Lithium ion (1+)

Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar133.02J/mol*KReviewChase, 1998Data last reviewed in December, 1983

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) • Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°165. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°165.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°131.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
165. (+10.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Argon = (Lithium ion (1+) • Argon)

By formula: Li+ + Ar = (Li+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°30. ± 4.kJ/molAVGN/AAverage of 4 out of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°30.J/mol*KDTMcKnight and Sawina, 1973gas phase; ΔrS approximate; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
5.9294.IMobCassidy and Elford, 1985gas phase; M
7.9319.DTKeller, Beyer, et al., 1973gas phase; LOW E/N; M
11.215.DTMcKnight and Sawina, 1973gas phase; ΔrS approximate; M

Lithium ion (1+) + Benzene = (Lithium ion (1+) • Benzene)

By formula: Li+ + C6H6 = (Li+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°161. ± 13.kJ/molCIDTAmicangelo and Armentrout, 2000RCD
ΔrH°159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°153.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°115.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°124.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) • Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°154. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°127.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Ammonia = (Lithium ion (1+) • Ammonia)

By formula: Li+ + H3N = (Li+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°164.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°161.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°134.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Formaldehyde = (Lithium ion (1+) • Formaldehyde)

By formula: Li+ + CH2O = (Li+ • CH2O)

Quantity Value Units Method Reference Comment
ΔrH°151.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°118.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) • Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ • CHN)

Quantity Value Units Method Reference Comment
ΔrH°152.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°120.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylamine, N,N-dimethyl- = (Lithium ion (1+) • Methylamine, N,N-dimethyl-)

By formula: Li+ + C3H9N = (Li+ • C3H9N)

Quantity Value Units Method Reference Comment
ΔrH°176.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°170.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°140.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

(Lithium ion (1+) • 3Water) + Water = (Lithium ion (1+) • 4Water)

By formula: (Li+ • 3H2O) + H2O = (Li+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°68.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°125.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) • 4Water) + Water = (Lithium ion (1+) • 5Water)

By formula: (Li+ • 4H2O) + H2O = (Li+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°58.2kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°131.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) • Dimethylamine)

By formula: Li+ + C2H7N = (Li+ • C2H7N)

Quantity Value Units Method Reference Comment
ΔrH°177.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°143.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methylamine = (Lithium ion (1+) • Methylamine)

By formula: Li+ + CH5N = (Li+ • CH5N)

Quantity Value Units Method Reference Comment
ΔrH°172.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°139.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) • 2Water) + Water = (Lithium ion (1+) • 3Water)

By formula: (Li+ • 2H2O) + H2O = (Li+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°94.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
ΔrH°86.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
ΔrS°104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

Lithium ion (1+) + helium = (Lithium ion (1+) • helium)

By formula: Li+ + He = (Li+ • He)

Quantity Value Units Method Reference Comment
ΔrH°7.15kJ/molIMobGatland, 1984gas phase; M
ΔrH°6.86kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°7.07kJ/molIMobViehland, 1984gas phase; M
ΔrH°4.56kJ/molIMobMason and Sharp, 1958gas phase; M
ΔrH°13.2kJ/molIMobTakebe, 1983gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-15.309.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Water = (Lithium ion (1+) • Water)

By formula: Li+ + H2O = (Li+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°135. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°140.kJ/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) • 5Water) + Water = (Lithium ion (1+) • 6Water)

By formula: (Li+ • 5H2O) + H2O = (Li+ • 6H2O)

Quantity Value Units Method Reference Comment
ΔrH°59.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°50.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°134.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) • Water) + Water = (Lithium ion (1+) • 2Water)

By formula: (Li+ • H2O) + H2O = (Li+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°113. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°108.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°88.3J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Lithium ion (1+) + Pyridine = (Lithium ion (1+) • Pyridine)

By formula: Li+ + C5H5N = (Li+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°181. ± 15.kJ/molCIDTAmunugama and Rodgers, 2000RCD
ΔrH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + neon = (Lithium ion (1+) • neon)

