and Sawina, 1973gas phase; M

(Sodium ion (1+) • Ethanol) + Ethanol = (Sodium ion (1+) • 2Ethanol)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°23.7 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°23.1 ± 1.1kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°23.7 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°23.3 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD

Sodium ion (1+) + Argon = (Sodium ion (1+) • Argon)

By formula: Na+ + Ar = (Na+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°3.7 ± 2.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°3.70kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°4.39kcal/molIMobViehland, 1984gas phase; M
ΔrH°4.4kcal/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°4.87kcal/molIMobTakebe, 1983gas phase; M

(Sodium ion (1+) • 4Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 5Acetonitrile)

By formula: (Na+ • 4C2H3N) + C2H3N = (Na+ • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°12.6 ± 0.8kcal/molCIDTValina, 2001CH3CN is fifth ligand; RCD
ΔrH°12.7kcal/molHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°41.2cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°8.0kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.6cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.2310.FAPerry, Rowe, et al., 1980gas phase; M
2.0310.DTBeyer and Keller, 1971gas phase; low E/N; M

(Sodium ion (1+) • Water • Carbon dioxide) + Water = (Sodium ion (1+) • 2Water • Carbon dioxide)

By formula: (Na+ • H2O • CO2) + H2O = (Na+ • 2H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°17.4kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°23.6cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

Sodium ion (1+) + Isopropyl Alcohol = (Sodium ion (1+) • Isopropyl Alcohol)

By formula: Na+ + C3H8O = (Na+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°27.0 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°27.1 ± 1.1kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
20.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

(Sodium ion (1+) • Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • 2Ethane, 1,2-dimethoxy-)

By formula: (Na+ • C4H10O2) + C4H10O2 = (Na+ • 2C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°27.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°27.2 ± 2.0kcal/molCIDTMore, Ray, et al., 1997RCD
ΔrH°35.1kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°40.5cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • Carbon monoxide) + Carbon monoxide = (Sodium ion (1+) • 2Carbon monoxide)

By formula: (Na+ • CO) + CO = (Na+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°5.7 ± 0.7kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°5.7 ± 0.7kcal/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°7.5kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°15.1cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + helium = (Sodium ion (1+) • helium)

By formula: Na+ + He = (Na+ • He)

Quantity Value Units Method Reference Comment
ΔrH°1.19kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°0.79kcal/molIMobViehland, 1984gas phase; M
ΔrH°0.93kcal/molIMobMason and Sharp, 1958gas phase; M
ΔrH°1.38kcal/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + Carbon monoxide = (Sodium ion (1+) • Carbon monoxide)

By formula: Na+ + CO = (Na+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°7.6 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°7.6 ± 1.9kcal/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°12.6kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.4cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + 1,4,7,10,13,16-Hexaoxacyclooctadecane = (Sodium ion (1+) • 1,4,7,10,13,16-Hexaoxacyclooctadecane)

By formula: Na+ + C12H24O6 = (Na+ • C12H24O6)

Quantity Value Units Method Reference Comment
ΔrH°70.7 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°71.7 ± 4.5kcal/molCIDTMore, Ray, et al., 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD
0.0298.CIDTMore, Ray, et al., 1999RCD

(Sodium ion (1+) • Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 2Carbon dioxide)

By formula: (Na+ • CO2) + CO2 = (Na+ • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°11.0kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.7cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.8310.DTKeller and Beyer, 1971gas phase; low E/N; M

Sodium ion (1+) + Ethyl ether = (Sodium ion (1+) • Ethyl ether)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°31.0 ± 0.3kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.2cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
21.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Hydrogen) + Hydrogen = (Sodium ion (1+) • 2Hydrogen)

By formula: (Na+ • H2) + H2 = (Na+ • 2H2)

Quantity Value Units Method Reference Comment
ΔrH°2.41kcal/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.25 kcal/mol; M
Quantity Value Units Method Reference Comment
ΔrS°12.4cal/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.25 kcal/mol; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°5.3kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°16.8cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
-0.3310.FAPerry, Rowe, et al., 1980gas phase; M

Sodium ion (1+) + Hydrogen = (Sodium ion (1+) • Hydrogen)

By formula: Na+ + H2 = (Na+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°2.93kcal/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.45 kcal/mol; M
Quantity Value Units Method Reference Comment
ΔrS°13.2cal/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.45 kcal/mol; M

Sodium ion (1+) + Phenol = (Sodium ion (1+) • Phenol)

By formula: Na+ + C6H6O = (Na+ • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°24.4 ± 0.8kcal/molCIDTAmunugama and Rodgers, 2002RCD
ΔrH°23.5 ± 0.8kcal/molCIDTArmentrout and Rodgers, 2000RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
16.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 2-Propanol, 2-methyl- = (Sodium ion (1+) • 2-Propanol, 2-methyl-)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°28.0 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°27.8 ± 1.0kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
21.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • 2Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 3Acetonitrile)

By formula: (Na+ • 2C2H3N) + C2H3N = (Na+ • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°21.2 ± 0.7kcal/molCIDTValina, 2001RCD
ΔrH°20.6kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.5cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 3Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 4Acetonitrile)

By formula: (Na+ • 3C2H3N) + C2H3N = (Na+ • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°15.4 ± 0.6kcal/molCIDTValina, 2001RCD
ΔrH°14.9kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.9cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 2Acetonitrile)

By formula: (Na+ • C2H3N) + C2H3N = (Na+ • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°26.1 ± 1.9kcal/molCIDTValina, 2001RCD
ΔrH°24.4kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.7cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

Sodium ion (1+) + Glycine = (Sodium ion (1+) • Glycine)

By formula: Na+ + C2H5NO2 = (Na+ • C2H5NO2)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 1.9kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD
ΔrH°39.2 ± 1.4kcal/molCIDTMoision and Armentrout, 2002RCD
ΔrH°36.6kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Xenon = (Sodium ion (1+) • Xenon)

By formula: Na+ + Xe = (Na+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°5.97kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°5.94kcal/molIMobViehland, 1984gas phase; M
ΔrH°9.52kcal/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + N-Glycylglycine = (Sodium ion (1+) • N-Glycylglycine)

By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)

Quantity Value Units Method Reference Comment
ΔrH°42.3 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998See amide; RCD
ΔrH°42.9kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
34.20.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + neon = (Sodium ion (1+) • neon)

By formula: Na+ + Ne = (Na+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°1.76kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°1.52kcal/molIMobViehland, 1984gas phase; M
ΔrH°1.45kcal/molIMobTakebe, 1983gas phase; M

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Sodium ion (1+) + Argon = (Sodium ion (1+) • Argon)

By formula: Na+ + Ar = (Na+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°3.7 ± 2.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°3.70kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°4.39kcal/molIMobViehland, 1984gas phase; M
ΔrH°4.4kcal/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°4.87kcal/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + 2H-Tetrazole = (Sodium ion (1+) • 2H-Tetrazole)

By formula: Na+ + CH2N4 = (Na+ • CH2N4)

Quantity Value Units Method Reference Comment
ΔrH°27.5 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + Methyl Alcohol = (Sodium ion (1+) • Methyl Alcohol)

By formula: Na+ + CH4O = (Na+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°23.2 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.9 ± 1.4kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°24.0 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°26.6 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20500.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°24.3cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 2Methyl Alcohol)

By formula: (Na+ • CH4O) + CH4O = (Na+ • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°20.5 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.4 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°20.5 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°20.2 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.7cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 2Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 3Methyl Alcohol)

By formula: (Na+ • 2CH4O) + CH4O = (Na+ • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°17.4 ± 0.4kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°25.1cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 3Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 4Methyl Alcohol)

By formula: (Na+ • 3CH4O) + CH4O = (Na+ • 4CH4O)

Quantity Value Units Method Reference Comment
ΔrH°15.7 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°30.0cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Sodium ion (1+) + Methane = (Sodium ion (1+) • Methane)

By formula: Na+ + CH4 = (Na+ • CH4)

Quantity Value Units Method Reference Comment
ΔrH°7.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°14.1cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + Methylamine = (Sodium ion (1+) • Methylamine)

By formula: Na+ + CH5N = (Na+ • CH5N)

Quantity Value Units Method Reference Comment
ΔrH°26.3 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°32.1kcal/molHPMSGuo and Castleman, 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22600.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°30.3cal/mol*KHPMSGuo and Castleman, 1990gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Carbon monoxide = (Sodium ion (1+) • Carbon monoxide)

