Sodium ion (1+)

Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar147.95J/mol*KReviewChase, 1998Data last reviewed in December, 1983

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(Sodium ion (1+) • 3Water) + Water = (Sodium ion (1+) • 4Water)

By formula: (Na+ • 3H2O) + H2O = (Na+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°55. ± 4.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°99. ± 10.J/mol*KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrG°26.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
54.8 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
27.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • Water) + Water = (Sodium ion (1+) • 2Water)

By formula: (Na+ • H2O) + H2O = (Na+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°79. ± 8.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
82.0 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 2Water) + Water = (Sodium ion (1+) • 3Water)

By formula: (Na+ • 2H2O) + H2O = (Na+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°62.3kJ/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°66.1kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°69.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°67.4kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrH°70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°87.0J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°91.6J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°92.0J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°40.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
70.3 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Sodium ion (1+) + Water = (Sodium ion (1+) • Water)

By formula: Na+ + H2O = (Na+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°100.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°87.9 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°82.0 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°95.0 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°111.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M
Quantity Value Units Method Reference Comment
ΔrS°90.0J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°92.J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
94.6 (+7.5,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
65.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • 4Water) + Water = (Sodium ion (1+) • 5Water)

By formula: (Na+ • 4H2O) + H2O = (Na+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°44.8kJ/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°48.5kJ/molHPMSTang and Castleman, 1972gas phase; M
ΔrH°51.5kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°104.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°111.J/mol*KHPMSTang and Castleman, 1972gas phase; M
ΔrS°118.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Sodium ion (1+) • Carbon dioxide) + Water = (Sodium ion (1+) • Water • Carbon dioxide)

By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°86.6kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrH°95.8kJ/molFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrS°107.J/mol*KFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M

(Sodium ion (1+) • Ammonia) + Ammonia = (Sodium ion (1+) • 2Ammonia)

By formula: (Na+ • H3N) + H3N = (Na+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°93. ± 5.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • Benzene) + Benzene = (Sodium ion (1+) • 2Benzene)

By formula: (Na+ • C6H6) + C6H6 = (Na+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°81. ± 5.kJ/molAVGN/AAverage of 7 values; Individual data points

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°85. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points

Sodium ion (1+) + Acetone = (Sodium ion (1+) • Acetone)

By formula: Na+ + C3H6O = (Na+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°131. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°129. ± 2.kJ/molHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrH°102.kJ/molCIDTKlassen, Anderson, et al., 1996RCD
ΔrH°140. ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°87900.J/mol*KHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrS°109.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
101.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Methyl Alcohol = (Sodium ion (1+) • Methyl Alcohol)

By formula: Na+ + CH4O = (Na+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°97.1 ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°91.6 ± 5.9kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°100. ± 0.8kJ/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°111. ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°85800.J/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°102.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
72.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Ammonia = (Sodium ion (1+) • Ammonia)

By formula: Na+ + H3N = (Na+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°102. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°102. ± 5.4kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°107. ± 0.8kJ/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°122.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°91200.J/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°108.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
77.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Benzene = (Sodium ion (1+) • Benzene)

By formula: Na+ + C6H6 = (Na+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°95.4 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°88.3 ± 5.0kJ/molCIDTAmicangelo and Armentrout, 2000RCD
ΔrH°88.3 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°117.kJ/molHPMSGuo, Purnell, et al., 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°131.J/mol*KHPMSGuo, Purnell, et al., 1990gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
65.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • Ethane, 1,2-dimethoxy-)

By formula: Na+ + C4H10O2 = (Na+ • C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°158. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000glyme; RCD
ΔrH°241. ± 18.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°161. ± 4.2kJ/molCIDTMore, Ray, et al., 1997RCD
ΔrH°197.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°145.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
133.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°100. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°91.6 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°92.0 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°92.9 ± 5.0kJ/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
73.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
73.6298.CIDCMcMahon and Ohanessian, 2000RCD

(Sodium ion (1+) • 2Water • Carbon dioxide) + Water = (Sodium ion (1+) • 3Water • Carbon dioxide)

By formula: (Na+ • 2H2O • CO2) + H2O = (Na+ • 3H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°51.9kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrG°23.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 2Methyl Alcohol)

By formula: (Na+ • CH4O) + CH4O = (Na+ • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°85.8 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°89.5 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°85.8 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°84.5 ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 3Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • 3Water)

By formula: (Na+ • 3H2O) + CO2 = (Na+ • CO2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°30.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°-1.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • 3Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 4Sulfur dioxide)

By formula: (Na+ • 3O2S) + O2S = (Na+ • 4O2S)

Quantity Value Units Method Reference Comment
ΔrH°51.5kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/ACastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.328.HPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • 3Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 4Carbon dioxide)

By formula: (Na+ • 3CO2) + CO2 = (Na+ • 4CO2)

Quantity Value Units Method Reference Comment
ΔrH°35.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.310.HPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

Sodium ion (1+) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide)

By formula: Na+ + CO2 = (Na+ • CO2)

Quantity Value Units Method Reference Comment
ΔrH°66.5kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrH°57.3kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.1J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrS°82.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.310.DTKeller and Beyer, 1971gas phase; low E/N; M

Sodium ion (1+) + Ethanol = (Sodium ion (1+) • Ethanol)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°110. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°102. ± 4.kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°102. ± 4.kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
79.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + Methylamine = (Sodium ion (1+) • Methylamine)

By formula: Na+ + CH5N = (Na+ • CH5N)

Quantity Value Units Method Reference Comment
ΔrH°110. ± 0.8kJ/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°134.kJ/molHPMSGuo and Castleman, 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°94600.J/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°127.J/mol*KHPMSGuo and Castleman, 1990gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
81.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide)

By formula: Na+ + O2S = (Na+ • O2S)

Quantity Value Units Method Reference Comment
ΔrH°79.1kJ/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°84.9J/mol*KN/APerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°53.6kJ/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M

Sodium ion (1+) + Krypton = (Sodium ion (1+) • Krypton)

By formula: Na+ + Kr = (Na+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°20.3kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°21.3kJ/molIMobViehland, 1984gas phase; M
ΔrH°24.kJ/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°27.5kJ/molIMobTakebe, 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.4J/mol*KDTMcKnight and Sawina, 1973gas phase; M

(Sodium ion (1+) • Ethanol) + Ethanol = (Sodium ion (1+) • 2Ethanol)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°99.2 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°96.7 ± 4.6kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°99.2 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°97.5 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD

Sodium ion (1+) + Argon = (Sodium ion (1+) • Argon)

By formula: Na+ + Ar = (Na+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 8.8kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°15.5kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°18.4kJ/molIMobViehland, 1984gas phase; M
ΔrH°18.kJ/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°20.4kJ/molIMobTakebe, 1983gas phase; M

(Sodium ion (1+) • 4Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 5Acetonitrile)

By formula: (Na+ • 4C2H3N) + C2H3N = (Na+ • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°53. ± 3.kJ/molCIDTValina, 2001CH3CN is fifth ligand; RCD
ΔrH°53.1kJ/molHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°172.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°33.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.2310.FAPerry, Rowe, et al., 1980gas phase; M
8.4310.DTBeyer and Keller, 1971gas phase; low E/N; M

(Sodium ion (1+) • Water • Carbon dioxide) + Water = (Sodium ion (1+) • 2Water • Carbon dioxide)

By formula: (Na+ • H2O • CO2) + H2O = (Na+ • 2H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°72.8kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°98.7J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

Sodium ion (1+) + Isopropyl Alcohol = (Sodium ion (1+) • Isopropyl Alcohol)

By formula: Na+ + C3H8O = (Na+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°113. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°113. ± 4.6kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
85.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

(Sodium ion (1+) • Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • 2Ethane, 1,2-dimethoxy-)

By formula: (Na+ • C4H10O2) + C4H10O2 = (Na+ • 2C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°116. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°114. ± 8.4kJ/molCIDTMore, Ray, et al., 1997RCD
ΔrH°147.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°169.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • Carbon monoxide) + Carbon monoxide = (Sodium ion (1+) • 2Carbon monoxide)

By formula: (Na+ • CO) + CO = (Na+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°24. ± 3.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°24. ± 3.kJ/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°31.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°63.2J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + helium = (Sodium ion (1+) • helium)

By formula: Na+ + He = (Na+ • He)

Quantity Value Units Method Reference Comment
ΔrH°4.98kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°3.3kJ/molIMobViehland, 1984gas phase; M
ΔrH°3.9kJ/molIMobMason and Sharp, 1958gas phase; M
ΔrH°5.77kJ/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + Carbon monoxide = (Sodium ion (1+) • Carbon monoxide)

By formula: Na+ + CO = (Na+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°32. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°32. ± 7.9kJ/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°52.7kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°85.4J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + 1,4,7,10,13,16-Hexaoxacyclooctadecane = (Sodium ion (1+) • 1,4,7,10,13,16-Hexaoxacyclooctadecane)

By formula: Na+ + C12H24O6 = (Na+ • C12H24O6)

Quantity Value Units Method Reference Comment
ΔrH°296. ± 19.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°300. ± 19.kJ/molCIDTMore, Ray, et al., 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD
0.0298.CIDTMore, Ray, et al., 1999RCD

(Sodium ion (1+) • Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 2Carbon dioxide)

By formula: (Na+ • CO2) + CO2 = (Na+ • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°46.0kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.310.DTKeller and Beyer, 1971gas phase; low E/N; M

Sodium ion (1+) + Ethyl ether = (Sodium ion (1+) • Ethyl ether)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°130. ± 1.kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°118.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
89.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Hydrogen) + Hydrogen = (Sodium ion (1+) • 2Hydrogen)

By formula: (Na+ • H2) + H2 = (Na+ • 2H2)

Quantity Value Units Method Reference Comment
ΔrH°10.1kJ/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 9.41 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°51.9J/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 9.41 kJ/mol; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.3J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-1.310.FAPerry, Rowe, et al., 1980gas phase; M

Sodium ion (1+) + Hydrogen = (Sodium ion (1+) • Hydrogen)

By formula: Na+ + H2 = (Na+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°12.3kJ/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 10.3 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°55.2J/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 10.3 kJ/mol; M

Sodium ion (1+) + Phenol = (Sodium ion (1+) • Phenol)

By formula: Na+ + C6H6O = (Na+ • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°102. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002RCD
ΔrH°98. ± 3.kJ/molCIDTArmentrout and Rodgers, 2000RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
69.9298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 2-Propanol, 2-methyl- = (Sodium ion (1+) • 2-Propanol, 2-methyl-)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°117. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°116. ± 4.2kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
89.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • 2Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 3Acetonitrile)