By formula: Li+ + Ne = (Li+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°11.0kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°11.9kJ/molIMobViehland, 1984gas phase; M
ΔrH°14.0kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Xenon = (Lithium ion (1+) • Xenon)

By formula: Li+ + Xe = (Li+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°51.5kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°52.7kJ/molIMobViehland, 1984gas phase; M
ΔrH°87.0kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Krypton = (Lithium ion (1+) • Krypton)

By formula: Li+ + Kr = (Li+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°44.4kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°38.kJ/molIMobViehland, 1984gas phase; M
ΔrH°68.6kJ/molIMobTakebe, 1983gas phase; M

(Lithium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 3Dimethyl ether)

By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°89.1 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
110. (+5.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 4Dimethyl ether)

By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°68. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
95.4 (+6.7,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 2Dimethyl ether)

By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°121. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
130. (+4.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Acetaldehyde = (Lithium ion (1+) • Acetaldehyde)

By formula: Li+ + C2H4O = (Li+ • C2H4O)

Quantity Value Units Method Reference Comment
ΔrH°173.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) • 2Ammonia) + Ammonia = (Lithium ion (1+) • 3Ammonia)

By formula: (Li+ • 2H3N) + H3N = (Li+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°87.9kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 3Ammonia) + Ammonia = (Lithium ion (1+) • 4Ammonia)

By formula: (Li+ • 3H3N) + H3N = (Li+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°69.0kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°136.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 4Ammonia) + Ammonia = (Lithium ion (1+) • 5Ammonia)

By formula: (Li+ • 4H3N) + H3N = (Li+ • 5H3N)

Quantity Value Units Method Reference Comment
ΔrH°46.4kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 5Ammonia) + Ammonia = (Lithium ion (1+) • 6Ammonia)

By formula: (Li+ • 5H3N) + H3N = (Li+ • 6H3N)

Quantity Value Units Method Reference Comment
ΔrH°39.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • Ammonia) + Ammonia = (Lithium ion (1+) • 2Ammonia)

By formula: (Li+ • H3N) + H3N = (Li+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°138.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°124.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Lithium ion (1+) + Propane, 2-fluoro- = (Lithium ion (1+) • Propane, 2-fluoro-)

By formula: Li+ + C3H7F = (Li+ • C3H7F)

Quantity Value Units Method Reference Comment
ΔrH°149.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) • Cyclohexane)

By formula: Li+ + C6H12 = (Li+ • C6H12)

Quantity Value Units Method Reference Comment
ΔrH°100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propene = (Lithium ion (1+) • Propene)

By formula: Li+ + C3H6 = (Li+ • C3H6)

Quantity Value Units Method Reference Comment
ΔrH°96.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1-Propene, 2-methyl- = (Lithium ion (1+) • 1-Propene, 2-methyl-)

By formula: Li+ + C4H8 = (Li+ • C4H8)

Quantity Value Units Method Reference Comment
ΔrH°120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Ethane, fluoro- = (Lithium ion (1+) • Ethane, fluoro-)

By formula: Li+ + C2H5F = (Li+ • C2H5F)

Quantity Value Units Method Reference Comment
ΔrH°140.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl fluoride = (Lithium ion (1+) • Methyl fluoride)

By formula: Li+ + CH3F = (Li+ • CH3F)

Quantity Value Units Method Reference Comment
ΔrH°130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetic acid = (Lithium ion (1+) • Acetic acid)

By formula: Li+ + C2H4O2 = (Li+ • C2H4O2)

Quantity Value Units Method Reference Comment
ΔrH°174.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetone = (Lithium ion (1+) • Acetone)

By formula: Li+ + C3H6O = (Li+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°186.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propyne = (Lithium ion (1+) • Propyne)

By formula: Li+ + C3H4 = (Li+ • C3H4)

Quantity Value Units Method Reference Comment
ΔrH°119.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Difluoromethane = (Lithium ion (1+) • Difluoromethane)

By formula: Li+ + CH2F2 = (Li+ • CH2F2)

Quantity Value Units Method Reference Comment
ΔrH°111.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) • Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ • C2H6S)

Quantity Value Units Method Reference Comment
ΔrH°137.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-bromo- = (Lithium ion (1+) • Propane, 2-bromo-)