By formula: Na+ + CO = (Na+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°7.6 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°7.6 ± 1.9kcal/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°12.6kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.4cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • Carbon monoxide) + Carbon monoxide = (Sodium ion (1+) • 2Carbon monoxide)

By formula: (Na+ • CO) + CO = (Na+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°5.7 ± 0.7kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°5.7 ± 0.7kcal/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°7.5kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°15.1cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide)

By formula: Na+ + CO2 = (Na+ • CO2)

Quantity Value Units Method Reference Comment
ΔrH°15.9kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrH°13.7kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.1cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrS°19.8cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.6310.DTKeller and Beyer, 1971gas phase; low E/N; M

(Sodium ion (1+) • Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 2Carbon dioxide)

By formula: (Na+ • CO2) + CO2 = (Na+ • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°11.0kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.7cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.8310.DTKeller and Beyer, 1971gas phase; low E/N; M

(Sodium ion (1+) • 2Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 3Carbon dioxide)

By formula: (Na+ • 2CO2) + CO2 = (Na+ • 3CO2)

Quantity Value Units Method Reference Comment
ΔrH°9.7kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.0cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Sodium ion (1+) • 3Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 4Carbon dioxide)

By formula: (Na+ • 3CO2) + CO2 = (Na+ • 4CO2)

Quantity Value Units Method Reference Comment
ΔrH°8.4kcal/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.7310.HPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • Carbon dioxide) + Water = (Sodium ion (1+) • Water • Carbon dioxide)

By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°20.7kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrH°22.9kcal/molFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M
Quantity Value Units Method Reference Comment
ΔrS°25.3cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrS°25.6cal/mol*KFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M

Sodium ion (1+) + Acetonitrile = (Sodium ion (1+) • Acetonitrile)

By formula: Na+ + C2H3N = (Na+ • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°30.5 ± 1.1kcal/molCIDTValina, 2001RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
23.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 2Acetonitrile)

By formula: (Na+ • C2H3N) + C2H3N = (Na+ • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°26.1 ± 1.9kcal/molCIDTValina, 2001RCD
ΔrH°24.4kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.7cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 2Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 3Acetonitrile)

By formula: (Na+ • 2C2H3N) + C2H3N = (Na+ • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°21.2 ± 0.7kcal/molCIDTValina, 2001RCD
ΔrH°20.6kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.5cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 3Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 4Acetonitrile)

By formula: (Na+ • 3C2H3N) + C2H3N = (Na+ • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°15.4 ± 0.6kcal/molCIDTValina, 2001RCD
ΔrH°14.9kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.9cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 4Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 5Acetonitrile)

By formula: (Na+ • 4C2H3N) + C2H3N = (Na+ • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°12.6 ± 0.8kcal/molCIDTValina, 2001CH3CN is fifth ligand; RCD
ΔrH°12.7kcal/molHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°41.2cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M

Sodium ion (1+) + C2H3N3 = (Sodium ion (1+) • C2H3N3)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°22.9 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + 1H-1,2,3-Triazole = (Sodium ion (1+) • 1H-1,2,3-Triazole)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°22.9 ± 1.1kcal/molCIDTRodgers and Armentrout, 1999, 2RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 1999, 2RCD

Sodium ion (1+) + 1H-1,2,4-Triazole = (Sodium ion (1+) • 1H-1,2,4-Triazole)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°29.6 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + 4H-1,2,4-triazole = (Sodium ion (1+) • 4H-1,2,4-triazole)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°29.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 1999, 2RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 1999, 2RCD

Sodium ion (1+) + Acetaldehyde = (Sodium ion (1+) • Acetaldehyde)

By formula: Na+ + C2H4O = (Na+ • C2H4O)

Quantity Value Units Method Reference Comment
ΔrH°27.1 ± 0.8kcal/molCIDTArmentrout and Rodgers, 2000RCD

Sodium ion (1+) + Ethylene = (Sodium ion (1+) • Ethylene)

By formula: Na+ + C2H4 = (Na+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°10.3 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD

Sodium ion (1+) + Ethanol, 2-fluoro- = (Sodium ion (1+) • Ethanol, 2-fluoro-)

By formula: Na+ + C2H5FO = (Na+ • C2H5FO)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
23.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Acetamide = (Sodium ion (1+) • Acetamide)

By formula: Na+ + C2H5NO = (Na+ • C2H5NO)

Quantity Value Units Method Reference Comment
ΔrH°34.7kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Glycine = (Sodium ion (1+) • Glycine)

By formula: Na+ + C2H5NO2 = (Na+ • C2H5NO2)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 1.9kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD
ΔrH°39.2 ± 1.4kcal/molCIDTMoision and Armentrout, 2002RCD
ΔrH°36.6kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Acetamide, 2-amino- = (Sodium ion (1+) • Acetamide, 2-amino-)

By formula: Na+ + C2H6N2O = (Na+ • C2H6N2O)

Quantity Value Units Method Reference Comment
ΔrH°41.4kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Dimethyl Sulfoxide = (Sodium ion (1+) • Dimethyl Sulfoxide)

By formula: Na+ + C2H6OS = (Na+ • C2H6OS)

Quantity Value Units Method Reference Comment
ΔrH°31.1kcal/molCIDKlassen, Anderson, et al., 1996RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
31.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Ethanol = (Sodium ion (1+) • Ethanol)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°26.3 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°24.4 ± 0.9kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°24.4 ± 0.9kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

(Sodium ion (1+) • Ethanol) + Ethanol = (Sodium ion (1+) • 2Ethanol)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°23.7 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°23.1 ± 1.1kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°23.7 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°23.3 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°24.0 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.9 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°22.0 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°22.2 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
17.6298.CIDCMcMahon and Ohanessian, 2000RCD

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points

(Sodium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 3Dimethyl ether)

By formula: (Na+ • 2C2H6O) + C2H6O = (Na+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°16.0 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

(Sodium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 4Dimethyl ether)

By formula: (Na+ • 3C2H6O) + C2H6O = (Na+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°14.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°13.9 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD

Sodium ion (1+) + Dimethyl sulfide = (Sodium ion (1+) • Dimethyl sulfide)

By formula: Na+ + C2H6S = (Na+ • C2H6S)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
14.2298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Monoethanolamine = (Sodium ion (1+) • Monoethanolamine)

By formula: Na+ + C2H7NO = (Na+ • C2H7NO)

Quantity Value Units Method Reference Comment
ΔrH°41.8 ± 1.7kcal/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + Dimethylamine = (Sodium ion (1+) • Dimethylamine)

By formula: Na+ + C2H7N = (Na+ • C2H7N)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1,3,5-Triazine = (Sodium ion (1+) • 1,3,5-Triazine)

By formula: Na+ + C3H3N3 = (Na+ • C3H3N3)

Quantity Value Units Method Reference Comment
ΔrH°21.1 ± 0.7kcal/molCIDTAmunugama and Rodgers, 2000RCD

Sodium ion (1+) + 1H-Pyrazole = (Sodium ion (1+) • 1H-Pyrazole)

By formula: Na+ + C3H4N2 = (Na+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°30.6 ± 2.2kcal/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + 1H-Imidazole = (Sodium ion (1+) • 1H-Imidazole)

By formula: Na+ + C3H4N2 = (Na+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°33.4 ± 1.2kcal/molCIDTHuang and Rodgers, 2002RCD
ΔrH°33.4 ± 1.3kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°33.4 ± 1.2kcal/molCIDTRodgers and Armentrout, 1999, 2RCD

Sodium ion (1+) + Propanenitrile = (Sodium ion (1+) • Propanenitrile)

By formula: Na+ + C3H5N = (Na+ • C3H5N)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
24.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Acetone = (Sodium ion (1+) • Acetone)

By formula: Na+ + C3H6O = (Na+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°31.2 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°30.8 ± 0.5kcal/molHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrH°24.4kcal/molCIDTKlassen, Anderson, et al., 1996RCD
ΔrH°33.4 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21000.cal/mol*KHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrS°26.1cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
24.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Acetone) + Acetone = (Sodium ion (1+) • 2Acetone)

By formula: (Na+ • C3H6O) + C3H6O = (Na+ • 2C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°25.2 ± 0.1kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.6cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 2Acetone) + Acetone = (Sodium ion (1+) • 3Acetone)

By formula: (Na+ • 2C3H6O) + C3H6O = (Na+ • 3C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°20.7 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°30.0cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 3Acetone) + Acetone = (Sodium ion (1+) • 4Acetone)