By formula: (Na+ • 2C2H3N) + C2H3N = (Na+ • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°89. ± 3.kJ/molCIDTValina, 2001RCD
ΔrH°86.2kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°115.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 3Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 4Acetonitrile)

By formula: (Na+ • 3C2H3N) + C2H3N = (Na+ • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°64. ± 3.kJ/molCIDTValina, 2001RCD
ΔrH°62.3kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 2Acetonitrile)

By formula: (Na+ • C2H3N) + C2H3N = (Na+ • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°109. ± 7.9kJ/molCIDTValina, 2001RCD
ΔrH°102.kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°95.0J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

Sodium ion (1+) + Glycine = (Sodium ion (1+) • Glycine)

By formula: Na+ + C2H5NO2 = (Na+ • C2H5NO2)

Quantity Value Units Method Reference Comment
ΔrH°161. ± 7.9kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD
ΔrH°164. ± 5.9kJ/molCIDTMoision and Armentrout, 2002RCD
ΔrH°153.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Xenon = (Sodium ion (1+) • Xenon)

By formula: Na+ + Xe = (Na+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°25.0kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°24.9kJ/molIMobViehland, 1984gas phase; M
ΔrH°39.8kJ/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + N-Glycylglycine = (Sodium ion (1+) • N-Glycylglycine)

By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)

Quantity Value Units Method Reference Comment
ΔrH°177. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998See amide; RCD
ΔrH°179.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
143.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + neon = (Sodium ion (1+) • neon)

By formula: Na+ + Ne = (Na+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°7.36kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°6.36kJ/molIMobViehland, 1984gas phase; M
ΔrH°6.07kJ/molIMobTakebe, 1983gas phase; M

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Sodium ion (1+) + Argon = (Sodium ion (1+) • Argon)

By formula: Na+ + Ar = (Na+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 8.8kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°15.5kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°18.4kJ/molIMobViehland, 1984gas phase; M
ΔrH°18.kJ/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°20.4kJ/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + 2H-Tetrazole = (Sodium ion (1+) • 2H-Tetrazole)

By formula: Na+ + CH2N4 = (Na+ • CH2N4)

Quantity Value Units Method Reference Comment
ΔrH°115. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + Methyl Alcohol = (Sodium ion (1+) • Methyl Alcohol)

By formula: Na+ + CH4O = (Na+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°97.1 ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°91.6 ± 5.9kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°100. ± 0.8kJ/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°111. ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°85800.J/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°102.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
72.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 2Methyl Alcohol)

By formula: (Na+ • CH4O) + CH4O = (Na+ • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°85.8 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°89.5 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°85.8 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°84.5 ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 2Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 3Methyl Alcohol)

By formula: (Na+ • 2CH4O) + CH4O = (Na+ • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°73. ± 2.kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 3Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 4Methyl Alcohol)

By formula: (Na+ • 3CH4O) + CH4O = (Na+ • 4CH4O)

Quantity Value Units Method Reference Comment
ΔrH°65.7 ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°126.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Sodium ion (1+) + Methane = (Sodium ion (1+) • Methane)

By formula: Na+ + CH4 = (Na+ • CH4)

Quantity Value Units Method Reference Comment
ΔrH°30.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.0J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + Methylamine = (Sodium ion (1+) • Methylamine)

By formula: Na+ + CH5N = (Na+ • CH5N)

Quantity Value Units Method Reference Comment
ΔrH°110. ± 0.8kJ/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°134.kJ/molHPMSGuo and Castleman, 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°94600.J/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°127.J/mol*KHPMSGuo and Castleman, 1990gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
81.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Carbon monoxide = (Sodium ion (1+) • Carbon monoxide)

By formula: Na+ + CO = (Na+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°32. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°32. ± 7.9kJ/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°52.7kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°85.4J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • Carbon monoxide) + Carbon monoxide = (Sodium ion (1+) • 2Carbon monoxide)

By formula: (Na+ • CO) + CO = (Na+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°24. ± 3.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°24. ± 3.kJ/molCIDTWalter, Sievers, et al., 1998RCD
ΔrH°31.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°63.2J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide)

By formula: Na+ + CO2 = (Na+ • CO2)

Quantity Value Units Method Reference Comment
ΔrH°66.5kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrH°57.3kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.1J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M
ΔrS°82.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.310.DTKeller and Beyer, 1971gas phase; low E/N; M

(Sodium ion (1+) • Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 2Carbon dioxide)

By formula: (Na+ • CO2) + CO2 = (Na+ • 2CO2)

Quantity Value Units Method Reference Comment
ΔrH°46.0kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.310.DTKeller and Beyer, 1971gas phase; low E/N; M

(Sodium ion (1+) • 2Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 3Carbon dioxide)

By formula: (Na+ • 2CO2) + CO2 = (Na+ • 3CO2)

Quantity Value Units Method Reference Comment
ΔrH°41.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Sodium ion (1+) • 3Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) • 4Carbon dioxide)

By formula: (Na+ • 3CO2) + CO2 = (Na+ • 4CO2)

Quantity Value Units Method Reference Comment
ΔrH°35.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.310.HPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • Carbon dioxide) + Water = (Sodium ion (1+) • Water • Carbon dioxide)

By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°86.6kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrH°95.8kJ/molFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
ΔrS°107.J/mol*KFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M

Sodium ion (1+) + Acetonitrile = (Sodium ion (1+) • Acetonitrile)

By formula: Na+ + C2H3N = (Na+ • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°128. ± 4.6kJ/molCIDTValina, 2001RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
98.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 2Acetonitrile)

By formula: (Na+ • C2H3N) + C2H3N = (Na+ • 2C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°109. ± 7.9kJ/molCIDTValina, 2001RCD
ΔrH°102.kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°95.0J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 2Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 3Acetonitrile)

By formula: (Na+ • 2C2H3N) + C2H3N = (Na+ • 3C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°89. ± 3.kJ/molCIDTValina, 2001RCD
ΔrH°86.2kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°115.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 3Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 4Acetonitrile)

By formula: (Na+ • 3C2H3N) + C2H3N = (Na+ • 4C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°64. ± 3.kJ/molCIDTValina, 2001RCD
ΔrH°62.3kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) • 4Acetonitrile) + Acetonitrile = (Sodium ion (1+) • 5Acetonitrile)

By formula: (Na+ • 4C2H3N) + C2H3N = (Na+ • 5C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°53. ± 3.kJ/molCIDTValina, 2001CH3CN is fifth ligand; RCD
ΔrH°53.1kJ/molHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°172.J/mol*KHPMSDavidson and Kebarle, 1976gas phase; Entropy change is questionable; M

Sodium ion (1+) + C2H3N3 = (Sodium ion (1+) • C2H3N3)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°95.8 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + 1H-1,2,3-Triazole = (Sodium ion (1+) • 1H-1,2,3-Triazole)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°95.8 ± 4.6kJ/molCIDTRodgers and Armentrout, 1999, 2RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 1999, 2RCD

Sodium ion (1+) + 1H-1,2,4-Triazole = (Sodium ion (1+) • 1H-1,2,4-Triazole)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°124. ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD

Sodium ion (1+) + 4H-1,2,4-triazole = (Sodium ion (1+) • 4H-1,2,4-triazole)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°124. ± 5.0kJ/molCIDTRodgers and Armentrout, 1999, 2RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 1999, 2RCD

Sodium ion (1+) + Acetaldehyde = (Sodium ion (1+) • Acetaldehyde)

By formula: Na+ + C2H4O = (Na+ • C2H4O)

Quantity Value Units Method Reference Comment
ΔrH°113. ± 3.kJ/molCIDTArmentrout and Rodgers, 2000RCD

Sodium ion (1+) + Ethylene = (Sodium ion (1+) • Ethylene)

By formula: Na+ + C2H4 = (Na+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°43.1 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD

Sodium ion (1+) + Ethanol, 2-fluoro- = (Sodium ion (1+) • Ethanol, 2-fluoro-)

By formula: Na+ + C2H5FO = (Na+ • C2H5FO)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
98.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Acetamide = (Sodium ion (1+) • Acetamide)

By formula: Na+ + C2H5NO = (Na+ • C2H5NO)

Quantity Value Units Method Reference Comment
ΔrH°145.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Glycine = (Sodium ion (1+) • Glycine)

By formula: Na+ + C2H5NO2 = (Na+ • C2H5NO2)

Quantity Value Units Method Reference Comment
ΔrH°161. ± 7.9kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD
ΔrH°164. ± 5.9kJ/molCIDTMoision and Armentrout, 2002RCD
ΔrH°153.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Acetamide, 2-amino- = (Sodium ion (1+) • Acetamide, 2-amino-)

By formula: Na+ + C2H6N2O = (Na+ • C2H6N2O)

Quantity Value Units Method Reference Comment
ΔrH°173.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + Dimethyl Sulfoxide = (Sodium ion (1+) • Dimethyl Sulfoxide)

By formula: Na+ + C2H6OS = (Na+ • C2H6OS)

Quantity Value Units Method Reference Comment
ΔrH°130.kJ/molCIDKlassen, Anderson, et al., 1996RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
130.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Ethanol = (Sodium ion (1+) • Ethanol)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°110. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°102. ± 4.kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°102. ± 4.kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
79.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

(Sodium ion (1+) • Ethanol) + Ethanol = (Sodium ion (1+) • 2Ethanol)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°99.2 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°96.7 ± 4.6kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°99.2 ± 6.7kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°97.5 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°100. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°91.6 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°92.0 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°92.9 ± 5.0kJ/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
73.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
73.6298.CIDCMcMahon and Ohanessian, 2000RCD

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°85. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points

(Sodium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 3Dimethyl ether)

By formula: (Na+ • 2C2H6O) + C2H6O = (Na+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°66.9 ± 5.0kJ/molCIDTMore, Ray, et al., 1997RCD

(Sodium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 4Dimethyl ether)

By formula: (Na+ • 3C2H6O) + C2H6O = (Na+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°61.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°58.2 ± 4.2kJ/molCIDTMore, Ray, et al., 1997RCD

Sodium ion (1+) + Dimethyl sulfide = (Sodium ion (1+) • Dimethyl sulfide)

By formula: Na+ + C2H6S = (Na+ • C2H6S)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
59.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Monoethanolamine = (Sodium ion (1+) • Monoethanolamine)

By formula: Na+ + C2H7NO = (Na+ • C2H7NO)