By formula: Li+ + C3H7Br = (Li+ • C3H7Br)

Quantity Value Units Method Reference Comment
ΔrH°128.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-iodo- = (Lithium ion (1+) • Propane, 2-iodo-)

By formula: Li+ + C3H7I = (Li+ • C3H7I)

Quantity Value Units Method Reference Comment
ΔrH°123.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ • C3H7NO)

Quantity Value Units Method Reference Comment
ΔrH°210.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Chloromethane = (Lithium ion (1+) • Chloromethane)

By formula: Li+ + CH3Cl = (Li+ • CH3Cl)

Quantity Value Units Method Reference Comment
ΔrH°100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetonitrile = (Lithium ion (1+) • Acetonitrile)

By formula: Li+ + C2H3N = (Li+ • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) • Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ • CH2Cl2)

Quantity Value Units Method Reference Comment
ΔrH°120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Propane, 2-chloro- = (Lithium ion (1+) • Propane, 2-chloro-)

By formula: Li+ + C3H7Cl = (Li+ • C3H7Cl)

Quantity Value Units Method Reference Comment
ΔrH°130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetic acid, methyl ester = (Lithium ion (1+) • Acetic acid, methyl ester)

By formula: Li+ + C3H6O2 = (Li+ • C3H6O2)

Quantity Value Units Method Reference Comment
ΔrH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) • Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ • CH3NO2)

Quantity Value Units Method Reference Comment
ΔrH°165.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Lithium ion (1+) + Argon = (Lithium ion (1+) • Argon)

By formula: Li+ + Ar = (Li+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°30. ± 4.kJ/molAVGN/AAverage of 4 out of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°30.J/mol*KDTMcKnight and Sawina, 1973gas phase; ΔrS approximate; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
5.9294.IMobCassidy and Elford, 1985gas phase; M
7.9319.DTKeller, Beyer, et al., 1973gas phase; LOW E/N; M
11.215.DTMcKnight and Sawina, 1973gas phase; ΔrS approximate; M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) • Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ • CHN)

Quantity Value Units Method Reference Comment
ΔrH°152.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°120.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) • Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ • CH2Cl2)

Quantity Value Units Method Reference Comment
ΔrH°120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Difluoromethane = (Lithium ion (1+) • Difluoromethane)

By formula: Li+ + CH2F2 = (Li+ • CH2F2)

Quantity Value Units Method Reference Comment
ΔrH°111.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + 2H-Tetrazole = (Lithium ion (1+) • 2H-Tetrazole)

By formula: Li+ + CH2N4 = (Li+ • CH2N4)

Quantity Value Units Method Reference Comment
ΔrH°151. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Formaldehyde = (Lithium ion (1+) • Formaldehyde)

By formula: Li+ + CH2O = (Li+ • CH2O)

Quantity Value Units Method Reference Comment
ΔrH°151.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°118.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Chloromethane = (Lithium ion (1+) • Chloromethane)

By formula: Li+ + CH3Cl = (Li+ • CH3Cl)

Quantity Value Units Method Reference Comment
ΔrH°100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methyl fluoride = (Lithium ion (1+) • Methyl fluoride)

By formula: Li+ + CH3F = (Li+ • CH3F)

Quantity Value Units Method Reference Comment
ΔrH°130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Formamide = (Lithium ion (1+) • Formamide)

By formula: Li+ + CH3NO = (Li+ • CH3NO)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
157.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) • Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ • CH3NO2)

Quantity Value Units Method Reference Comment
ΔrH°165.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) • Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°154. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°127.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylamine = (Lithium ion (1+) • Methylamine)

By formula: Li+ + CH5N = (Li+ • CH5N)

Quantity Value Units Method Reference Comment
ΔrH°172.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°139.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Carbon monoxide = (Lithium ion (1+) • Carbon monoxide)

By formula: Li+ + CO = (Li+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°55. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°55. ± 12.kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) • Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) • 2Carbon monoxide)

By formula: (Li+ • CO) + CO = (Li+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°36. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°36. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) • 3Carbon monoxide)