By formula: (Na+ • 3C3H6O) + C3H6O = (Na+ • 4C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°14.7 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.3cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Sodium ion (1+) + Propanoic acid = (Sodium ion (1+) • Propanoic acid)

By formula: Na+ + C3H6O2 = (Na+ • C3H6O2)

Quantity Value Units Method Reference Comment
ΔrH°28.2 ± 1.4kcal/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + Acetic acid, methyl ester = (Sodium ion (1+) • Acetic acid, methyl ester)

By formula: Na+ + C3H6O2 = (Na+ • C3H6O2)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
23.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Formamide, N,N-dimethyl- = (Sodium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Na+ + C3H7NO = (Na+ • C3H7NO)

Quantity Value Units Method Reference Comment
ΔrH°37.4 ± 0.9kcal/molCIDTArmentrout and Rodgers, 2000See 96KLA/AND?; RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
30.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Acetamide, N-methyl- = (Sodium ion (1+) • Acetamide, N-methyl-)

By formula: Na+ + C3H7NO = (Na+ • C3H7NO)

Quantity Value Units Method Reference Comment
ΔrH°35.7kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + dl-Cysteine = (Sodium ion (1+) • dl-Cysteine)

By formula: Na+ + C3H7NO2S = (Na+ • C3H7NO2S)

Quantity Value Units Method Reference Comment
ΔrH°42.8 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.2; RCD
ΔrH°41.8kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Alanine = (Sodium ion (1+) • Alanine)

By formula: Na+ + C3H7NO2 = (Na+ • C3H7NO2)

Quantity Value Units Method Reference Comment
ΔrH°40.4 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.0; RCD
ΔrH°39.9kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + dl-Serine = (Sodium ion (1+) • dl-Serine)

By formula: Na+ + C3H7NO3 = (Na+ • C3H7NO3)

Quantity Value Units Method Reference Comment
ΔrH°44.9 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.4; RCD
ΔrH°45.9kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Isopropyl Alcohol = (Sodium ion (1+) • Isopropyl Alcohol)

By formula: Na+ + C3H8O = (Na+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°27.0 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°27.1 ± 1.1kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
20.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + 1-Propanol = (Sodium ion (1+) • 1-Propanol)

By formula: Na+ + C3H8O = (Na+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°25.8 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°25.8 ± 1.0kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + Methylamine, N,N-dimethyl- = (Sodium ion (1+) • Methylamine, N,N-dimethyl-)

By formula: Na+ + C3H9N = (Na+ • C3H9N)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Propylamine = (Sodium ion (1+) • Propylamine)

By formula: Na+ + C3H9N = (Na+ • C3H9N)

Quantity Value Units Method Reference Comment
ΔrH°28.9 ± 1.4kcal/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + Uracil = (Sodium ion (1+) • Uracil)

By formula: Na+ + C4H4N2O2 = (Na+ • C4H4N2O2)

Quantity Value Units Method Reference Comment
ΔrH°32.2 ± 0.8kcal/molCIDTRodgers and Armentrout, 2000, 2RCD
ΔrH°33.7kcal/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + Pyrazine = (Sodium ion (1+) • Pyrazine)

By formula: Na+ + C4H4N2 = (Na+ • C4H4N2)

Quantity Value Units Method Reference Comment
ΔrH°25.7 ± 0.8kcal/molCIDTAmunugama and Rodgers, 2000RCD

Sodium ion (1+) + Furan = (Sodium ion (1+) • Furan)

By formula: Na+ + C4H4O = (Na+ • C4H4O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
11.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Pyrrole = (Sodium ion (1+) • Pyrrole)

By formula: Na+ + C4H5N = (Na+ • C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°24.3 ± 1.1kcal/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + Cytosine = (Sodium ion (1+) • Cytosine)

By formula: Na+ + C4H5N3O = (Na+ • C4H5N3O)

Quantity Value Units Method Reference Comment
ΔrH°42.3kcal/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + 2,5-Piperazinedione = (Sodium ion (1+) • 2,5-Piperazinedione)

By formula: Na+ + C4H6N2O2 = (Na+ • C4H6N2O2)

Quantity Value Units Method Reference Comment
ΔrH°34.2 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + 1H-Imidazole, 1-methyl- = (Sodium ion (1+) • 1H-Imidazole, 1-methyl-)

By formula: Na+ + C4H6N2 = (Na+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°38.4 ± 1.2kcal/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + 1H-Pyrazole, 1-methyl- = (Sodium ion (1+) • 1H-Pyrazole, 1-methyl-)

By formula: Na+ + C4H6N2 = (Na+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°31.4 ± 0.7kcal/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + Acetic anhydride = (Sodium ion (1+) • Acetic anhydride)

By formula: Na+ + C4H6O3 = (Na+ • C4H6O3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
31.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1,3-Butadiene = (Sodium ion (1+) • 1,3-Butadiene)

By formula: Na+ + C4H6 = (Na+ • C4H6)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Glycine, N-acetyl- = (Sodium ion (1+) • Glycine, N-acetyl-)

By formula: Na+ + C4H7NO3 = (Na+ • C4H7NO3)

Quantity Value Units Method Reference Comment
ΔrH°41.1 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
30.80.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + dl-Aspartic acid = (Sodium ion (1+) • dl-Aspartic acid)

By formula: Na+ + C4H7NO4 = (Na+ • C4H7NO4)

Quantity Value Units Method Reference Comment
ΔrH°48.5kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Butanediamide = (Sodium ion (1+) • Butanediamide)

By formula: Na+ + C4H8N2O2 = (Na+ • C4H8N2O2)

Quantity Value Units Method Reference Comment
ΔrH°44.5kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + L-Asparagine = (Sodium ion (1+) • L-Asparagine)

By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)

Quantity Value Units Method Reference Comment
ΔrH°49.2kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + N-Glycylglycine = (Sodium ion (1+) • N-Glycylglycine)

By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)

Quantity Value Units Method Reference Comment
ΔrH°42.3 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998See amide; RCD
ΔrH°42.9kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
34.20.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + 2-Butanone = (Sodium ion (1+) • 2-Butanone)

By formula: Na+ + C4H8O = (Na+ • C4H8O)

Quantity Value Units Method Reference Comment
ΔrH°31.3 ± 1.7kcal/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + 1,4-Dioxane = (Sodium ion (1+) • 1,4-Dioxane)

By formula: Na+ + C4H8O2 = (Na+ • C4H8O2)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
24.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1-Propene, 2-methyl- = (Sodium ion (1+) • 1-Propene, 2-methyl-)

By formula: Na+ + C4H8 = (Na+ • C4H8)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Butane, 1-bromo- = (Sodium ion (1+) • Butane, 1-bromo-)

By formula: Na+ + C4H9Br = (Na+ • C4H9Br)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
12.2298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Propane, 2-bromo-2-methyl- = (Sodium ion (1+) • Propane, 2-bromo-2-methyl-)

By formula: Na+ + C4H9Br = (Na+ • C4H9Br)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
13.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Propane, 2-chloro-2-methyl- = (Sodium ion (1+) • Propane, 2-chloro-2-methyl-)

By formula: Na+ + C4H9Cl = (Na+ • C4H9Cl)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
13.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + N,N-Dimethylacetamide = (Sodium ion (1+) • N,N-Dimethylacetamide)

By formula: Na+ + C4H9NO = (Na+ • C4H9NO)

Quantity Value Units Method Reference Comment
ΔrH°37.5kcal/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + L-Alanine, N-methyl- = (Sodium ion (1+) • L-Alanine, N-methyl-)

By formula: Na+ + C4H9NO2 = (Na+ • C4H9NO2)

Quantity Value Units Method Reference Comment
ΔrH°42.0 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.7; RCD

Sodium ion (1+) + dl-Threonine = (Sodium ion (1+) • dl-Threonine)

By formula: Na+ + C4H9NO3 = (Na+ • C4H9NO3)

Quantity Value Units Method Reference Comment
ΔrH°47.1kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Ethyl ether = (Sodium ion (1+) • Ethyl ether)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°31.0 ± 0.3kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.2cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
21.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Ethyl ether) + Ethyl ether = (Sodium ion (1+) • 2Ethyl ether)

By formula: (Na+ • C4H10O) + C4H10O = (Na+ • 2C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°22.9 ± 0.3kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.0cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 2Ethyl ether) + Ethyl ether = (Sodium ion (1+) • 3Ethyl ether)