Quantity Value Units Method Reference Comment
ΔrH°175. ± 7.1kJ/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + Dimethylamine = (Sodium ion (1+) • Dimethylamine)

By formula: Na+ + C2H7N = (Na+ • C2H7N)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
82.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1,3,5-Triazine = (Sodium ion (1+) • 1,3,5-Triazine)

By formula: Na+ + C3H3N3 = (Na+ • C3H3N3)

Quantity Value Units Method Reference Comment
ΔrH°88. ± 3.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Sodium ion (1+) + 1H-Pyrazole = (Sodium ion (1+) • 1H-Pyrazole)

By formula: Na+ + C3H4N2 = (Na+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°128. ± 9.2kJ/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + 1H-Imidazole = (Sodium ion (1+) • 1H-Imidazole)

By formula: Na+ + C3H4N2 = (Na+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°140. ± 5.0kJ/molCIDTHuang and Rodgers, 2002RCD
ΔrH°140. ± 5.4kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°140. ± 5.0kJ/molCIDTRodgers and Armentrout, 1999, 2RCD

Sodium ion (1+) + Propanenitrile = (Sodium ion (1+) • Propanenitrile)

By formula: Na+ + C3H5N = (Na+ • C3H5N)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
103.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Acetone = (Sodium ion (1+) • Acetone)

By formula: Na+ + C3H6O = (Na+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°131. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°129. ± 2.kJ/molHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrH°102.kJ/molCIDTKlassen, Anderson, et al., 1996RCD
ΔrH°140. ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°87900.J/mol*KHPMSHoyau, Norrman, et al., 1999See 96KLA/AND?; RCD
ΔrS°109.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
101.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Acetone) + Acetone = (Sodium ion (1+) • 2Acetone)

By formula: (Na+ • C3H6O) + C3H6O = (Na+ • 2C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°105. ± 0.4kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°103.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 2Acetone) + Acetone = (Sodium ion (1+) • 3Acetone)

By formula: (Na+ • 2C3H6O) + C3H6O = (Na+ • 3C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°86.6 ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°126.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 3Acetone) + Acetone = (Sodium ion (1+) • 4Acetone)

By formula: (Na+ • 3C3H6O) + C3H6O = (Na+ • 4C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°61.5 ± 0.8kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°114.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Sodium ion (1+) + Propanoic acid = (Sodium ion (1+) • Propanoic acid)

By formula: Na+ + C3H6O2 = (Na+ • C3H6O2)

Quantity Value Units Method Reference Comment
ΔrH°118. ± 5.9kJ/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + Acetic acid, methyl ester = (Sodium ion (1+) • Acetic acid, methyl ester)

By formula: Na+ + C3H6O2 = (Na+ • C3H6O2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
97.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Formamide, N,N-dimethyl- = (Sodium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Na+ + C3H7NO = (Na+ • C3H7NO)

Quantity Value Units Method Reference Comment
ΔrH°156. ± 4.kJ/molCIDTArmentrout and Rodgers, 2000See 96KLA/AND?; RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
126.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Acetamide, N-methyl- = (Sodium ion (1+) • Acetamide, N-methyl-)

By formula: Na+ + C3H7NO = (Na+ • C3H7NO)

Quantity Value Units Method Reference Comment
ΔrH°149.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + dl-Cysteine = (Sodium ion (1+) • dl-Cysteine)

By formula: Na+ + C3H7NO2S = (Na+ • C3H7NO2S)

Quantity Value Units Method Reference Comment
ΔrH°179. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.2; RCD
ΔrH°175.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Alanine = (Sodium ion (1+) • Alanine)

By formula: Na+ + C3H7NO2 = (Na+ • C3H7NO2)

Quantity Value Units Method Reference Comment
ΔrH°169. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.0; RCD
ΔrH°167.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + dl-Serine = (Sodium ion (1+) • dl-Serine)

By formula: Na+ + C3H7NO3 = (Na+ • C3H7NO3)

Quantity Value Units Method Reference Comment
ΔrH°188. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.4; RCD
ΔrH°192.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Isopropyl Alcohol = (Sodium ion (1+) • Isopropyl Alcohol)

By formula: Na+ + C3H8O = (Na+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°113. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°113. ± 4.6kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
85.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
0.00.CIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + 1-Propanol = (Sodium ion (1+) • 1-Propanol)

By formula: Na+ + C3H8O = (Na+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°108. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°108. ± 4.2kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + Methylamine, N,N-dimethyl- = (Sodium ion (1+) • Methylamine, N,N-dimethyl-)

By formula: Na+ + C3H9N = (Na+ • C3H9N)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
79.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Propylamine = (Sodium ion (1+) • Propylamine)

By formula: Na+ + C3H9N = (Na+ • C3H9N)

Quantity Value Units Method Reference Comment
ΔrH°121. ± 5.9kJ/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + Uracil = (Sodium ion (1+) • Uracil)

By formula: Na+ + C4H4N2O2 = (Na+ • C4H4N2O2)

Quantity Value Units Method Reference Comment
ΔrH°135. ± 3.kJ/molCIDTRodgers and Armentrout, 2000, 2RCD
ΔrH°141.kJ/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + Pyrazine = (Sodium ion (1+) • Pyrazine)

By formula: Na+ + C4H4N2 = (Na+ • C4H4N2)

Quantity Value Units Method Reference Comment
ΔrH°108. ± 3.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Sodium ion (1+) + Furan = (Sodium ion (1+) • Furan)

By formula: Na+ + C4H4O = (Na+ • C4H4O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
49.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Pyrrole = (Sodium ion (1+) • Pyrrole)

By formula: Na+ + C4H5N = (Na+ • C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°102. ± 4.6kJ/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + Cytosine = (Sodium ion (1+) • Cytosine)

By formula: Na+ + C4H5N3O = (Na+ • C4H5N3O)

Quantity Value Units Method Reference Comment
ΔrH°177.kJ/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + 2,5-Piperazinedione = (Sodium ion (1+) • 2,5-Piperazinedione)

By formula: Na+ + C4H6N2O2 = (Na+ • C4H6N2O2)

Quantity Value Units Method Reference Comment
ΔrH°143. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + 1H-Imidazole, 1-methyl- = (Sodium ion (1+) • 1H-Imidazole, 1-methyl-)

By formula: Na+ + C4H6N2 = (Na+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°161. ± 5.0kJ/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + 1H-Pyrazole, 1-methyl- = (Sodium ion (1+) • 1H-Pyrazole, 1-methyl-)

By formula: Na+ + C4H6N2 = (Na+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°131. ± 3.kJ/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + Acetic anhydride = (Sodium ion (1+) • Acetic anhydride)

By formula: Na+ + C4H6O3 = (Na+ • C4H6O3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
130.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1,3-Butadiene = (Sodium ion (1+) • 1,3-Butadiene)

By formula: Na+ + C4H6 = (Na+ • C4H6)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
43.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Glycine, N-acetyl- = (Sodium ion (1+) • Glycine, N-acetyl-)

By formula: Na+ + C4H7NO3 = (Na+ • C4H7NO3)

Quantity Value Units Method Reference Comment
ΔrH°172. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
129.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + dl-Aspartic acid = (Sodium ion (1+) • dl-Aspartic acid)

By formula: Na+ + C4H7NO4 = (Na+ • C4H7NO4)

Quantity Value Units Method Reference Comment
ΔrH°203.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Butanediamide = (Sodium ion (1+) • Butanediamide)

By formula: Na+ + C4H8N2O2 = (Na+ • C4H8N2O2)

Quantity Value Units Method Reference Comment
ΔrH°186.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + L-Asparagine = (Sodium ion (1+) • L-Asparagine)

By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)

Quantity Value Units Method Reference Comment
ΔrH°206.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + N-Glycylglycine = (Sodium ion (1+) • N-Glycylglycine)

By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)

Quantity Value Units Method Reference Comment
ΔrH°177. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998See amide; RCD
ΔrH°179.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
143.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + 2-Butanone = (Sodium ion (1+) • 2-Butanone)

By formula: Na+ + C4H8O = (Na+ • C4H8O)

Quantity Value Units Method Reference Comment
ΔrH°131. ± 7.1kJ/molCIDTMoision and Armentrout, 2002RCD

Sodium ion (1+) + 1,4-Dioxane = (Sodium ion (1+) • 1,4-Dioxane)

By formula: Na+ + C4H8O2 = (Na+ • C4H8O2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
101.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1-Propene, 2-methyl- = (Sodium ion (1+) • 1-Propene, 2-methyl-)

By formula: Na+ + C4H8 = (Na+ • C4H8)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Butane, 1-bromo- = (Sodium ion (1+) • Butane, 1-bromo-)

By formula: Na+ + C4H9Br = (Na+ • C4H9Br)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
51.0298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Propane, 2-bromo-2-methyl- = (Sodium ion (1+) • Propane, 2-bromo-2-methyl-)

By formula: Na+ + C4H9Br = (Na+ • C4H9Br)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
57.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Propane, 2-chloro-2-methyl- = (Sodium ion (1+) • Propane, 2-chloro-2-methyl-)

By formula: Na+ + C4H9Cl = (Na+ • C4H9Cl)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
57.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + N,N-Dimethylacetamide = (Sodium ion (1+) • N,N-Dimethylacetamide)

By formula: Na+ + C4H9NO = (Na+ • C4H9NO)

Quantity Value Units Method Reference Comment
ΔrH°157.kJ/molCIDTKlassen, Anderson, et al., 1996RCD

Sodium ion (1+) + L-Alanine, N-methyl- = (Sodium ion (1+) • L-Alanine, N-methyl-)

By formula: Na+ + C4H9NO2 = (Na+ • C4H9NO2)

Quantity Value Units Method Reference Comment
ΔrH°176. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.7; RCD

Sodium ion (1+) + dl-Threonine = (Sodium ion (1+) • dl-Threonine)

By formula: Na+ + C4H9NO3 = (Na+ • C4H9NO3)

Quantity Value Units Method Reference Comment
ΔrH°197.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Ethyl ether = (Sodium ion (1+) • Ethyl ether)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°130. ± 1.kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°118.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
89.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Ethyl ether) + Ethyl ether = (Sodium ion (1+) • 2Ethyl ether)

By formula: (Na+ • C4H10O) + C4H10O = (Na+ • 2C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°96. ± 1.kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

(Sodium ion (1+) • 2Ethyl ether) + Ethyl ether = (Sodium ion (1+) • 3Ethyl ether)