By formula: (Li+ • 2CO) + CO = (Li+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°35. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°35. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

Lithium ion (1+) + Acetonitrile = (Lithium ion (1+) • Acetonitrile)

By formula: Li+ + C2H3N = (Li+ • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + C2H3N3 = (Lithium ion (1+) • C2H3N3)

By formula: Li+ + C2H3N3 = (Li+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°136. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1H-1,2,4-Triazole = (Lithium ion (1+) • 1H-1,2,4-Triazole)

By formula: Li+ + C2H3N3 = (Li+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°191. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Acetaldehyde = (Lithium ion (1+) • Acetaldehyde)

By formula: Li+ + C2H4O = (Li+ • C2H4O)

Quantity Value Units Method Reference Comment
ΔrH°173.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetic acid = (Lithium ion (1+) • Acetic acid)

By formula: Li+ + C2H4O2 = (Li+ • C2H4O2)

Quantity Value Units Method Reference Comment
ΔrH°174.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + 1,3,2-Dioxathiolane, 2-oxide = (Lithium ion (1+) • 1,3,2-Dioxathiolane, 2-oxide)

By formula: Li+ + C2H4O3S = (Li+ • C2H4O3S)

Quantity Value Units Method Reference Comment
ΔrH°199.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Ethane, fluoro- = (Lithium ion (1+) • Ethane, fluoro-)

By formula: Li+ + C2H5F = (Li+ • C2H5F)

Quantity Value Units Method Reference Comment
ΔrH°140.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N-methyl- = (Lithium ion (1+) • Formamide, N-methyl-)

By formula: Li+ + C2H5NO = (Li+ • C2H5NO)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
166.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Ethanol = (Lithium ion (1+) • Ethanol)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°164. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) • Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°165. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°165.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°131.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
165. (+10.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 2Dimethyl ether)

By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°121. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
130. (+4.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 3Dimethyl ether)

By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°89.1 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
110. (+5.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 4Dimethyl ether)

By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°68. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
95.4 (+6.7,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Dimethyl sulfone = (Lithium ion (1+) • Dimethyl sulfone)

By formula: Li+ + C2H6O2S = (Li+ • C2H6O2S)

Quantity Value Units Method Reference Comment
ΔrH°203.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) • Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ • C2H6S)

Quantity Value Units Method Reference Comment
ΔrH°137.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) • Dimethylamine)

By formula: Li+ + C2H7N = (Li+ • C2H7N)

Quantity Value Units Method Reference Comment
ΔrH°177.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°143.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1,3,5-Triazine = (Lithium ion (1+) • 1,3,5-Triazine)

By formula: Li+ + C3H3N3 = (Li+ • C3H3N3)

Quantity Value Units Method Reference Comment
ΔrH°127. ± 13.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + 1H-Pyrazole = (Lithium ion (1+) • 1H-Pyrazole)

By formula: Li+ + C3H4N2 = (Li+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°187. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole = (Lithium ion (1+) • 1H-Imidazole)

By formula: Li+ + C3H4N2 = (Li+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°211. ± 9.6kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Propyne = (Lithium ion (1+) • Propyne)

By formula: Li+ + C3H4 = (Li+ • C3H4)

Quantity Value Units Method Reference Comment
ΔrH°119.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetone = (Lithium ion (1+) • Acetone)

By formula: Li+ + C3H6O = (Li+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°186.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetic acid, methyl ester = (Lithium ion (1+) • Acetic acid, methyl ester)

By formula: Li+ + C3H6O2 = (Li+ • C3H6O2)

Quantity Value Units Method Reference Comment
ΔrH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propene = (Lithium ion (1+) • Propene)

By formula: Li+ + C3H6 = (Li+ • C3H6)

Quantity Value Units Method Reference Comment
ΔrH°96.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-bromo- = (Lithium ion (1+) • Propane, 2-bromo-)

By formula: Li+ + C3H7Br = (Li+ • C3H7Br)

Quantity Value Units Method Reference Comment
ΔrH°128.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-chloro- = (Lithium ion (1+) • Propane, 2-chloro-)

By formula: Li+ + C3H7Cl = (Li+ • C3H7Cl)