By formula: (Na+ • 2C4H10O) + C4H10O = (Na+ • 3C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°16.4 ± 0.3kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.5cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Sodium ion (1+) + 1-Butanol = (Sodium ion (1+) • 1-Butanol)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°26.1 ± 1.2kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 2-Propanol, 2-methyl- = (Sodium ion (1+) • 2-Propanol, 2-methyl-)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°28.0 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°27.8 ± 1.0kcal/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
21.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1-Propanol, 2-methyl- = (Sodium ion (1+) • 1-Propanol, 2-methyl-)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°25.1 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°25.1 ± 1.4kcal/molCIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + 2-Butanol = (Sodium ion (1+) • 2-Butanol)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°28.0 ± 1.2kcal/molCIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • Ethane, 1,2-dimethoxy-)

By formula: Na+ + C4H10O2 = (Na+ • C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°37.8 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000glyme; RCD
ΔrH°57.6 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°38.5 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD
ΔrH°47.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°34.6cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
31.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • 2Ethane, 1,2-dimethoxy-)

By formula: (Na+ • C4H10O2) + C4H10O2 = (Na+ • 2C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°27.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°27.2 ± 2.0kcal/molCIDTMore, Ray, et al., 1997RCD
ΔrH°35.1kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°40.5cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • 3Ethane, 1,2-dimethoxy-)

By formula: (Na+ • 2C4H10O2) + C4H10O2 = (Na+ • 3C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°23.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°42.2cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + Pyridine = (Sodium ion (1+) • Pyridine)

By formula: Na+ + C5H5N = (Na+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°30.3 ± 0.7kcal/molCIDTAmunugama and Rodgers, 2000RCD

Sodium ion (1+) + Guanine = (Sodium ion (1+) • Guanine)

By formula: Na+ + C5H5N5O = (Na+ • C5H5N5O)

Quantity Value Units Method Reference Comment
ΔrH°43.5kcal/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + Adenine = (Sodium ion (1+) • Adenine)

By formula: Na+ + C5H5N5 = (Na+ • C5H5N5)

Quantity Value Units Method Reference Comment
ΔrH°33.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000, 2RCD
ΔrH°41.1kcal/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + Thymine = (Sodium ion (1+) • Thymine)

By formula: Na+ + C5H6N2O2 = (Na+ • C5H6N2O2)

Quantity Value Units Method Reference Comment
ΔrH°32.3 ± 0.9kcal/molCIDTRodgers and Armentrout, 2000, 2RCD
ΔrH°34.4kcal/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + 3-Aminopyridine = (Sodium ion (1+) • 3-Aminopyridine)

By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°32.5 ± 0.9kcal/molCIDTRodgers, 2001RCD

Sodium ion (1+) + 4-Aminopyridine = (Sodium ion (1+) • 4-Aminopyridine)

By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°35.0 ± 1.1kcal/molCIDTRodgers, 2001RCD

Sodium ion (1+) + 2-Aminopyridine = (Sodium ion (1+) • 2-Aminopyridine)

By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°35.0 ± 1.4kcal/molCIDTRodgers, 2001RCD

Sodium ion (1+) + 2-Cyclopenten-1-one = (Sodium ion (1+) • 2-Cyclopenten-1-one)

By formula: Na+ + C5H6O = (Na+ • C5H6O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
25.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1H-Pyrrole, 1-methyl- = (Sodium ion (1+) • 1H-Pyrrole, 1-methyl-)

By formula: Na+ + C5H7N = (Na+ • C5H7N)

Quantity Value Units Method Reference Comment
ΔrH°26.6 ± 0.8kcal/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + c-alanylglycine = (Sodium ion (1+) • c-alanylglycine)

By formula: Na+ + C5H8N2O2 = (Na+ • C5H8N2O2)

Quantity Value Units Method Reference Comment
ΔrH°35.6 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + 2-Butenal, 3-methyl- = (Sodium ion (1+) • 2-Butenal, 3-methyl-)

By formula: Na+ + C5H8O = (Na+ • C5H8O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
26.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + dl-Proline = (Sodium ion (1+) • dl-Proline)

By formula: Na+ + C5H9NO2 = (Na+ • C5H9NO2)

Quantity Value Units Method Reference Comment
ΔrH°41.8 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.3; RCD
ΔrH°46.8kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + L-Cysteine, N-acetyl- = (Sodium ion (1+) • L-Cysteine, N-acetyl-)

By formula: Na+ + C5H9NO3S = (Na+ • C5H9NO3S)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
30.90.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Alanine, N-acetyl- = (Sodium ion (1+) • L-Alanine, N-acetyl-)

By formula: Na+ + C5H9NO3 = (Na+ • C5H9NO3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
32.10.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + DL-Glutamic acid = (Sodium ion (1+) • DL-Glutamic acid)

By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)

Quantity Value Units Method Reference Comment
ΔrH°48.7kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + N-acetyl-Ser = (Sodium ion (1+) • N-acetyl-Ser)

By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
33.90.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + C5H10N2O3S = (Sodium ion (1+) • C5H10N2O3S)

By formula: Na+ + C5H10N2O3S = (Na+ • C5H10N2O3S)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
34.30.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Glutamine = (Sodium ion (1+) • L-Glutamine)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Quantity Value Units Method Reference Comment
ΔrH°50.6kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Glycyl-dl-alanine = (Sodium ion (1+) • Glycyl-dl-alanine)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Quantity Value Units Method Reference Comment
ΔrH°42.8 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + N-dl-Alanylglycine = (Sodium ion (1+) • N-dl-Alanylglycine)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Quantity Value Units Method Reference Comment
ΔrH°42.5 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + L-Alanine, N-glycyl- = (Sodium ion (1+) • L-Alanine, N-glycyl-)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
35.50.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Serine, N-glycyl- = (Sodium ion (1+) • L-Serine, N-glycyl-)

By formula: Na+ + C5H10N2O4 = (Na+ • C5H10N2O4)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
37.40.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + 2-Pentanone = (Sodium ion (1+) • 2-Pentanone)

By formula: Na+ + C5H10O = (Na+ • C5H10O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
24.9298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + D-Ribose = (Sodium ion (1+) • D-Ribose)

By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)

Quantity Value Units Method Reference Comment
ΔrH°42.1kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + arabinose = (Sodium ion (1+) • arabinose)

By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)

Quantity Value Units Method Reference Comment
ΔrH°40.6kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + xylose = (Sodium ion (1+) • xylose)

By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)

Quantity Value Units Method Reference Comment
ΔrH°40.9kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + DL-Valine = (Sodium ion (1+) • DL-Valine)

By formula: Na+ + C5H11NO2 = (Na+ • C5H11NO2)

Quantity Value Units Method Reference Comment
ΔrH°41.3 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.1; RCD
ΔrH°41.3kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Methane, diethoxy- = (Sodium ion (1+) • Methane, diethoxy-)

By formula: Na+ + C5H12O2 = (Na+ • C5H12O2)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
27.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Benzene, fluoro- = (Sodium ion (1+) • Benzene, fluoro-)

By formula: Na+ + C6H5F = (Na+ • C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°16.7 ± 0.8kcal/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Sodium ion (1+) • Benzene, fluoro-) + Benzene, fluoro- = (Sodium ion (1+) • 2Benzene, fluoro-)

By formula: (Na+ • C6H5F) + C6H5F = (Na+ • 2C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°15.7 ± 0.9kcal/molCIDTAmunugama and Rodgers, 2002, 2RCD

Sodium ion (1+) + Phenol = (Sodium ion (1+) • Phenol)

By formula: Na+ + C6H6O = (Na+ • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°24.4 ± 0.8kcal/molCIDTAmunugama and Rodgers, 2002RCD
ΔrH°23.5 ± 0.8kcal/molCIDTArmentrout and Rodgers, 2000RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
16.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Phenol) + Phenol = (Sodium ion (1+) • 2Phenol)

By formula: (Na+ • C6H6O) + C6H6O = (Na+ • 2C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°19.5 ± 0.8kcal/molCIDTAmunugama and Rodgers, 2002RCD

Sodium ion (1+) + Benzene = (Sodium ion (1+) • Benzene)

By formula: Na+ + C6H6 = (Na+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°22.8 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.1 ± 1.2kcal/molCIDTAmicangelo and Armentrout, 2000RCD
ΔrH°21.1 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°28.0kcal/molHPMSGuo, Purnell, et al., 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°31.2cal/mol*KHPMSGuo, Purnell, et al., 1990gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
15.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Benzene) + Benzene = (Sodium ion (1+) • 2Benzene)