By formula: (Na+ • 2C4H10O) + C4H10O = (Na+ • 3C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°69. ± 1.kJ/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°123.J/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Sodium ion (1+) + 1-Butanol = (Sodium ion (1+) • 1-Butanol)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°109. ± 5.0kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
82.4298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 2-Propanol, 2-methyl- = (Sodium ion (1+) • 2-Propanol, 2-methyl-)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°117. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°116. ± 4.2kJ/molCIDTRodgers and Armentrout, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
89.5298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1-Propanol, 2-methyl- = (Sodium ion (1+) • 1-Propanol, 2-methyl-)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°105. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°105. ± 5.9kJ/molCIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + 2-Butanol = (Sodium ion (1+) • 2-Butanol)

By formula: Na+ + C4H10O = (Na+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°117. ± 5.0kJ/molCIDTRodgers and Armentrout, 1999RCD

Sodium ion (1+) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • Ethane, 1,2-dimethoxy-)

By formula: Na+ + C4H10O2 = (Na+ • C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°158. ± 4.2kJ/molCIDTArmentrout and Rodgers, 2000glyme; RCD
ΔrH°241. ± 18.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°161. ± 4.2kJ/molCIDTMore, Ray, et al., 1997RCD
ΔrH°197.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°145.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
133.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • 2Ethane, 1,2-dimethoxy-)

By formula: (Na+ • C4H10O2) + C4H10O2 = (Na+ • 2C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°116. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°114. ± 8.4kJ/molCIDTMore, Ray, et al., 1997RCD
ΔrH°147.kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°169.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) • 3Ethane, 1,2-dimethoxy-)

By formula: (Na+ • 2C4H10O2) + C4H10O2 = (Na+ • 3C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°97.1kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°177.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Sodium ion (1+) + Pyridine = (Sodium ion (1+) • Pyridine)

By formula: Na+ + C5H5N = (Na+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°127. ± 3.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Sodium ion (1+) + Guanine = (Sodium ion (1+) • Guanine)

By formula: Na+ + C5H5N5O = (Na+ • C5H5N5O)

Quantity Value Units Method Reference Comment
ΔrH°182.kJ/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + Adenine = (Sodium ion (1+) • Adenine)

By formula: Na+ + C5H5N5 = (Na+ • C5H5N5)

Quantity Value Units Method Reference Comment
ΔrH°140. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000, 2RCD
ΔrH°172.kJ/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + Thymine = (Sodium ion (1+) • Thymine)

By formula: Na+ + C5H6N2O2 = (Na+ • C5H6N2O2)

Quantity Value Units Method Reference Comment
ΔrH°135. ± 4.kJ/molCIDTRodgers and Armentrout, 2000, 2RCD
ΔrH°144.kJ/molCIDCCerda and Wesdemiotis, 1996RCD

Sodium ion (1+) + 3-Aminopyridine = (Sodium ion (1+) • 3-Aminopyridine)

By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°136. ± 4.kJ/molCIDTRodgers, 2001RCD

Sodium ion (1+) + 4-Aminopyridine = (Sodium ion (1+) • 4-Aminopyridine)

By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°146. ± 4.6kJ/molCIDTRodgers, 2001RCD

Sodium ion (1+) + 2-Aminopyridine = (Sodium ion (1+) • 2-Aminopyridine)

By formula: Na+ + C5H6N2 = (Na+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°146. ± 5.9kJ/molCIDTRodgers, 2001RCD

Sodium ion (1+) + 2-Cyclopenten-1-one = (Sodium ion (1+) • 2-Cyclopenten-1-one)

By formula: Na+ + C5H6O = (Na+ • C5H6O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
108.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + 1H-Pyrrole, 1-methyl- = (Sodium ion (1+) • 1H-Pyrrole, 1-methyl-)

By formula: Na+ + C5H7N = (Na+ • C5H7N)

Quantity Value Units Method Reference Comment
ΔrH°111. ± 3.kJ/molCIDTHuang and Rodgers, 2002RCD

Sodium ion (1+) + c-alanylglycine = (Sodium ion (1+) • c-alanylglycine)

By formula: Na+ + C5H8N2O2 = (Na+ • C5H8N2O2)

Quantity Value Units Method Reference Comment
ΔrH°149. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + 2-Butenal, 3-methyl- = (Sodium ion (1+) • 2-Butenal, 3-methyl-)

By formula: Na+ + C5H8O = (Na+ • C5H8O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
109.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + dl-Proline = (Sodium ion (1+) • dl-Proline)

By formula: Na+ + C5H9NO2 = (Na+ • C5H9NO2)

Quantity Value Units Method Reference Comment
ΔrH°175. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.3; RCD
ΔrH°196.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + L-Cysteine, N-acetyl- = (Sodium ion (1+) • L-Cysteine, N-acetyl-)

By formula: Na+ + C5H9NO3S = (Na+ • C5H9NO3S)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
129.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Alanine, N-acetyl- = (Sodium ion (1+) • L-Alanine, N-acetyl-)

By formula: Na+ + C5H9NO3 = (Na+ • C5H9NO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
134.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + DL-Glutamic acid = (Sodium ion (1+) • DL-Glutamic acid)

By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)

Quantity Value Units Method Reference Comment
ΔrH°204.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + N-acetyl-Ser = (Sodium ion (1+) • N-acetyl-Ser)

By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
142.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + C5H10N2O3S = (Sodium ion (1+) • C5H10N2O3S)

By formula: Na+ + C5H10N2O3S = (Na+ • C5H10N2O3S)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
144.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Glutamine = (Sodium ion (1+) • L-Glutamine)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Quantity Value Units Method Reference Comment
ΔrH°212.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Glycyl-dl-alanine = (Sodium ion (1+) • Glycyl-dl-alanine)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Quantity Value Units Method Reference Comment
ΔrH°179. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + N-dl-Alanylglycine = (Sodium ion (1+) • N-dl-Alanylglycine)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Quantity Value Units Method Reference Comment
ΔrH°178. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + L-Alanine, N-glycyl- = (Sodium ion (1+) • L-Alanine, N-glycyl-)

By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
149.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Serine, N-glycyl- = (Sodium ion (1+) • L-Serine, N-glycyl-)

By formula: Na+ + C5H10N2O4 = (Na+ • C5H10N2O4)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
156.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + 2-Pentanone = (Sodium ion (1+) • 2-Pentanone)

By formula: Na+ + C5H10O = (Na+ • C5H10O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
104.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + D-Ribose = (Sodium ion (1+) • D-Ribose)

By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)

Quantity Value Units Method Reference Comment
ΔrH°176.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + arabinose = (Sodium ion (1+) • arabinose)

By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)

Quantity Value Units Method Reference Comment
ΔrH°170.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + xylose = (Sodium ion (1+) • xylose)

By formula: Na+ + C5H10O5 = (Na+ • C5H10O5)

Quantity Value Units Method Reference Comment
ΔrH°171.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + DL-Valine = (Sodium ion (1+) • DL-Valine)

By formula: Na+ + C5H11NO2 = (Na+ • C5H11NO2)

Quantity Value Units Method Reference Comment
ΔrH°173. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.1; RCD
ΔrH°173.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Methane, diethoxy- = (Sodium ion (1+) • Methane, diethoxy-)

By formula: Na+ + C5H12O2 = (Na+ • C5H12O2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
115.298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Sodium ion (1+) + Benzene, fluoro- = (Sodium ion (1+) • Benzene, fluoro-)

By formula: Na+ + C6H5F = (Na+ • C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°70. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Sodium ion (1+) • Benzene, fluoro-) + Benzene, fluoro- = (Sodium ion (1+) • 2Benzene, fluoro-)

By formula: (Na+ • C6H5F) + C6H5F = (Na+ • 2C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°66. ± 4.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

Sodium ion (1+) + Phenol = (Sodium ion (1+) • Phenol)

By formula: Na+ + C6H6O = (Na+ • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°102. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002RCD
ΔrH°98. ± 3.kJ/molCIDTArmentrout and Rodgers, 2000RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
69.9298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Phenol) + Phenol = (Sodium ion (1+) • 2Phenol)

By formula: (Na+ • C6H6O) + C6H6O = (Na+ • 2C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°82. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002RCD

Sodium ion (1+) + Benzene = (Sodium ion (1+) • Benzene)

By formula: Na+ + C6H6 = (Na+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°95.4 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°88.3 ± 5.0kJ/molCIDTAmicangelo and Armentrout, 2000RCD
ΔrH°88.3 ± 4.6kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°117.kJ/molHPMSGuo, Purnell, et al., 1990gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°131.J/mol*KHPMSGuo, Purnell, et al., 1990gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
65.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Benzene) + Benzene = (Sodium ion (1+) • 2Benzene)

By formula: (Na+ • C6H6) + C6H6 = (Na+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°81. ± 5.kJ/molAVGN/AAverage of 7 values; Individual data points

Sodium ion (1+) + Pyridine, 4-methyl- = (Sodium ion (1+) • Pyridine, 4-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°133. ± 4.kJ/molCIDTRodgers, 2001, 2RCD

Sodium ion (1+) + Pyridine, 3-methyl- = (Sodium ion (1+) • Pyridine, 3-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°133. ± 4.2kJ/molCIDTRodgers, 2001, 2RCD

Sodium ion (1+) + Pyridine, 2-methyl- = (Sodium ion (1+) • Pyridine, 2-methyl-)

By formula: Na+ + C6H7N = (Na+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°128. ± 4.6kJ/molCIDTRodgers, 2001, 2RCD

Sodium ion (1+) + N-acetyl-L-aspartic acid = (Sodium ion (1+) • N-acetyl-L-aspartic acid)

By formula: Na+ + C6H9NO5 = (Na+ • C6H9NO5)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
146.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Histidine = (Sodium ion (1+) • Histidine)

By formula: Na+ + C6H9N3O2 = (Na+ • C6H9N3O2)

Quantity Value Units Method Reference Comment
ΔrH°219.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + 2,5-Piperazinedione, 3,6-dimethyl-, trans- = (Sodium ion (1+) • 2,5-Piperazinedione, 3,6-dimethyl-, trans-)

By formula: Na+ + C6H10N2O2 = (Na+ • C6H10N2O2)

Quantity Value Units Method Reference Comment
ΔrH°151. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + L-Aspartic acid, N-glycyl- = (Sodium ion (1+) • L-Aspartic acid, N-glycyl-)