Quantity Value Units Method Reference Comment
ΔrH°130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-fluoro- = (Lithium ion (1+) • Propane, 2-fluoro-)

By formula: Li+ + C3H7F = (Li+ • C3H7F)

Quantity Value Units Method Reference Comment
ΔrH°149.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-iodo- = (Lithium ion (1+) • Propane, 2-iodo-)

By formula: Li+ + C3H7I = (Li+ • C3H7I)

Quantity Value Units Method Reference Comment
ΔrH°123.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ • C3H7NO)

Quantity Value Units Method Reference Comment
ΔrH°210.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetamide, N-methyl- = (Lithium ion (1+) • Acetamide, N-methyl-)

By formula: Li+ + C3H7NO = (Li+ • C3H7NO)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
173.373.CIDT,ICRHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Isopropyl Alcohol = (Lithium ion (1+) • Isopropyl Alcohol)

By formula: Li+ + C3H8O = (Li+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°173. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol = (Lithium ion (1+) • 1-Propanol)

By formula: Li+ + C3H8O = (Li+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°171. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Methylamine, N,N-dimethyl- = (Lithium ion (1+) • Methylamine, N,N-dimethyl-)

By formula: Li+ + C3H9N = (Li+ • C3H9N)

Quantity Value Units Method Reference Comment
ΔrH°176.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°170.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°120.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°140.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Pyrazine = (Lithium ion (1+) • Pyrazine)

By formula: Li+ + C4H4N2 = (Li+ • C4H4N2)

Quantity Value Units Method Reference Comment
ΔrH°149. ± 14.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + Pyrrole = (Lithium ion (1+) • Pyrrole)

By formula: Li+ + C4H5N = (Li+ • C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°177. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole, 1-methyl- = (Lithium ion (1+) • 1H-Imidazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°242. ± 21.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Pyrazole, 1-methyl- = (Lithium ion (1+) • 1H-Pyrazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°207. ± 19.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1-Propene, 2-methyl- = (Lithium ion (1+) • 1-Propene, 2-methyl-)

By formula: Li+ + C4H8 = (Li+ • C4H8)

Quantity Value Units Method Reference Comment
ΔrH°120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1-Butanol = (Lithium ion (1+) • 1-Butanol)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°178. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Propanol, 2-methyl- = (Lithium ion (1+) • 2-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°178. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol, 2-methyl- = (Lithium ion (1+) • 1-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°169. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Butanol = (Lithium ion (1+) • 2-Butanol)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°174. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) • Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ • C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°158. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Lithium ion (1+) • Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) • 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ • C4H10O2) + C4H10O2 = (Li+ • 2C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°139. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine = (Lithium ion (1+) • Pyridine)

By formula: Li+ + C5H5N = (Li+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°181. ± 15.kJ/molCIDTAmunugama and Rodgers, 2000RCD
ΔrH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 3-Aminopyridine = (Lithium ion (1+) • 3-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°202. ± 10.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 4-Aminopyridine = (Lithium ion (1+) • 4-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°217. ± 21.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 2-Aminopyridine = (Lithium ion (1+) • 2-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°238. ± 21.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 1H-Pyrrole, 1-methyl- = (Lithium ion (1+) • 1H-Pyrrole, 1-methyl-)

By formula: Li+ + C5H7N = (Li+ • C5H7N)

Quantity Value Units Method Reference Comment
ΔrH°186. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Benzene, fluoro- = (Lithium ion (1+) • Benzene, fluoro-)

By formula: Li+ + C6H5F = (Li+ • C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°147. ± 21.kJ/molCIDTAmunugama and Rodgers, 2002RCD

(Lithium ion (1+) • Benzene, fluoro-) + Benzene, fluoro- = (Lithium ion (1+) • 2Benzene, fluoro-)

By formula: (Li+ • C6H5F) + C6H5F = (Li+ • 2C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°95. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002RCD

Lithium ion (1+) + Phenol = (Lithium ion (1+) • Phenol)

By formula: Li+ + C6H6O = (Li+ • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°178. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Lithium ion (1+) • Phenol) + Phenol = (Lithium ion (1+) • 2Phenol)