By formula: (Na+ • C6H6) + C6H6 = (Na+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 1.kcal/molAVGN/AAverage of 7 values; Individual data points

Sodium ion (1+) + Pyridine, 4-methyl- = (Sodium ion (1+) • Pyridine, 4-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°31.9 ± 0.9kcal/molCIDTRodgers, 2001, 2RCD

Sodium ion (1+) + Pyridine, 3-methyl- = (Sodium ion (1+) • Pyridine, 3-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°31.8 ± 1.0kcal/molCIDTRodgers, 2001, 2RCD

Sodium ion (1+) + Pyridine, 2-methyl- = (Sodium ion (1+) • Pyridine, 2-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°30.6 ± 1.1kcal/molCIDTRodgers, 2001, 2RCD

Sodium ion (1+) + N-acetyl-L-aspartic acid = (Sodium ion (1+) • N-acetyl-L-aspartic acid)

By formula: Na+ + C6H9NO5 = (Na+ • C6H9NO5)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
34.90.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Histidine = (Sodium ion (1+) • Histidine)

By formula: Na+ + C6H9N3O2 = (Na+ • C6H9N3O2)

Quantity Value Units Method Reference Comment
ΔrH°52.3kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + 2,5-Piperazinedione, 3,6-dimethyl-, trans- = (Sodium ion (1+) • 2,5-Piperazinedione, 3,6-dimethyl-, trans-)

By formula: Na+ + C6H10N2O2 = (Na+ • C6H10N2O2)

Quantity Value Units Method Reference Comment
ΔrH°36.1 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + L-Aspartic acid, N-glycyl- = (Sodium ion (1+) • L-Aspartic acid, N-glycyl-)

By formula: Na+ + C6H10N2O5 = (Na+ • C6H10N2O5)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
38.50.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + DL-Alanine, N-DL-alanyl- = (Sodium ion (1+) • DL-Alanine, N-DL-alanyl-)

By formula: Na+ + C6H12N2O3 = (Na+ • C6H12N2O3)

Quantity Value Units Method Reference Comment
ΔrH°43.0 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + Glycylglycine ethyl ester = (Sodium ion (1+) • Glycylglycine ethyl ester)

By formula: Na+ + C6H12N2O4 = (Na+ • C6H12N2O4)

Quantity Value Units Method Reference Comment
ΔrH°43.2 ± 1.7kcal/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + L-Threonine, N-glycyl- = (Sodium ion (1+) • L-Threonine, N-glycyl-)

By formula: Na+ + C6H12N2O4 = (Na+ • C6H12N2O4)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
38.60.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glucose = (Sodium ion (1+) • Glucose)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
ΔrH°41.6kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + d-Mannose = (Sodium ion (1+) • d-Mannose)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
ΔrH°42.8kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + C6H12O6 = (Sodium ion (1+) • C6H12O6)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
ΔrH°42.3kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + DL-Leucine = (Sodium ion (1+) • DL-Leucine)

By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)

Quantity Value Units Method Reference Comment
ΔrH°41.8kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + DL-Isoleucine = (Sodium ion (1+) • DL-Isoleucine)

By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)

Quantity Value Units Method Reference Comment
ΔrH°42.0kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + methylvaline = (Sodium ion (1+) • methylvaline)

By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)

Quantity Value Units Method Reference Comment
ΔrH°42.8 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.8; RCD

Sodium ion (1+) + dl-Lysine = (Sodium ion (1+) • dl-Lysine)

By formula: Na+ + C6H14N2O2 = (Na+ • C6H14N2O2)

Quantity Value Units Method Reference Comment
ΔrH°>50.9kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Arginine = (Sodium ion (1+) • Arginine)

By formula: Na+ + C6H14N4O2 = (Na+ • C6H14N4O2)

Quantity Value Units Method Reference Comment
ΔrH°>53.7kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Anisole = (Sodium ion (1+) • Anisole)

By formula: Na+ + C7H8O = (Na+ • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°27.1 ± 2.0kcal/molCIDTAmunugama and Rodgers, 2003RCD

(Sodium ion (1+) • Anisole) + Anisole = (Sodium ion (1+) • 2Anisole)

By formula: (Na+ • C7H8O) + C7H8O = (Na+ • 2C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°21.4 ± 0.6kcal/molCIDTAmunugama and Rodgers, 2003RCD

Sodium ion (1+) + Toluene = (Sodium ion (1+) • Toluene)

By formula: Na+ + C7H8 = (Na+ • C7H8)

Quantity Value Units Method Reference Comment
ΔrH°26.8 ± 0.8kcal/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Sodium ion (1+) • Toluene) + Toluene = (Sodium ion (1+) • 2Toluene)

By formula: (Na+ • C7H8) + C7H8 = (Na+ • 2C7H8)

Quantity Value Units Method Reference Comment
ΔrH°20.7 ± 0.5kcal/molCIDTAmunugama and Rodgers, 2002, 3RCD

Sodium ion (1+) + L-Proline, 1-acetyl- = (Sodium ion (1+) • L-Proline, 1-acetyl-)

By formula: Na+ + C7H10NO3 = (Na+ • C7H10NO3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
35.20.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + N-Acetyl-L-glutamic acid = (Sodium ion (1+) • N-Acetyl-L-glutamic acid)

By formula: Na+ + C7H11NO5 = (Na+ • C7H11NO5)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
37.00.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-proline = (Sodium ion (1+) • Glycyl-L-proline)

By formula: Na+ + C7H12N2O3 = (Na+ • C7H12N2O3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
38.90.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-glutamic acid = (Sodium ion (1+) • Glycyl-L-glutamic acid)

By formula: Na+ + C7H12N2O5 = (Na+ • C7H12N2O5)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
40.70.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Methionine, N-acetyl- = (Sodium ion (1+) • L-Methionine, N-acetyl-)

By formula: Na+ + C7H13NO3S = (Na+ • C7H13NO3S)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
34.30.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Valine, N-acetyl- = (Sodium ion (1+) • L-Valine, N-acetyl-)

By formula: Na+ + C7H13NO3 = (Na+ • C7H13NO3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
33.50.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + C7H14N2O3S = (Sodium ion (1+) • C7H14N2O3S)

By formula: Na+ + C7H14N2O3S = (Na+ • C7H14N2O3S)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
37.40.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Valine, N-glycyl- = (Sodium ion (1+) • L-Valine, N-glycyl-)

By formula: Na+ + C7H14N2O3 = (Na+ • C7H14N2O3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
36.70.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + N-Acetyl-L-leucine = (Sodium ion (1+) • N-Acetyl-L-leucine)

By formula: Na+ + C8H15NO3 = (Na+ • C8H15NO3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
33.90.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Leucine, N-glycyl- = (Sodium ion (1+) • L-Leucine, N-glycyl-)

By formula: Na+ + C8H16N2O3 = (Na+ • C8H16N2O3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
36.90.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + 12-Crown-4 = (Sodium ion (1+) • 12-Crown-4)

By formula: Na+ + C8H16O4 = (Na+ • C8H16O4)

Quantity Value Units Method Reference Comment
ΔrH°89. ± 12.kcal/molCIDTMore, Ray, et al., 1997RCD

Sodium ion (1+) + DL-Phenylalanine = (Sodium ion (1+) • DL-Phenylalanine)

By formula: Na+ + C9H11NO2 = (Na+ • C9H11NO2)

Quantity Value Units Method Reference Comment
ΔrH°47.3 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.5; RCD
ΔrH°47.3kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + 2-Amino-3-(4-hydroxyphenyl)-propanoic acid = (Sodium ion (1+) • 2-Amino-3-(4-hydroxyphenyl)-propanoic acid)

By formula: Na+ + C9H11NO3 = (Na+ • C9H11NO3)

Quantity Value Units Method Reference Comment
ΔrH°48.0kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + 15-Crown-5 = (Sodium ion (1+) • 15-Crown-5)

By formula: Na+ + C10H20O5 = (Na+ • C10H20O5)

Quantity Value Units Method Reference Comment
ΔrH°70.3 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°71.2 ± 4.3kcal/molCIDTMore, Ray, et al., 1999RCD

Sodium ion (1+) + Tryptophan = (Sodium ion (1+) • Tryptophan)