By formula: Na+ + C6H10N2O5 = (Na+ • C6H10N2O5)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
161.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + DL-Alanine, N-DL-alanyl- = (Sodium ion (1+) • DL-Alanine, N-DL-alanyl-)

By formula: Na+ + C6H12N2O3 = (Na+ • C6H12N2O3)

Quantity Value Units Method Reference Comment
ΔrH°180. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + Glycylglycine ethyl ester = (Sodium ion (1+) • Glycylglycine ethyl ester)

By formula: Na+ + C6H12N2O4 = (Na+ • C6H12N2O4)

Quantity Value Units Method Reference Comment
ΔrH°181. ± 7.1kJ/molCIDCCerda, Hoyau, et al., 1998RCD

Sodium ion (1+) + L-Threonine, N-glycyl- = (Sodium ion (1+) • L-Threonine, N-glycyl-)

By formula: Na+ + C6H12N2O4 = (Na+ • C6H12N2O4)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
162.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glucose = (Sodium ion (1+) • Glucose)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
ΔrH°174.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + d-Mannose = (Sodium ion (1+) • d-Mannose)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
ΔrH°179.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + C6H12O6 = (Sodium ion (1+) • C6H12O6)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
ΔrH°177.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + DL-Leucine = (Sodium ion (1+) • DL-Leucine)

By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)

Quantity Value Units Method Reference Comment
ΔrH°175.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + DL-Isoleucine = (Sodium ion (1+) • DL-Isoleucine)

By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)

Quantity Value Units Method Reference Comment
ΔrH°176.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + methylvaline = (Sodium ion (1+) • methylvaline)

By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)

Quantity Value Units Method Reference Comment
ΔrH°179. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.8; RCD

Sodium ion (1+) + dl-Lysine = (Sodium ion (1+) • dl-Lysine)

By formula: Na+ + C6H14N2O2 = (Na+ • C6H14N2O2)

Quantity Value Units Method Reference Comment
ΔrH°>213.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Arginine = (Sodium ion (1+) • Arginine)

By formula: Na+ + C6H14N4O2 = (Na+ • C6H14N4O2)

Quantity Value Units Method Reference Comment
ΔrH°>225.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + Anisole = (Sodium ion (1+) • Anisole)

By formula: Na+ + C7H8O = (Na+ • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°113. ± 8.4kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Sodium ion (1+) • Anisole) + Anisole = (Sodium ion (1+) • 2Anisole)

By formula: (Na+ • C7H8O) + C7H8O = (Na+ • 2C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°90. ± 3.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Sodium ion (1+) + Toluene = (Sodium ion (1+) • Toluene)

By formula: Na+ + C7H8 = (Na+ • C7H8)

Quantity Value Units Method Reference Comment
ΔrH°112. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Sodium ion (1+) • Toluene) + Toluene = (Sodium ion (1+) • 2Toluene)

By formula: (Na+ • C7H8) + C7H8 = (Na+ • 2C7H8)

Quantity Value Units Method Reference Comment
ΔrH°87. ± 2.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

Sodium ion (1+) + L-Proline, 1-acetyl- = (Sodium ion (1+) • L-Proline, 1-acetyl-)

By formula: Na+ + C7H10NO3 = (Na+ • C7H10NO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
147.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + N-Acetyl-L-glutamic acid = (Sodium ion (1+) • N-Acetyl-L-glutamic acid)

By formula: Na+ + C7H11NO5 = (Na+ • C7H11NO5)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
155.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-proline = (Sodium ion (1+) • Glycyl-L-proline)

By formula: Na+ + C7H12N2O3 = (Na+ • C7H12N2O3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
163.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-glutamic acid = (Sodium ion (1+) • Glycyl-L-glutamic acid)

By formula: Na+ + C7H12N2O5 = (Na+ • C7H12N2O5)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
170.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Methionine, N-acetyl- = (Sodium ion (1+) • L-Methionine, N-acetyl-)

By formula: Na+ + C7H13NO3S = (Na+ • C7H13NO3S)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
144.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Valine, N-acetyl- = (Sodium ion (1+) • L-Valine, N-acetyl-)

By formula: Na+ + C7H13NO3 = (Na+ • C7H13NO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
140.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + C7H14N2O3S = (Sodium ion (1+) • C7H14N2O3S)

By formula: Na+ + C7H14N2O3S = (Na+ • C7H14N2O3S)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
156.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Valine, N-glycyl- = (Sodium ion (1+) • L-Valine, N-glycyl-)

By formula: Na+ + C7H14N2O3 = (Na+ • C7H14N2O3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
154.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + N-Acetyl-L-leucine = (Sodium ion (1+) • N-Acetyl-L-leucine)

By formula: Na+ + C8H15NO3 = (Na+ • C8H15NO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
142.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + L-Leucine, N-glycyl- = (Sodium ion (1+) • L-Leucine, N-glycyl-)

By formula: Na+ + C8H16N2O3 = (Na+ • C8H16N2O3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
154.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + 12-Crown-4 = (Sodium ion (1+) • 12-Crown-4)

By formula: Na+ + C8H16O4 = (Na+ • C8H16O4)

Quantity Value Units Method Reference Comment
ΔrH°372. ± 51.kJ/molCIDTMore, Ray, et al., 1997RCD

Sodium ion (1+) + DL-Phenylalanine = (Sodium ion (1+) • DL-Phenylalanine)

By formula: Na+ + C9H11NO2 = (Na+ • C9H11NO2)

Quantity Value Units Method Reference Comment
ΔrH°198. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.5; RCD
ΔrH°198.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + 2-Amino-3-(4-hydroxyphenyl)-propanoic acid = (Sodium ion (1+) • 2-Amino-3-(4-hydroxyphenyl)-propanoic acid)

By formula: Na+ + C9H11NO3 = (Na+ • C9H11NO3)

Quantity Value Units Method Reference Comment
ΔrH°201.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + 15-Crown-5 = (Sodium ion (1+) • 15-Crown-5)

By formula: Na+ + C10H20O5 = (Na+ • C10H20O5)

Quantity Value Units Method Reference Comment
ΔrH°294. ± 18.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°298. ± 18.kJ/molCIDTMore, Ray, et al., 1999RCD

Sodium ion (1+) + Tryptophan = (Sodium ion (1+) • Tryptophan)

By formula: Na+ + C11H12N2O2 = (Na+ • C11H12N2O2)

Quantity Value Units Method Reference Comment
ΔrH°205. ± 13.kJ/molIMREGapeev and Dunbar, 2003Anchor glycine=38.5+-2.6; RCD
ΔrH°210.kJ/molCIDCKish, Ohanessian, et al., 2003Anchor alanine=39.89; RCD

Sodium ion (1+) + L-Phenylalanine, N-acetyl- = (Sodium ion (1+) • L-Phenylalanine, N-acetyl-)

By formula: Na+ + C11H13NO3 = (Na+ • C11H13NO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
146.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + N-acetyl-L-tyrosine = (Sodium ion (1+) • N-acetyl-L-tyrosine)

By formula: Na+ + C11H13NO4 = (Na+ • C11H13NO4)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
145.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-phenyl alanine = (Sodium ion (1+) • Glycyl-L-phenyl alanine)

By formula: Na+ + C11H14N2O3 = (Na+ • C11H14N2O3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
159.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-tyrosine = (Sodium ion (1+) • Glycyl-L-tyrosine)

By formula: Na+ + C11H14N2O4 = (Na+ • C11H14N2O4)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
159.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Lactose = (Sodium ion (1+) • Lactose)

By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)

Quantity Value Units Method Reference Comment
ΔrH°204.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + gentiobiose = (Sodium ion (1+) • gentiobiose)

By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)

Quantity Value Units Method Reference Comment
ΔrH°201.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + C12H22O11 = (Sodium ion (1+) • C12H22O11)

By formula: Na+ + C12H22O11 = (Na+ • C12H22O11)

Quantity Value Units Method Reference Comment
ΔrH°198.kJ/molCIDCCerda and Wesdemiotis, 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0298.CIDCCerda and Wesdemiotis, 1999RCD

Sodium ion (1+) + 1,4,7,10,13,16-Hexaoxacyclooctadecane = (Sodium ion (1+) • 1,4,7,10,13,16-Hexaoxacyclooctadecane)

By formula: Na+ + C12H24O6 = (Na+ • C12H24O6)

Quantity Value Units Method Reference Comment
ΔrH°296. ± 19.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°300. ± 19.kJ/molCIDTMore, Ray, et al., 1999RCD

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD
0.0298.CIDTMore, Ray, et al., 1999RCD

Sodium ion (1+) + L-Tryptophan, N-acetyl- = (Sodium ion (1+) • L-Tryptophan, N-acetyl-)

By formula: Na+ + C13H14NO3 = (Na+ • C13H14NO3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
156.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + Glycyl-L-tryptophan = (Sodium ion (1+) • Glycyl-L-tryptophan)

By formula: Na+ + C13H15N2O3 = (Na+ • C13H15N2O3)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
172.0.CIDCFeng, Gronert, et al., 1999RCD

Sodium ion (1+) + sodium chloride = (Sodium ion (1+) • sodium chloride)

By formula: Na+ + ClNa = (Na+ • ClNa)

Quantity Value Units Method Reference Comment
ΔrH°177.kJ/molMSChupka, 1959gas phase; Knudsen cell; M
Quantity Value Units Method Reference Comment
ΔrS°73.6J/mol*KMSChupka, 1959gas phase; Knudsen cell; M

Sodium ion (1+) + sodium fluoride = (Sodium ion (1+) • sodium fluoride)

By formula: Na+ + FNa = (Na+ • FNa)

Quantity Value Units Method Reference Comment
ΔrH°262.kJ/molMSTsirlina, Gusarov, et al., 1986gas phase; Knudsen cell; M

(Sodium ion (1+) • sodium fluoride) + sodium fluoride = (Sodium ion (1+) • 2sodium fluoride)

By formula: (Na+ • FNa) + FNa = (Na+ • 2FNa)

Quantity Value Units Method Reference Comment
ΔrH°200.kJ/molMSTsirlina, Gusarov, et al., 1986gas phase; Knudsen cell; M

Sodium ion (1+) + F3Sc = (Sodium ion (1+) • F3Sc)

By formula: Na+ + F3Sc = (Na+ • F3Sc)

Quantity Value Units Method Reference Comment
ΔrH°140.kJ/molMSTsirlina, Gusarov, et al., 1986gas phase; Knudsen cell; M