By formula: (Li+ • C6H6O) + C6H6O = (Li+ • 2C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°115. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

Lithium ion (1+) + Benzene = (Lithium ion (1+) • Benzene)

By formula: Li+ + C6H6 = (Li+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°161. ± 13.kJ/molCIDTAmicangelo and Armentrout, 2000RCD
ΔrH°159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°153.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°115.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°124.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

(Lithium ion (1+) • Benzene) + Benzene = (Lithium ion (1+) • 2Benzene)

By formula: (Li+ • C6H6) + C6H6 = (Li+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°104. ± 7.1kJ/molCIDTAmicangelo and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine, 4-methyl- = (Lithium ion (1+) • Pyridine, 4-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°196. ± 14.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) • Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°197. ± 15.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Pyridine, 2-methyl- = (Lithium ion (1+) • Pyridine, 2-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°194. ± 6.7kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) • Cyclohexane)

By formula: Li+ + C6H12 = (Li+ • C6H12)

Quantity Value Units Method Reference Comment
ΔrH°100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl 4-nitrophenyl sulfone = (Lithium ion (1+) • Methyl 4-nitrophenyl sulfone)

By formula: Li+ + C7H8NO4S = (Li+ • C7H8NO4S)

Quantity Value Units Method Reference Comment
ΔrH°198.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Benzene, (methylsulfinyl)- = (Lithium ion (1+) • Benzene, (methylsulfinyl)-)

By formula: Li+ + C7H8OS = (Li+ • C7H8OS)

Quantity Value Units Method Reference Comment
ΔrH°230.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Anisole = (Lithium ion (1+) • Anisole)

By formula: Li+ + C7H8O = (Li+ • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°185. ± 19.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Lithium ion (1+) • Anisole) + Anisole = (Lithium ion (1+) • 2Anisole)

By formula: (Li+ • C7H8O) + C7H8O = (Li+ • 2C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°121. ± 4.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Lithium ion (1+) + Sulfone, methyl phenyl = (Lithium ion (1+) • Sulfone, methyl phenyl)

By formula: Li+ + C7H8O2S = (Li+ • C7H8O2S)

Quantity Value Units Method Reference Comment
ΔrH°213.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + C7H8O3S = (Lithium ion (1+) • C7H8O3S)

By formula: Li+ + C7H8O3S = (Li+ • C7H8O3S)

Quantity Value Units Method Reference Comment
ΔrH°206.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Toluene = (Lithium ion (1+) • Toluene)

By formula: Li+ + C7H8 = (Li+ • C7H8)

Quantity Value Units Method Reference Comment
ΔrH°183. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Lithium ion (1+) • Toluene) + Toluene = (Lithium ion (1+) • 2Toluene)

By formula: (Li+ • C7H8) + C7H8 = (Li+ • 2C7H8)

Quantity Value Units Method Reference Comment
ΔrH°116. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

Lithium ion (1+) + Benzene, 1-methyl-4-(methylsulfonyl)- = (Lithium ion (1+) • Benzene, 1-methyl-4-(methylsulfonyl)-)

By formula: Li+ + C8H10O2S = (Li+ • C8H10O2S)

Quantity Value Units Method Reference Comment
ΔrH°216.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + 12-Crown-4 = (Lithium ion (1+) • 12-Crown-4)

By formula: Li+ + C8H16O4 = (Li+ • C8H16O4)

Quantity Value Units Method Reference Comment
ΔrH°252. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Diphenyl sulfoxide = (Lithium ion (1+) • Diphenyl sulfoxide)

By formula: Li+ + C12H10OS = (Li+ • C12H10OS)

Quantity Value Units Method Reference Comment
ΔrH°234.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Diphenyl sulfone = (Lithium ion (1+) • Diphenyl sulfone)

By formula: Li+ + C12H10O2S = (Li+ • C12H10O2S)

Quantity Value Units Method Reference Comment
ΔrH°218.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Water = (Lithium ion (1+) • Water)