By formula: Na+ + C11H12N2O2 = (Na+ • C11H12N2O2)

Quantity Value Units Method Reference Comment
ΔrH°49.0 ± 3.0kcal/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.6; RCD
ΔrH°50.2kcal/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + L-Phenylalanine, N-acetyl- = (Sodium ion (1+) • L-Phenylalanine, N-acetyl-)

By formula: Na+ + C11H13NO3 = (Na+ • C11H13NO3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
34.80.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + N-acetyl-L-tyrosine = (Sodium ion (1+) • N-acetyl-L-tyrosine)

By formula: Na+ + C11H13NO4 = (Na+ • C11H13NO4)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
34.60.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-phenyl alanine = (Sodium ion (1+) • Glycyl-L-phenyl alanine)

By formula: Na+ + C11H14N2O3 = (Na+ • C11H14N2O3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
38.10.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-tyrosine = (Sodium ion (1+) • Glycyl-L-tyrosine)

By formula: Na+ + C11H14N2O4 = (Na+ • C11H14N2O4)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
38.00.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Lactose = (Sodium ion (1+) • Lactose)

By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)

Quantity Value Units Method Reference Comment
ΔrH°48.8kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + gentiobiose = (Sodium ion (1+) • gentiobiose)

By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)

Quantity Value Units Method Reference Comment
ΔrH°48.0kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + C12H22O11 = (Sodium ion (1+) • C12H22O11)

By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)

Quantity Value Units Method Reference Comment
ΔrH°47.3kcal/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + 1,4,7,10,13,16-Hexaoxacyclooctadecane = (Sodium ion (1+) • 1,4,7,10,13,16-Hexaoxacyclooctadecane)

By formula: Na+ + C12H24O6 = (Na+ • C12H24O6)

Quantity Value Units Method Reference Comment
ΔrH°70.7 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°71.7 ± 4.5kcal/molCIDTMore, Ray, et al., 1999RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD
0.0298.CIDTMore, Ray, et al., 1999RCD

Sodium ion (1+) + L-Tryptophan, N-acetyl- = (Sodium ion (1+) • L-Tryptophan, N-acetyl-)

By formula: Na+ + C13H14NO3 = (Na+ • C13H14NO3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
37.40.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-tryptophan = (Sodium ion (1+) • Glycyl-L-tryptophan)

By formula: Na+ + C13H15N2O3 = (Na+ • C13H15N2O3)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
41.20.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + sodium chloride = (Sodium ion (1+) • sodium chloride)

By formula: Na+ + ClNa = (Na+ • ClNa)

Quantity Value Units Method Reference Comment
ΔrH°42.4kcal/molMSChupka, 1959gas phase; Knudsen cell; M
Quantity Value Units Method Reference Comment
ΔrS°17.6cal/mol*KMSChupka, 1959gas phase; Knudsen cell; M

Sodium ion (1+) + sodium fluoride = (Sodium ion (1+) • sodium fluoride)

By formula: Na+ + FNa = (Na+ • FNa)

Quantity Value Units Method Reference Comment
ΔrH°62.7kcal/molMSTsirlina, Gusarov, et al., 1986gas phase; Knudsen cell; M

(Sodium ion (1+) • sodium fluoride) + sodium fluoride = (Sodium ion (1+) • 2sodium fluoride)

By formula: (Na+ • FNa) + FNa = (Na+ • 2FNa)

Quantity Value Units Method Reference Comment
ΔrH°47.kcal/molMSTsirlina, Gusarov, et al., 1986gas phase; Knudsen cell; M

Sodium ion (1+) + F3Sc = (Sodium ion (1+) • F3Sc)

By formula: Na+ + F3Sc = (Na+ • F3Sc)

Quantity Value Units Method Reference Comment
ΔrH°33.kcal/molMSTsirlina, Gusarov, et al., 1986gas phase; Knudsen cell; M

Sodium ion (1+) + Hydrogen chloride = (Sodium ion (1+) • Hydrogen chloride)

By formula: Na+ + HCl = (Na+ • HCl)

Quantity Value Units Method Reference Comment
ΔrH°12.2kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.4cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Sodium ion (1+) + Nitric acid = (Sodium ion (1+) • Nitric acid)

By formula: Na+ + HNO3 = (Na+ • HNO3)

Quantity Value Units Method Reference Comment
ΔrH°20.6kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.3cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Sodium ion (1+) + Water = (Sodium ion (1+) • Water)

By formula: Na+ + H2O = (Na+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°24.0kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°21.0 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°19.6 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°22.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°26.5kcal/molMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M
Quantity Value Units Method Reference Comment
ΔrS°21.5cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°22.cal/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.6 (+1.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
15.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • Water)

By formula: (Na+ • H2O) + CO2 = (Na+ • CO2 • H2O)

Quantity Value Units Method Reference Comment
ΔrH°12.6kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.5cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Sodium ion (1+) • 2Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • 2Water)

By formula: (Na+ • 2H2O) + CO2 = (Na+ • CO2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°10.3kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.9cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Sodium ion (1+) • 3Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • 3Water)

By formula: (Na+ • 3H2O) + CO2 = (Na+ • CO2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°7.2kcal/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°-0.3kcal/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • Water • Carbon dioxide) + Water = (Sodium ion (1+) • 2Water • Carbon dioxide)

By formula: (Na+ • H2O • CO2) + H2O = (Na+ • 2H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°17.4kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°23.6cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • 2Water • Carbon dioxide) + Water = (Sodium ion (1+) • 3Water • Carbon dioxide)

By formula: (Na+ • 2H2O • CO2) + H2O = (Na+ • 3H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°12.4kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°23.cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrG°5.5kcal/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • Water) + Water = (Sodium ion (1+) • 2Water)

By formula: (Na+ • H2O) + H2O = (Na+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 2.kcal/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°22.2cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
19.6 (+1.4,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.0300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 2Water) + Water = (Sodium ion (1+) • 3Water)

By formula: (Na+ • 2H2O) + H2O = (Na+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°14.9kcal/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°15.8kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°16.7 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°16.1kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrH°16. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°20.8cal/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°21.9cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°22.0cal/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrS°23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°9.5kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.8 (+1.4,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
9.4300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 3Water) + Water = (Sodium ion (1+) • 4Water)

By formula: (Na+ • 3H2O) + H2O = (Na+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 0.9kcal/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°24. ± 3.cal/mol*KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrG°6.1kcal/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
13.1 (+1.4,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.6293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
6.4300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 4Water) + Water = (Sodium ion (1+) • 5Water)

By formula: (Na+ • 4H2O) + H2O = (Na+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°10.7kcal/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°11.6kcal/molHPMSTang and Castleman, 1972gas phase; M
ΔrH°12.3kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.9cal/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°26.5cal/mol*KHPMSTang and Castleman, 1972gas phase; M
ΔrS°28.1cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.7293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Sodium ion (1+) • 5Water) + Water = (Sodium ion (1+) • 6Water)

By formula: (Na+ • 5H2O) + H2O = (Na+ • 6H2O)

Quantity Value Units Method Reference Comment
ΔrH°10.7kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°26.0cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Sodium ion (1+) • Water) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide • Water)

By formula: (Na+ • H2O) + O2S = (Na+ • O2S • H2O)

Quantity Value Units Method Reference Comment
ΔrH°14.1kcal/molHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°17.4cal/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M

(Sodium ion (1+) • 3Water) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide • 3Water)

By formula: (Na+ • 3H2O) + O2S = (Na+ • O2S • 3H2O)

Quantity Value Units Method Reference Comment
ΔrG°4.8kcal/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

Sodium ion (1+) + Hydrogen = (Sodium ion (1+) • Hydrogen)

By formula: Na+ + H2 = (Na+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°2.93kcal/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.45 kcal/mol; M
Quantity Value Units Method Reference Comment
ΔrS°13.2cal/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.45 kcal/mol; M

(Sodium ion (1+) • Hydrogen) + Hydrogen = (Sodium ion (1+) • 2Hydrogen)

By formula: (Na+ • H2) + H2 = (Na+ • 2H2)

Quantity Value Units Method Reference Comment
ΔrH°2.41kcal/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.25 kcal/mol; M
Quantity Value Units Method Reference Comment
ΔrS°12.4cal/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 2.25 kcal/mol; M

Sodium ion (1+) + Ammonia = (Sodium ion (1+) • Ammonia)

By formula: Na+ + H3N = (Na+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°24.4 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°24.4 ± 1.3kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°25.6 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°29.1kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21800.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°25.7cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
18.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Ammonia) + Ammonia = (Sodium ion (1+) • 2Ammonia)