Sodium ion (1+) + Hydrogen chloride = (Sodium ion (1+) • Hydrogen chloride)

By formula: Na+ + HCl = (Na+ • HCl)

Quantity Value Units Method Reference Comment
ΔrH°51.0kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°85.4J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Sodium ion (1+) + Nitric acid = (Sodium ion (1+) • Nitric acid)

By formula: Na+ + HNO3 = (Na+ • HNO3)

Quantity Value Units Method Reference Comment
ΔrH°86.2kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.9J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Sodium ion (1+) + Water = (Sodium ion (1+) • Water)

By formula: Na+ + H2O = (Na+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°100.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°87.9 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°82.0 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°95.0 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°111.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M
Quantity Value Units Method Reference Comment
ΔrS°90.0J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°92.J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
94.6 (+7.5,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
65.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • Water)

By formula: (Na+ • H2O) + CO2 = (Na+ • CO2 • H2O)

Quantity Value Units Method Reference Comment
ΔrH°52.7kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°94.1J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Sodium ion (1+) • 2Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • 2Water)

By formula: (Na+ • 2H2O) + CO2 = (Na+ • CO2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°43.1kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Sodium ion (1+) • 3Water) + Carbon dioxide = (Sodium ion (1+) • Carbon dioxide • 3Water)

By formula: (Na+ • 3H2O) + CO2 = (Na+ • CO2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°30.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/APeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°-1.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • Water • Carbon dioxide) + Water = (Sodium ion (1+) • 2Water • Carbon dioxide)

By formula: (Na+ • H2O • CO2) + H2O = (Na+ • 2H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°72.8kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°98.7J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • 2Water • Carbon dioxide) + Water = (Sodium ion (1+) • 3Water • Carbon dioxide)

By formula: (Na+ • 2H2O • CO2) + H2O = (Na+ • 3H2O • CO2)

Quantity Value Units Method Reference Comment
ΔrH°51.9kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrG°23.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • Water) + Water = (Sodium ion (1+) • 2Water)

By formula: (Na+ • H2O) + H2O = (Na+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°79. ± 8.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
82.0 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 2Water) + Water = (Sodium ion (1+) • 3Water)

By formula: (Na+ • 2H2O) + H2O = (Na+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°62.3kJ/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°66.1kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°69.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°67.4kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrH°70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°87.0J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°91.6J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°92.0J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°40.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
70.3 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 3Water) + Water = (Sodium ion (1+) • 4Water)

By formula: (Na+ • 3H2O) + H2O = (Na+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°55. ± 4.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°99. ± 10.J/mol*KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrG°26.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
54.8 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
27.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 4Water) + Water = (Sodium ion (1+) • 5Water)

By formula: (Na+ • 4H2O) + H2O = (Na+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°44.8kJ/molHPMSTang, Lian, et al., 1976gas phase; M
ΔrH°48.5kJ/molHPMSTang and Castleman, 1972gas phase; M
ΔrH°51.5kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°104.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
ΔrS°111.J/mol*KHPMSTang and Castleman, 1972gas phase; M
ΔrS°118.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Sodium ion (1+) • 5Water) + Water = (Sodium ion (1+) • 6Water)

By formula: (Na+ • 5H2O) + H2O = (Na+ • 6H2O)

Quantity Value Units Method Reference Comment
ΔrH°44.8kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°109.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Sodium ion (1+) • Water) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide • Water)

By formula: (Na+ • H2O) + O2S = (Na+ • O2S • H2O)

Quantity Value Units Method Reference Comment
ΔrH°59.0kJ/molHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°72.8J/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M

(Sodium ion (1+) • 3Water) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide • 3Water)

By formula: (Na+ • 3H2O) + O2S = (Na+ • O2S • 3H2O)

Quantity Value Units Method Reference Comment
ΔrG°20.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

Sodium ion (1+) + Hydrogen = (Sodium ion (1+) • Hydrogen)

By formula: Na+ + H2 = (Na+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°12.3kJ/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 10.3 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°55.2J/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 10.3 kJ/mol; M

(Sodium ion (1+) • Hydrogen) + Hydrogen = (Sodium ion (1+) • 2Hydrogen)

By formula: (Na+ • H2) + H2 = (Na+ • 2H2)

Quantity Value Units Method Reference Comment
ΔrH°10.1kJ/molSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 9.41 kJ/mol; M
Quantity Value Units Method Reference Comment
ΔrS°51.9J/mol*KSIDTBushnell, Kemper, et al., 1994gas phase; ΔrH(0K) = 9.41 kJ/mol; M

Sodium ion (1+) + Ammonia = (Sodium ion (1+) • Ammonia)

By formula: Na+ + H3N = (Na+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°102. ± 5.4kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°102. ± 5.4kJ/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°107. ± 0.8kJ/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°122.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°91200.J/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°108.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
77.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Ammonia) + Ammonia = (Sodium ion (1+) • 2Ammonia)

By formula: (Na+ • H3N) + H3N = (Na+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°93. ± 5.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°105.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 2Ammonia) + Ammonia = (Sodium ion (1+) • 3Ammonia)

By formula: (Na+ • 2H3N) + H3N = (Na+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°71.5kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 3Ammonia) + Ammonia = (Sodium ion (1+) • 4Ammonia)

By formula: (Na+ • 3H3N) + H3N = (Na+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°61.5kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°121.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 4Ammonia) + Ammonia = (Sodium ion (1+) • 5Ammonia)

By formula: (Na+ • 4H3N) + H3N = (Na+ • 5H3N)

Quantity Value Units Method Reference Comment
ΔrH°44.8kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°125.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Sodium ion (1+) • 5Ammonia) + Ammonia = (Sodium ion (1+) • 6Ammonia)

By formula: (Na+ • 5H3N) + H3N = (Na+ • 6H3N)

Quantity Value Units Method Reference Comment
ΔrH°41.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°124.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Sodium ion (1+) + helium = (Sodium ion (1+) • helium)

By formula: Na+ + He = (Na+ • He)

Quantity Value Units Method Reference Comment
ΔrH°4.98kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°3.3kJ/molIMobViehland, 1984gas phase; M
ΔrH°3.9kJ/molIMobMason and Sharp, 1958gas phase; M
ΔrH°5.77kJ/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + Krypton = (Sodium ion (1+) • Krypton)

By formula: Na+ + Kr = (Na+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°20.3kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°21.3kJ/molIMobViehland, 1984gas phase; M
ΔrH°24.kJ/molDTMcKnight and Sawina, 1973gas phase; M
ΔrH°27.5kJ/molIMobTakebe, 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.4J/mol*KDTMcKnight and Sawina, 1973gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°33.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.2310.FAPerry, Rowe, et al., 1980gas phase; M
8.4310.DTBeyer and Keller, 1971gas phase; low E/N; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.3J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-1.310.FAPerry, Rowe, et al., 1980gas phase; M

(Sodium ion (1+) • sodium) + sodium = (Sodium ion (1+) • 2sodium)

By formula: (Na+ • Na) + Na = (Na+ • 2Na)

Quantity Value Units Method Reference Comment
ΔrH°133.kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 2sodium) + sodium = (Sodium ion (1+) • 3sodium)

By formula: (Na+ • 2Na) + Na = (Na+ • 3Na)

Quantity Value Units Method Reference Comment
ΔrH°56.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 3sodium) + sodium = (Sodium ion (1+) • 4sodium)

By formula: (Na+ • 3Na) + Na = (Na+ • 4Na)

Quantity Value Units Method Reference Comment
ΔrH°84.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 4sodium) + sodium = (Sodium ion (1+) • 5sodium)

By formula: (Na+ • 4Na) + Na = (Na+ • 5Na)

Quantity Value Units Method Reference Comment
ΔrH°57.7kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 5sodium) + sodium = (Sodium ion (1+) • 6sodium)

By formula: (Na+ • 5Na) + Na = (Na+ • 6Na)

Quantity Value Units Method Reference Comment
ΔrH°110.kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 6sodium) + sodium = (Sodium ion (1+) • 7sodium)

By formula: (Na+ • 6Na) + Na = (Na+ • 7Na)

Quantity Value Units Method Reference Comment
ΔrH°73.2kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 7sodium) + sodium = (Sodium ion (1+) • 8sodium)

By formula: (Na+ • 7Na) + Na = (Na+ • 8Na)

Quantity Value Units Method Reference Comment
ΔrH°126.kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 8sodium) + sodium = (Sodium ion (1+) • 9sodium)

By formula: (Na+ • 8Na) + Na = (Na+ • 9Na)

Quantity Value Units Method Reference Comment
ΔrH°75.3kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; ΔrH<; M

(Sodium ion (1+) • 9sodium) + sodium = (Sodium ion (1+) • 10sodium)

By formula: (Na+ • 9Na) + Na = (Na+ • 10Na)

Quantity Value Units Method Reference Comment
ΔrH°75.3kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 10sodium) + sodium = (Sodium ion (1+) • 11sodium)

By formula: (Na+ • 10Na) + Na = (Na+ • 11Na)

Quantity Value Units Method Reference Comment
ΔrH°65.7kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 11sodium) + sodium = (Sodium ion (1+) • 12sodium)

By formula: (Na+ • 11Na) + Na = (Na+ • 12Na)

Quantity Value Units Method Reference Comment
ΔrH°87.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 12sodium) + sodium = (Sodium ion (1+) • 13sodium)

By formula: (Na+ • 12Na) + Na = (Na+ • 13Na)

Quantity Value Units Method Reference Comment
ΔrH°69.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 13sodium) + sodium = (Sodium ion (1+) • 14sodium)

By formula: (Na+ • 13Na) + Na = (Na+ • 14Na)

Quantity Value Units Method Reference Comment
ΔrH°76.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 14sodium) + sodium = (Sodium ion (1+) • 15sodium)

By formula: (Na+ • 14Na) + Na = (Na+ • 15Na)

Quantity Value Units Method Reference Comment
ΔrH°66.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 15sodium) + sodium = (Sodium ion (1+) • 16sodium)

By formula: (Na+ • 15Na) + Na = (Na+ • 16Na)

Quantity Value Units Method Reference Comment
ΔrH°79.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 16sodium) + sodium = (Sodium ion (1+) • 17sodium)

By formula: (Na+ • 16Na) + Na = (Na+ • 17Na)

Quantity Value Units Method Reference Comment
ΔrH°82.8kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 17sodium) + sodium = (Sodium ion (1+) • 18sodium)