By formula: Li+ + H2O = (Li+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°135. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°140.kJ/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) • Water) + Water = (Lithium ion (1+) • 2Water)

By formula: (Li+ • H2O) + H2O = (Li+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°113. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°108.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°88.3J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) • 2Water) + Water = (Lithium ion (1+) • 3Water)

By formula: (Li+ • 2H2O) + H2O = (Li+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°94.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
ΔrH°86.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
ΔrS°104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

(Lithium ion (1+) • 3Water) + Water = (Lithium ion (1+) • 4Water)

By formula: (Li+ • 3H2O) + H2O = (Li+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°68.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°125.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) • 4Water) + Water = (Lithium ion (1+) • 5Water)

By formula: (Li+ • 4H2O) + H2O = (Li+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°58.2kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°131.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Lithium ion (1+) • 5Water) + Water = (Lithium ion (1+) • 6Water)

By formula: (Li+ • 5H2O) + H2O = (Li+ • 6H2O)

Quantity Value Units Method Reference Comment
ΔrH°59.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°50.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°134.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Lithium ion (1+) + Hydrogen = (Lithium ion (1+) • Hydrogen)

By formula: Li+ + H2 = (Li+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°27. ± 19.kJ/molEIWu, 1979gas phase; M

Lithium ion (1+) + Ammonia = (Lithium ion (1+) • Ammonia)

By formula: Li+ + H3N = (Li+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°164.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°161.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°96.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°134.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) • Ammonia) + Ammonia = (Lithium ion (1+) • 2Ammonia)

By formula: (Li+ • H3N) + H3N = (Li+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°138.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°124.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 2Ammonia) + Ammonia = (Lithium ion (1+) • 3Ammonia)

By formula: (Li+ • 2H3N) + H3N = (Li+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°87.9kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 3Ammonia) + Ammonia = (Lithium ion (1+) • 4Ammonia)

By formula: (Li+ • 3H3N) + H3N = (Li+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°69.0kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°136.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 4Ammonia) + Ammonia = (Lithium ion (1+) • 5Ammonia)

By formula: (Li+ • 4H3N) + H3N = (Li+ • 5H3N)

Quantity Value Units Method Reference Comment
ΔrH°46.4kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°117.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 5Ammonia) + Ammonia = (Lithium ion (1+) • 6Ammonia)

By formula: (Li+ • 5H3N) + H3N = (Li+ • 6H3N)

Quantity Value Units Method Reference Comment
ΔrH°39.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Lithium ion (1+) + helium = (Lithium ion (1+) • helium)

By formula: Li+ + He = (Li+ • He)

Quantity Value Units Method Reference Comment
ΔrH°7.15kJ/molIMobGatland, 1984gas phase; M
ΔrH°6.86kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°7.07kJ/molIMobViehland, 1984gas phase; M
ΔrH°4.56kJ/molIMobMason and Sharp, 1958gas phase; M
ΔrH°13.2kJ/molIMobTakebe, 1983gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-15.309.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Krypton = (Lithium ion (1+) • Krypton)

By formula: Li+ + Kr = (Li+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°44.4kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°38.kJ/molIMobViehland, 1984gas phase; M
ΔrH°68.6kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) • Nitrogen)

By formula: Li+ + N2 = (Li+ • N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

(Lithium ion (1+) • Nitrogen) + Nitrogen = (Lithium ion (1+) • 2Nitrogen)

By formula: (Li+ • N2) + N2 = (Li+ • 2N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

Lithium ion (1+) + neon = (Lithium ion (1+) • neon)

By formula: Li+ + Ne = (Li+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°11.0kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°11.9kJ/molIMobViehland, 1984gas phase; M
ΔrH°14.0kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Oxygen = (Lithium ion (1+) • Oxygen)

By formula: Li+ + O2 = (Li+ • O2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.319.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Xenon = (Lithium ion (1+) • Xenon)

By formula: Li+ + Xe = (Li+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°51.5kJ/molSCATTERINGGislason, 1984gas phase; M
ΔrH°52.7kJ/molIMobViehland, 1984gas phase; M
ΔrH°87.0kJ/molIMobTakebe, 1983gas phase; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
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Notes

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