By formula: (Na+ • H3N) + H3N = (Na+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°22. ± 1.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°25.1cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 2Ammonia) + Ammonia = (Sodium ion (1+) • 3Ammonia)

By formula: (Na+ • 2H3N) + H3N = (Na+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°17.1kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.0cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 3Ammonia) + Ammonia = (Sodium ion (1+) • 4Ammonia)

By formula: (Na+ • 3H3N) + H3N = (Na+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°14.7kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.0cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 4Ammonia) + Ammonia = (Sodium ion (1+) • 5Ammonia)

By formula: (Na+ • 4H3N) + H3N = (Na+ • 5H3N)

Quantity Value Units Method Reference Comment
ΔrH°10.7kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.8cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 5Ammonia) + Ammonia = (Sodium ion (1+) • 6Ammonia)

By formula: (Na+ • 5H3N) + H3N = (Na+ • 6H3N)

Quantity Value Units Method Reference Comment
ΔrH°9.7kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.7cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Sodium ion (1+) + helium = (Sodium ion (1+) • helium)

By formula: Na+ + He = (Na+ • He)

Quantity Value Units Method Reference Comment
ΔrH°1.19kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°0.79kcal/molIMobViehland, 1984gas phase; M
ΔrH°0.93kcal/molIMobMason and Sharp, 1958gas phase; M
ΔrH°1.38kcal/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + Krypton = (Sodium ion (1+) • Krypton)

By formula: Na+ + Kr = (Na+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°4.84kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°5.08kcal/molIMobViehland, 1984gas phase; M
ΔrH°5.8kcal/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°6.57kcal/molIMobTakebe, 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.5cal/mol*KDTMcKnight and Sawina, 1973gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°8.0kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°18.6cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.2310.FAPerry, Rowe, et al., 1980gas phase; M
2.0310.DTBeyer and Keller, 1971gas phase; low E/N; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°5.3kcal/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°16.8cal/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
-0.3310.FAPerry, Rowe, et al., 1980gas phase; M

(Sodium ion (1+) • sodium) + sodium = (Sodium ion (1+) • 2sodium)

By formula: (Na+ • Na) + Na = (Na+ • 2Na)

Quantity Value Units Method Reference Comment
ΔrH°31.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 2sodium) + sodium = (Sodium ion (1+) • 3sodium)

By formula: (Na+ • 2Na) + Na = (Na+ • 3Na)

Quantity Value Units Method Reference Comment
ΔrH°13.4kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 3sodium) + sodium = (Sodium ion (1+) • 4sodium)

By formula: (Na+ • 3Na) + Na = (Na+ • 4Na)

Quantity Value Units Method Reference Comment
ΔrH°20.1kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 4sodium) + sodium = (Sodium ion (1+) • 5sodium)

By formula: (Na+ • 4Na) + Na = (Na+ • 5Na)

Quantity Value Units Method Reference Comment
ΔrH°13.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 5sodium) + sodium = (Sodium ion (1+) • 6sodium)

By formula: (Na+ • 5Na) + Na = (Na+ • 6Na)

Quantity Value Units Method Reference Comment
ΔrH°26.3kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 6sodium) + sodium = (Sodium ion (1+) • 7sodium)

By formula: (Na+ • 6Na) + Na = (Na+ • 7Na)

Quantity Value Units Method Reference Comment
ΔrH°17.5kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 7sodium) + sodium = (Sodium ion (1+) • 8sodium)

By formula: (Na+ • 7Na) + Na = (Na+ • 8Na)

Quantity Value Units Method Reference Comment
ΔrH°30.2kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 8sodium) + sodium = (Sodium ion (1+) • 9sodium)

By formula: (Na+ • 8Na) + Na = (Na+ • 9Na)

Quantity Value Units Method Reference Comment
ΔrH°18.0kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; ΔrH<; M

(Sodium ion (1+) • 9sodium) + sodium = (Sodium ion (1+) • 10sodium)

By formula: (Na+ • 9Na) + Na = (Na+ • 10Na)

Quantity Value Units Method Reference Comment
ΔrH°18.0kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 10sodium) + sodium = (Sodium ion (1+) • 11sodium)

By formula: (Na+ • 10Na) + Na = (Na+ • 11Na)

Quantity Value Units Method Reference Comment
ΔrH°15.7kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 11sodium) + sodium = (Sodium ion (1+) • 12sodium)

By formula: (Na+ • 11Na) + Na = (Na+ • 12Na)

Quantity Value Units Method Reference Comment
ΔrH°20.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 12sodium) + sodium = (Sodium ion (1+) • 13sodium)

By formula: (Na+ • 12Na) + Na = (Na+ • 13Na)

Quantity Value Units Method Reference Comment
ΔrH°16.6kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 13sodium) + sodium = (Sodium ion (1+) • 14sodium)

By formula: (Na+ • 13Na) + Na = (Na+ • 14Na)

Quantity Value Units Method Reference Comment
ΔrH°18.2kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 14sodium) + sodium = (Sodium ion (1+) • 15sodium)

By formula: (Na+ • 14Na) + Na = (Na+ • 15Na)

Quantity Value Units Method Reference Comment
ΔrH°15.9kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 15sodium) + sodium = (Sodium ion (1+) • 16sodium)

By formula: (Na+ • 15Na) + Na = (Na+ • 16Na)

Quantity Value Units Method Reference Comment
ΔrH°18.9kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 16sodium) + sodium = (Sodium ion (1+) • 17sodium)

By formula: (Na+ • 16Na) + Na = (Na+ • 17Na)

Quantity Value Units Method Reference Comment
ΔrH°19.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 17sodium) + sodium = (Sodium ion (1+) • 18sodium)

By formula: (Na+ • 17Na) + Na = (Na+ • 18Na)

Quantity Value Units Method Reference Comment
ΔrH°20.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 18sodium) + sodium = (Sodium ion (1+) • 19sodium)

By formula: (Na+ • 18Na) + Na = (Na+ • 19Na)

Quantity Value Units Method Reference Comment
ΔrH°19.6kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 19sodium) + sodium = (Sodium ion (1+) • 20sodium)

By formula: (Na+ • 19Na) + Na = (Na+ • 20Na)

Quantity Value Units Method Reference Comment
ΔrH°21.4kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 22sodium) + sodium = (Sodium ion (1+) • 23sodium)

By formula: (Na+ • 22Na) + Na = (Na+ • 23Na)

Quantity Value Units Method Reference Comment
ΔrH°17.1kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 23sodium) + sodium = (Sodium ion (1+) • 24sodium)

By formula: (Na+ • 23Na) + Na = (Na+ • 24Na)

Quantity Value Units Method Reference Comment
ΔrH°18.9kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 24sodium) + sodium = (Sodium ion (1+) • 25sodium)

By formula: (Na+ • 24Na) + Na = (Na+ • 25Na)

Quantity Value Units Method Reference Comment
ΔrH°18.2kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 25sodium) + sodium = (Sodium ion (1+) • 26sodium)

By formula: (Na+ • 25Na) + Na = (Na+ • 26Na)

Quantity Value Units Method Reference Comment
ΔrH°19.4kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 26sodium) + sodium = (Sodium ion (1+) • 27sodium)

By formula: (Na+ • 26Na) + Na = (Na+ • 27Na)

Quantity Value Units Method Reference Comment
ΔrH°18.2kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 27sodium) + sodium = (Sodium ion (1+) • 28sodium)

By formula: (Na+ • 27Na) + Na = (Na+ • 28Na)

Quantity Value Units Method Reference Comment
ΔrH°20.1kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 28sodium) + sodium = (Sodium ion (1+) • 29sodium)

By formula: (Na+ • 28Na) + Na = (Na+ • 29Na)

Quantity Value Units Method Reference Comment
ΔrH°19.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 29sodium) + sodium = (Sodium ion (1+) • 30sodium)

By formula: (Na+ • 29Na) + Na = (Na+ • 30Na)

Quantity Value Units Method Reference Comment
ΔrH°20.5kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 30sodium) + sodium = (Sodium ion (1+) • 31sodium)

By formula: (Na+ • 30Na) + Na = (Na+ • 31Na)

Quantity Value Units Method Reference Comment
ΔrH°19.4kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 31sodium) + sodium = (Sodium ion (1+) • 32sodium)

By formula: (Na+ • 31Na) + Na = (Na+ • 32Na)