By formula: (Na+ • 17Na) + Na = (Na+ • 18Na)

Quantity Value Units Method Reference Comment
ΔrH°87.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 18sodium) + sodium = (Sodium ion (1+) • 19sodium)

By formula: (Na+ • 18Na) + Na = (Na+ • 19Na)

Quantity Value Units Method Reference Comment
ΔrH°82.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 19sodium) + sodium = (Sodium ion (1+) • 20sodium)

By formula: (Na+ • 19Na) + Na = (Na+ • 20Na)

Quantity Value Units Method Reference Comment
ΔrH°89.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 22sodium) + sodium = (Sodium ion (1+) • 23sodium)

By formula: (Na+ • 22Na) + Na = (Na+ • 23Na)

Quantity Value Units Method Reference Comment
ΔrH°71.5kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 23sodium) + sodium = (Sodium ion (1+) • 24sodium)

By formula: (Na+ • 23Na) + Na = (Na+ • 24Na)

Quantity Value Units Method Reference Comment
ΔrH°79.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 24sodium) + sodium = (Sodium ion (1+) • 25sodium)

By formula: (Na+ • 24Na) + Na = (Na+ • 25Na)

Quantity Value Units Method Reference Comment
ΔrH°76.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 25sodium) + sodium = (Sodium ion (1+) • 26sodium)

By formula: (Na+ • 25Na) + Na = (Na+ • 26Na)

Quantity Value Units Method Reference Comment
ΔrH°81.2kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 26sodium) + sodium = (Sodium ion (1+) • 27sodium)

By formula: (Na+ • 26Na) + Na = (Na+ • 27Na)

Quantity Value Units Method Reference Comment
ΔrH°76.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 27sodium) + sodium = (Sodium ion (1+) • 28sodium)

By formula: (Na+ • 27Na) + Na = (Na+ • 28Na)

Quantity Value Units Method Reference Comment
ΔrH°84.1kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 28sodium) + sodium = (Sodium ion (1+) • 29sodium)

By formula: (Na+ • 28Na) + Na = (Na+ • 29Na)

Quantity Value Units Method Reference Comment
ΔrH°82.8kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 29sodium) + sodium = (Sodium ion (1+) • 30sodium)

By formula: (Na+ • 29Na) + Na = (Na+ • 30Na)

Quantity Value Units Method Reference Comment
ΔrH°85.8kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 30sodium) + sodium = (Sodium ion (1+) • 31sodium)

By formula: (Na+ • 30Na) + Na = (Na+ • 31Na)

Quantity Value Units Method Reference Comment
ΔrH°81.2kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 31sodium) + sodium = (Sodium ion (1+) • 32sodium)

By formula: (Na+ • 31Na) + Na = (Na+ • 32Na)

Quantity Value Units Method Reference Comment
ΔrH°87.9kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 32sodium) + sodium = (Sodium ion (1+) • 33sodium)

By formula: (Na+ • 32Na) + Na = (Na+ • 33Na)

Quantity Value Units Method Reference Comment
ΔrH°88.7kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 33sodium) + sodium = (Sodium ion (1+) • 34sodium)

By formula: (Na+ • 33Na) + Na = (Na+ • 34Na)

Quantity Value Units Method Reference Comment
ΔrH°91.6kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 34sodium) + sodium = (Sodium ion (1+) • 35sodium)

By formula: (Na+ • 34Na) + Na = (Na+ • 35Na)

Quantity Value Units Method Reference Comment
ΔrH°82.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

(Sodium ion (1+) • 35sodium) + sodium = (Sodium ion (1+) • 36sodium)

By formula: (Na+ • 35Na) + Na = (Na+ • 36Na)

Quantity Value Units Method Reference Comment
ΔrH°87.0kJ/molPDissBrechignac, Cahuzac, et al., 1989gas phase; M

Sodium ion (1+) + neon = (Sodium ion (1+) • neon)

By formula: Na+ + Ne = (Na+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°7.36kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°6.36kJ/molIMobViehland, 1984gas phase; M
ΔrH°6.07kJ/molIMobTakebe, 1983gas phase; M

Sodium ion (1+) + Sulfur dioxide = (Sodium ion (1+) • Sulfur dioxide)

By formula: Na+ + O2S = (Na+ • O2S)

Quantity Value Units Method Reference Comment
ΔrH°79.1kJ/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°84.9J/mol*KN/APerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°53.6kJ/molFAPerry, Rowe, et al., 1980gas phase; Entropy change calculated or estimated; M

(Sodium ion (1+) • Sulfur dioxide) + Water = (Sodium ion (1+) • Water • Sulfur dioxide)

By formula: (Na+ • O2S) + H2O = (Na+ • H2O • O2S)

Quantity Value Units Method Reference Comment
ΔrH°82.8kJ/molHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M

(Sodium ion (1+) • Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 2Sulfur dioxide)

By formula: (Na+ • O2S) + O2S = (Na+ • 2O2S)

Quantity Value Units Method Reference Comment
ΔrH°69.5kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°107.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • 2Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 3Sulfur dioxide)

By formula: (Na+ • 2O2S) + O2S = (Na+ • 3O2S)

Quantity Value Units Method Reference Comment
ΔrH°59.8kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°113.J/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(Sodium ion (1+) • 3Sulfur dioxide) + Sulfur dioxide = (Sodium ion (1+) • 4Sulfur dioxide)

By formula: (Na+ • 3O2S) + O2S = (Na+ • 4O2S)

Quantity Value Units Method Reference Comment
ΔrH°51.5kJ/molHPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/ACastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.328.HPMSCastleman, Peterson, et al., 1983gas phase; Entropy change calculated or estimated; M

Sodium ion (1+) + Oxygen = (Sodium ion (1+) • Oxygen)

By formula: Na+ + O2 = (Na+ • O2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.8310.DTKeller and Beyer, 1971gas phase; low E/N; M

Sodium ion (1+) + Ozone = (Sodium ion (1+) • Ozone)

By formula: Na+ + O3 = (Na+ • O3)

Quantity Value Units Method Reference Comment
ΔrH°52.3kJ/molFARowe, Viggiano, et al., 1982gas phase; M

Sodium ion (1+) + Xenon = (Sodium ion (1+) • Xenon)

By formula: Na+ + Xe = (Na+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°25.0kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°24.9kJ/molIMobViehland, 1984gas phase; M
ΔrH°39.8kJ/molIMobTakebe, 1983gas phase; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Blades, Klassen, et al., 1996
Blades, A.T.; Klassen, J.S.; Kebarle, P., Determination of Ion-Solvent Equilibria in the Gas Phase. Hydration of Diprotonated Diamines and Bis(trimethylammonium) Alkanes, J. Am. Chem. Soc., 1996, 118, 49, 12437, https://doi.org/10.1021/ja962641t . [all data]

Dalleska, Tjelta, et al., 1994
Dalleska, N.F.; Tjelta, B.L.; Armentrout, P.B., Sequential Bond Energies of Water to Na+ (3s0), Mg+ (3s1), and Al+ (3s2), J. Phys. Chem., 1994, 98, 15, 4191, https://doi.org/10.1021/j100066a045 . [all data]

Klassen, Blades, et al., 1995
Klassen, J.S.; Blades, A.T.; Kebarle, P., Determinations of Ion-Molecule Equilibria Involving Ions Produced by Electrospray. Hydration of Protonated Amines, Diamines, and Some Small Peptides, J. Phys. Chem., 1995, 99, 42, 15509, https://doi.org/10.1021/j100042a027 . [all data]

Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P., Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry, J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Tang, Lian, et al., 1976
Tang, I.N.; Lian, M.S.; Castleman, A.W., Mass Spectrometric Study of Gas - Phase Clustering Reactions: Hydration of the Monovalent Strontium Ion, J. Chem. Phys., 1976, 65, 10, 4022, https://doi.org/10.1063/1.432854 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Amicangelo and Armentrout, 2001
Amicangelo, J.C.; Armentrout, P.B., Relative and Absolute Bond Dissociation Energies of Sodium Cation Complexes Determined Using Competitive Collision-Induced Dissociation Experiments, Int. J. Mass Spectrom., 2001, 212, 1-3, 301, https://doi.org/10.1016/S1387-3806(01)00494-8 . [all data]

Burdett and Hayhurst, 1982
Burdett, N.A.; Hayhurst, A.N., Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer., J. Chem. Soc. Faraday Trans. 1, 1982, 78, 2997. [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]

Tang and Castleman, 1972
Tang, I.N.; Castleman, A.W., Mass Spectrometric Study of the Gas - Phase Hydration of the Monovalent Lead Ion, J. Chem. Phys., 1972, 57, 9, 3638, https://doi.org/10.1063/1.1678820 . [all data]

Peterson, Mark, et al., 1984
Peterson, K.I.; Mark, T.D.; Keesee, R.G.; Castleman, A.W., Thermochemical Properties of Gas - Phase Mixed Clusters: H2O/CO2 with Na+, J. Phys. Chem., 1984, 88, 13, 2880, https://doi.org/10.1021/j150657a042 . [all data]

Perry, Rowe, et al., 1980
Perry, R.A.; Rowe, B.R.; Viggiano, A.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C., Laboratory Measurements of Stratospheric Sodium Ion Measurements, Geophys. Res. Lett., 1980, 7, 9, 693, https://doi.org/10.1029/GL007i009p00693 . [all data]

Castleman, Holland, et al., 1978
Castleman, A.W.; Holland, P.M.; Lindsay, D.M.; Peterson, K.I., The Properties of Clusters in the Gas Phase. 2. Ammonia about Metal Ions, J. Am. Chem. Soc., 1978, 100, 19, 6039, https://doi.org/10.1021/ja00487a011 . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

Hoyau, Norrman, et al., 1999
Hoyau, S.; Norrman, K.; McMahon, T.B.; Ohanessian, G., A Quantitative Basis for a Scale of Na+ Affinities of Organic and Small Biological Molecules in the Gas Phase, J. Am. Chem. Soc., 1999, 121, 38, 8864, https://doi.org/10.1021/ja9841198 . [all data]

Klassen, Anderson, et al., 1996
Klassen, J.S.; Anderson, S.G.; Blades, A.T.; Kebarle, P., Reaction Enthalpies for M+L = M+ + L, Where M+ = Na+ and K+ and L = Acetamide, N-Methylacetamide, N,N-Dimethylacetamide, Glycine, and Glycylglycine, from Determinations of the Collision-Induced Dissociation Thresholds, J. Phys. Chem., 1996, 100, 33, 14218, https://doi.org/10.1021/jp9608382 . [all data]

Guo, Conklin, et al., 1989
Guo, B.C.; Conklin, B.J.; Castleman, A.W., Thermochemical Properties of Ion Complexes Na+(M)n in the Gas Phase, J. Am. Chem. Soc., 1989, 111, 17, 6506, https://doi.org/10.1021/ja00199a005 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Guo, Purnell, et al., 1990
Guo, B.C.; Purnell, J.W.; Castleman, A.W., The Clustering Reactions of Benzene with Sodium and Lead Ions, Chem. Phys. Lett., 1990, 168, 2, 155, https://doi.org/10.1016/0009-2614(90)85122-S . [all data]

More, Ray, et al., 1997
More, M.B.; Ray, D.; Armentrout, P.B., Cation-ether complexes in the gas phase: Bond dissociation energies of Na+(dimethyl ether)(x), x=1-4; Na+(1,2-dimethoxyethane)(x), x=1 and 2; and Na+(12-crown-4), J. Phys. Chem. AJOURNAL OF PHYSICAL CHEMISTRY A 101 (5): 831-839 JAN 30 1997, 1997, 101, 831. [all data]

Castleman, Peterson, et al., 1983
Castleman, A.W.; Peterson, K.I.; Upschulte, B.L.; Schelling, F.J., Energetics and Structure of Na+ Cluster Ions, Int. J. Mass Spectrom. Ion Phys., 1983, 47, 203, https://doi.org/10.1016/0020-7381(83)87171-X . [all data]

Keller and Beyer, 1971
Keller, G.E.; Beyer, R.A., CO2 and O2 Clustering to Sodium Ions, J. Geophys. Res., 1971, 74, 1, 289, https://doi.org/10.1029/JA076i001p00289 . [all data]

Rodgers and Armentrout, 1999
Rodgers, M.T.; Armentrout, P.B., Absolute Binding Energies of Sodium Ions to Short-Chain Alcohols, CnH2n+2O, n=1-4, Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, 1999, 4955. [all data]

Guo and Castleman, 1990
Guo, B.C.; Castleman, A.W., The Association Reactions of Pb+ Ion with CH3OH and CH3NH2 in the Gas Phase, Int. J. Mass Spectrom. Ion Proc., 1990, 100, 665, https://doi.org/10.1016/0168-1176(90)85101-7 . [all data]

Gislason, 1984
Gislason, E.A., Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Viehland, 1984
Viehland, L.A., Interaction Potentials for Li+ - Rare - Gas Systems, Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3 . [all data]

McKnight and Sawina, 1973
McKnight, L.G.; Sawina, J.M., Equilibrium Constants and Binding Energies of Alkali Metal Ions with Inert Gases, Bull. Am. Phys. Soc., 1973, 18, 804. [all data]

Takebe, 1983
Takebe, M., The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves, J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763 . [all data]

Valina, 2001
Valina, A.B., Collision-Induced Dissociation and Theoretical Studies of Na+-Acetonitrile Complexes, J. Phys. Chem. A, 2001, 105, 49, 11057, https://doi.org/10.1021/jp0128123 . [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Ionic Solvation by Aprotic Solvents. Gas Phase Solvation of the Alkali Ions by Acetonitrile, J. Am. Chem. Soc., 1976, 98, 20, 6125, https://doi.org/10.1021/ja00436a010 . [all data]

Beyer and Keller, 1971
Beyer, R.A.; Keller, G.E., The Clustering of Atmospheric Gases to Alkali Ions, Trans. Am. Geophys. Union, 1971, 52, 303. [all data]

Walter, Sievers, et al., 1998
Walter, D.; Sievers, M.R.; Armentrout, P.B., Alkali Ion Carbonyls: Sequential Bond Energies of Li+(CO)x (x=1-3), Na+(CO)x (x=1, 2), and K+(CO), Int. J. Mass Spectrom., 1998, 175, 1-2, 93, https://doi.org/10.1016/S0168-1176(98)00109-8 . [all data]

Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W., Mobility of gaseous lons in weak electric fields, Ann. Phys., 1958, 4, 3, 233, https://doi.org/10.1016/0003-4916(58)90049-6 . [all data]

More, Ray, et al., 1999
More, M.B.; Ray, D.; Armentrout, P.B., Intrinsic Affinities of Alkali Cations for 15-Crown-5 and 18-Crown-6: Bond Dissociation Energies of Gas-Phase M+-Crown Ether Complexes, J. Am. Chem. Soc., 1999, 121, 2, 417, https://doi.org/10.1021/ja9823159 . [all data]

Bushnell, Kemper, et al., 1994
Bushnell, J.E.; Kemper, P.R.; Bowers, M.T., Na+/K+(H2)1,2 clusters: experiment, J. Phys. Chem., 1994, 98, 8, 2044, https://doi.org/10.1021/j100059a011 . [all data]

Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T., The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584 . [all data]

Kish, Ohanessian, et al., 2003
Kish, M.M.; Ohanessian, G.; Wesdemiotis, C., The Na+ affinities of a-amino acids: side-chain substituent effects, Int. J. Mass Spectrom., 2003, 227, 3, 509, https://doi.org/10.1016/S1387-3806(03)00082-4 . [all data]

Moision and Armentrout, 2002
Moision, R.M.; Armentrout, P.B., Experimental and Theoretical Dissection of Sodium Cation/Glycine Interactions, J. Phys. Chem A, 2002, 106, 43, 10350, https://doi.org/10.1021/jp0216373 . [all data]

Cerda, Hoyau, et al., 1998
Cerda, B.A.; Hoyau, S.; Ohanessian, G.; Wesdemiotis, C., PAs of Peptides, J. Am. Chem. Soc., 1998, 120, 2437. [all data]

Feng, Gronert, et al., 1999
Feng, W.Y.; Gronert, S.; Lebrilla, C.B., Lithium and sodium ion binding energies of N-acetyl and N-glycyl amino acids, J. Am. Chem. Soc., 1999, 121, 6, 1365, https://doi.org/10.1021/ja983116s . [all data]

Rodgers and Armentrout, 1999, 2
Rodgers, M.T.; Armentrout, P.B., Absolute Alkali Metal Ion Binding Affinities of Several Azoles Determined by Threshold Collision-Induced Dissociation, Int. J. Mass Spectrom. Ion Proc., 1999, 185/186/187, 359. [all data]

Amunugama and Rodgers, 2000
Amunugama, R.; Rodgers, M.T., Absolute Alkali Metal Ion Binding Affinities of Several Azines Determined by Threshold Collision-Induced Dissociation and Ab Initio Theory, Int. J. Mass Spectrom., 2000, 195/196, 439, https://doi.org/10.1016/S1387-3806(99)00145-1 . [all data]

Huang and Rodgers, 2002
Huang, H.; Rodgers, M.T., Sigma versus Pi interactions in alkali metal ion binding to azoles: Threshold collision-induced dissociation and ab initio theory studies, J. Phys. Chem. A, 2002, 106, 16, 4277, https://doi.org/10.1021/jp013630b . [all data]

Gapeev and Dunbar, 2003
Gapeev, A.; Dunbar, R.C., Na+ Affinities of Gas-Phase Amino Acids by Ligand Exchange Equilibrium, Int. J. Mass Spectrom., 2003, 228, 2-3, 825, https://doi.org/10.1016/S1387-3806(03)00242-2 . [all data]

Rodgers and Armentrout, 2000, 2
Rodgers, M.T.; Armentrout, P.B., Noncovalent Interactions of Nucleic Acid Bases (Uracil, Thymine, and Adenine) with Alkali Metal Ions. Threshold Collision-Induced Dissociation and Theoretical Studies, J. Am. Chem. Soc., 2000, 121, 35, 8548, https://doi.org/10.1021/ja001638d . [all data]

Cerda and Wesdemiotis, 1996
Cerda, B.A.; Wesdemiotis, C., PAs of Peptides, J. Am. Chem. Soc., 1996, 118, 11884. [all data]

Rodgers, 2001
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Aminopyridines, J. Phys. Chem. A, 2001, 105, 35, 8145, https://doi.org/10.1021/jp011555z . [all data]

Cerda and Wesdemiotis, 1999
Cerda, B.A.; Wesdemiotis, C., Thermochemistry and Structures of Na+ Coordinated Mono- and Disaccharide Stereoisomers, Int. J. Mass Spectrom., 1999, 189, 2-3, 189, https://doi.org/10.1016/S1387-3806(99)00085-8 . [all data]

Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a . [all data]

Rodgers, 2001, 2
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Methylpyridines, J. Phys. Chem. A, 2001, 105, 11, 2374, https://doi.org/10.1021/jp004055z . [all data]

Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4 . [all data]

Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b . [all data]

Chupka, 1959
Chupka, W.A., Dissociation Energies of Some Gaseous Halide Complex Ions and the Hydrated Ion K(H2O)+, J. Chem. Phys., 1959, 40, 2, 458, https://doi.org/10.1063/1.1729974 . [all data]

Tsirlina, Gusarov, et al., 1986
Tsirlina, E.A.; Gusarov, A.V.; Gorokhov, L.N., High Temp., 1986, 14, 1064. [all data]

Upschulte, Schelling, et al., 1984
Upschulte, B.L.; Schelling, F.J.; Keesee, R.G.; Castleman, A.W., Thermochemical Properties of Gas Phase Mixed Clusters: Water and Sulfur Dioxide with Na+ and Cl-, Chem. Phys. Lett., 1984, 111, 4-5, 389, https://doi.org/10.1016/0009-2614(84)85526-8 . [all data]

Banic and Iribarne, 1985
Banic, C.M.; Iribarne, J.V., Equilibrium Constants for Clustering of Neutral Molecules about Gaseous Ions, J. Chem. Phys., 1985, 83, 12, 6432, https://doi.org/10.1063/1.449543 . [all data]

Brechignac, Cahuzac, et al., 1989
Brechignac, C.; Cahuzac, P.; Leygnier, J.; Weiner, J., Dynamics of Unimolecular Dissociation of Sodium Cluster Ions, J. Chem. Phys., 1989, 90, 3, 1492, https://doi.org/10.1063/1.456675 . [all data]

Rowe, Viggiano, et al., 1982
Rowe, B.R.; Viggiano, A.A.; Fehsenfeld, F.C.; Fahey, D.W.; Ferguson, E.E., Reactions between Neutrals Clustered on Ions, J. Chem. Phys., 1982, 76, 1, 742, https://doi.org/10.1063/1.442684 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References