Quantity Value Units Method Reference Comment
ΔrH°21.0kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 32sodium) + sodium = (Sodium ion (1+) • 33sodium)

By formula: (Na+ • 32Na) + Na = (Na+ • 33Na)

Quantity Value Units Method Reference Comment
ΔrH°21.2kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 33sodium) + sodium = (Sodium ion (1+) • 34sodium)

By formula: (Na+ • 33Na) + Na = (Na+ • 34Na)

Quantity Value Units Method Reference Comment
ΔrH°21.9kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 34sodium) + sodium = (Sodium ion (1+) • 35sodium)

By formula: (Na+ • 34Na) + Na = (Na+ • 35Na)

Quantity Value Units Method Reference Comment
ΔrH°19.6kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 35sodium) + sodium = (Sodium ion (1+) • 36sodium)

By formula: (Na+ • 35Na) + Na = (Na+ • 36Na)

Quantity Value Units Method Reference Comment
ΔrH°20.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

Sodium ion (1+) + neon = (Sodium ion (1+) • neon)

By formula: Na+ + Ne = (Na+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°1.76kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°1.52kcal/molIMobViehland, 1984gas phase; M
ΔrH°1.45kcal/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide)

By formula: Na+ + O2S = (Na+ • O2S)

Quantity Value Units Method Reference Comment
ΔrH°18.9kcal/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°20.3cal/mol*KN/APerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°12.8kcal/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • Sulfur dioxide) + Water = (Sodium ion (1+) • Water • Sulfur dioxide)

By formula: (Na+ • O2S) + H2O = (Na+ • H2O • O2S)

Quantity Value Units Method Reference Comment
ΔrH°19.8kcal/molHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20.2cal/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M

(Sodium ion (1+) • Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 2Sulfur dioxide)

By formula: (Na+ • O2S) + O2S = (Na+ • 2O2S)

Quantity Value Units Method Reference Comment
ΔrH°16.6kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°25.5cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • 2Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 3Sulfur dioxide)

By formula: (Na+ • 2O2S) + O2S = (Na+ • 3O2S)

Quantity Value Units Method Reference Comment
ΔrH°14.3kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°26.9cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • 3Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 4Sulfur dioxide)

By formula: (Na+ • 3O2S) + O2S = (Na+ • 4O2S)

Quantity Value Units Method Reference Comment
ΔrH°12.3kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°27.cal/mol*KN/ACastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.2328.HPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

Sodium ion (1+) + Oxygen = (Sodium ion (1+) • Oxygen)

By formula: Na+ + O2 = (Na+ • O2)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.2310.DTKeller and Beyer, 1971gas phase; low E/N; M

Sodium ion (1+) + Ozone = (Sodium ion (1+) • Ozone)

By formula: Na+ + O3 = (Na+ • O3)

Quantity Value Units Method Reference Comment
ΔrH°12.5kcal/molFARowe, Viggiano, et al., 1982gas phase; M

Sodium ion (1+) + Xenon = (Sodium ion (1+) • Xenon)

By formula: Na+ + Xe = (Na+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°5.97kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°5.94kcal/molIMobViehland, 1984gas phase; M
ΔrH°9.52kcal/molIMobTakebe, 1983gas phase; M

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blades, Klassen, et al., 1996
Blades, A.T.; Klassen, J.S.; Kebarle, P., Determination of Ion-Solvent Equilibria in the Gas Phase. Hydration of Diprotonated Diamines and Bis(trimethylammonium) Alkanes, J. Am. Chem. Soc., 1996, 118, 49, 12437, https://doi.org/10.1021/ja962641t . [all data]

Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B., Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2), J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045 . [all data]

Klassen, Blades, et al., 1995
Klassen, J.S.; Blades, A.T.; Kebarle, P., Determinations of Ion-Molecule Equilibria Involving Ions Produced by Electrospray. Hydration of Protonated Amines, Diamines, and Some Small Peptides, J. Phys. Chem., 1995, 99, 42, 15509, https://doi.org/10.1021/j100042a027 . [all data]

Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P., Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry, J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Tang, Lian, et al., 1976
Tang, I.N.; Lian, M.S.; Castleman, A.W., Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Strontium Ion, J. Chem. Phys., 1976, 65, 10, 4022, https://doi.org/10.1063/1.432854 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amicangelo and Armentrout, 2001
Amicangelo, J.C.; Armentrout, P.B., Relative and Absolute Bond Dissociation Energies of Sodium Cation Complexes Determined Using Competitive Collision-Induced Dissociation Experiments, Int. J. Mass Spectrom., 2001, 212, 1-3, 301, https://doi.org/10.1016/S1387-3806(01)00494-8 . [all data]

Burdett and Hayhurst, 1982
Burdett, N.A.; Hayhurst, A.N., Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer., J. Chem. Soc. Faraday Trans. 1, 1982, 78, 2997. [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]

Tang and Castleman, 1972
Tang, I.N.; Castleman, A.W., Mass Spectrometric Study of the Gas - Phase Hydration of the Monovalent Lead Ion, J. Chem. Phys., 1972, 57, 9, 3638, https://doi.org/10.1063/1.1678820 . [all data]

Peterson, Mark, et al., 1984
Peterson, K.I.; Mark, T.D.; Keesee, R.G.; Castleman, A.W., Thermochemical Properties of Gas - Phase Mixed Clusters: H2O/CO2 with Na+, J. Phys. Chem., 1984, 88, 13, 2880, https://doi.org/10.1021/j150657a042 . [all data]

Perry, Rowe, et al., 1980
Perry, R.A.; Rowe, B.R.; Viggiano, A.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C., Laboratory Measurements of Stratospheric Sodium Ion Measurements, Geophys. Res. Lett., 1980, 7, 9, 693, https://doi.org/10.1029/GL007i009p00693 . [all data]

Castleman, Holland, et al., 1978
Castleman, A.W.; Holland, P.M.; Lindsay, D.M.; Peterson, K.I., The Properties of Clusters in the Gas Phase. 2. Ammonia about Metal Ions, J. Am. Chem. Soc., 1978, 100, 19, 6039, https://doi.org/10.1021/ja00487a011 . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

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Hoyau, S.; Norrman, K.; McMahon, T.B.; Ohanessian, G., A Quantitative Basis for a Scale of Na+ Affinities of Organic and Small Biological Molecules in the Gas Phase, J. Am. Chem. Soc., 1999, 121, 38, 8864, https://doi.org/10.1021/ja9841198 . [all data]

Klassen, Anderson, et al., 1996
Klassen, J.S.; Anderson, S.G.; Blades, A.T.; Kebarle, P., Reaction Enthalpies for M+L = M+ + L, Where M+ = Na+ and K+ and L = Acetamide, N-Methylacetamide, N,N-Dimethylacetamide, Glycine, and Glycylglycine, from Determinations of the Collision-Induced Dissociation Thresholds, J. Phys. Chem., 1996, 100, 33, 14218, https://doi.org/10.1021/jp9608382 . [all data]

Guo, Conklin, et al., 1989
Guo, B.C.; Conklin, B.J.; Castleman, A.W., Thermochemical Properties of Ion Complexes Na+(M)n in the Gas Phase, J. Am. Chem. Soc., 1989, 111, 17, 6506, https://doi.org/10.1021/ja00199a005 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Guo, Purnell, et al., 1990
Guo, B.C.; Purnell, J.W.; Castleman, A.W., The Clustering Reactions of Benzene with Sodium and Lead Ions, Chem. Phys. Lett., 1990, 168, 2, 155, https://doi.org/10.1016/0009-2614(90)85122-S . [all data]

More, Ray, et al., 1997
More, M.B.; Ray, D.; Armentrout, P.B., Cation-ether complexes in the gas phase: Bond dissociation energies of Na+(dimethyl ether)(x), x=1-4; Na+(1,2-dimethoxyethane)(x), x=1 and 2; and Na+(12-crown-4), J. Phys. Chem. AJOURNAL OF PHYSICAL CHEMISTRY A 101 (5): 831-839 JAN 30 1997, 1997, 101, 831. [all data]

Castleman, Peterson, et al., 1983
Castleman, A.W.; Peterson, K.I.; Upschulte, B.L.; Schelling, F.J., Energetics and Structure of Na+ Cluster Ions, Int. J. Mass Spectrom. Ion Phys., 1983, 47, 203, https://doi.org/10.1016/0020-7381(83)87171-X . [all data]

Keller and Beyer, 1971
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Notes

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