Lithium ion (1+)
- Formula: Li+
- Molecular weight: 6.940
- IUPAC Standard InChIKey: HBBGRARXTFLTSG-UHFFFAOYSA-N
- CAS Registry Number: 17341-24-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Lithium cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 106
- Options:
Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: Li+ + Ar = (Li+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. ± 4. | kJ/mol | AVG | N/A | Average of 4 out of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 30. | J/mol*K | DT | McKnight and Sawina, 1973 | gas phase; ΔrS approximate; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
5.9 | 294. | IMob | Cassidy and Elford, 1985 | gas phase; M |
7.9 | 319. | DT | Keller, Beyer, et al., 1973 | gas phase; LOW E/N; M |
11. | 215. | DT | McKnight and Sawina, 1973 | gas phase; ΔrS approximate; M |
By formula: Li+ + CHN = (Li+ • CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 152. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
ΔrH° | 150. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 120. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CH2Cl2 = (Li+ • CH2Cl2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 120. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CH2F2 = (Li+ • CH2F2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 111. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CH2N4 = (Li+ • CH2N4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 151. ± 7.1 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + CH2O = (Li+ • CH2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 151. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
ΔrH° | 150. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 118. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CH3Cl = (Li+ • CH3Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 100. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CH3F = (Li+ • CH3F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 130. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CH3NO = (Li+ • CH3NO)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
157. | 373. | CIDC | Herreros, Gal, et al., 1999 | RCD |
By formula: Li+ + CH3NO2 = (Li+ • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 165. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M |
By formula: Li+ + CH4O = (Li+ • CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 154. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 159. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
ΔrH° | 160. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 127. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CH5N = (Li+ • CH5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 172. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 139. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + CO = (Li+ • CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 55. ± 13. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 55. ± 12. | kJ/mol | CIDT | Walter, Sievers, et al., 1998 | RCD |
By formula: (Li+ • CO) + CO = (Li+ • 2CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 36. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 36. ± 4.2 | kJ/mol | CIDT | Walter, Sievers, et al., 1998 | RCD |
By formula: (Li+ • 2CO) + CO = (Li+ • 3CO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 35. ± 4.2 | kJ/mol | CIDT | Walter, Sievers, et al., 1998 | RCD |
By formula: Li+ + C2H3N = (Li+ • C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 180. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + C2H3N3 = (Li+ • C2H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 136. ± 7.1 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C2H3N3 = (Li+ • C2H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 191. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C2H4O = (Li+ • C2H4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 173. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + C2H4O2 = (Li+ • C2H4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 174. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M |
By formula: Li+ + C2H4O3S = (Li+ • C2H4O3S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 199. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C2H5F = (Li+ • C2H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 140. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C2H5NO = (Li+ • C2H5NO)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
166. | 373. | CIDC | Herreros, Gal, et al., 1999 | RCD |
By formula: Li+ + C2H6O = (Li+ • C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 164. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C2H6O = (Li+ • C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 165. ± 11. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 165. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
ΔrH° | 160. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 131. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
165. (+10.,-0.) | CID | More, Gledening, et al., 1996 | gas phase; guided ion beam CID; M |
By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 121. ± 5.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
130. (+4.,-0.) | CID | More, Gledening, et al., 1996 | gas phase; guided ion beam CID; M |
By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 89.1 ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
110. (+5.9,-0.) | CID | More, Gledening, et al., 1996 | gas phase; guided ion beam CID; M |
By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 68. ± 10. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
95.4 (+6.7,-0.) | CID | More, Gledening, et al., 1996 | gas phase; guided ion beam CID; M |
By formula: Li+ + C2H6O2S = (Li+ • C2H6O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 203. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C2H6S = (Li+ • C2H6S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 137. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C2H7N = (Li+ • C2H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 110. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 143. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H3N3 = (Li+ • C3H3N3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 127. ± 13. | kJ/mol | CIDT | Amunugama and Rodgers, 2000 | RCD |
By formula: Li+ + C3H4N2 = (Li+ • C3H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 187. ± 17. | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Li+ + C3H4N2 = (Li+ • C3H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 211. ± 9.6 | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Li+ + C3H4 = (Li+ • C3H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 119. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H6O = (Li+ • C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 186. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H6O2 = (Li+ • C3H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 180. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H6 = (Li+ • C3H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 96. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H7Br = (Li+ • C3H7Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 128. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H7Cl = (Li+ • C3H7Cl)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 130. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H7F = (Li+ • C3H7F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 149. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H7I = (Li+ • C3H7I)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 123. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H7NO = (Li+ • C3H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 210. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C3H7NO = (Li+ • C3H7NO)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
173. | 373. | CIDT,ICR | Herreros, Gal, et al., 1999 | RCD |
By formula: Li+ + C3H8O = (Li+ • C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 173. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C3H8O = (Li+ • C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 171. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C3H9N = (Li+ • C3H9N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
ΔrH° | 170. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 120. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 140. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C4H4N2 = (Li+ • C4H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 149. ± 14. | kJ/mol | CIDT | Amunugama and Rodgers, 2000 | RCD |
By formula: Li+ + C4H5N = (Li+ • C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 177. ± 17. | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Li+ + C4H6N2 = (Li+ • C4H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 242. ± 21. | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Li+ + C4H6N2 = (Li+ • C4H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 207. ± 19. | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Li+ + C4H8 = (Li+ • C4H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 120. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C4H10O = (Li+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 178. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C4H10O = (Li+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 178. ± 10. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C4H10O = (Li+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 169. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C4H10O = (Li+ • C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 174. ± 9.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C4H10O2 = (Li+ • C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 158. ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: (Li+ • C4H10O2) + C4H10O2 = (Li+ • 2C4H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 139. ± 12. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C5H5N = (Li+ • C5H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 181. ± 15. | kJ/mol | CIDT | Amunugama and Rodgers, 2000 | RCD |
ΔrH° | 180. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 202. ± 10. | kJ/mol | CIDT | Rodgers, 2001 | RCD |
By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 217. ± 21. | kJ/mol | CIDT | Rodgers, 2001 | RCD |
By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 238. ± 21. | kJ/mol | CIDT | Rodgers, 2001 | RCD |
By formula: Li+ + C5H7N = (Li+ • C5H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 186. ± 17. | kJ/mol | CIDT | Huang and Rodgers, 2002 | RCD |
By formula: Li+ + C6H5F = (Li+ • C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 147. ± 21. | kJ/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: (Li+ • C6H5F) + C6H5F = (Li+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 95. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: Li+ + C6H6O = (Li+ • C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 178. ± 17. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 2 | RCD |
By formula: (Li+ • C6H6O) + C6H6O = (Li+ • 2C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 115. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 2 | RCD |
By formula: Li+ + C6H6 = (Li+ • C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 161. ± 13. | kJ/mol | CIDT | Amicangelo and Armentrout, 2000 | RCD |
ΔrH° | 159. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
ΔrH° | 153. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 115. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 124. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: (Li+ • C6H6) + C6H6 = (Li+ • 2C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 104. ± 7.1 | kJ/mol | CIDT | Amicangelo and Armentrout, 2000 | RCD |
By formula: Li+ + C6H7N = (Li+ • C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 196. ± 14. | kJ/mol | CIDT | Rodgers, 2001, 2 | RCD |
By formula: Li+ + C6H7N = (Li+ • C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 197. ± 15. | kJ/mol | CIDT | Rodgers, 2001, 2 | RCD |
By formula: Li+ + C6H7N = (Li+ • C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 194. ± 6.7 | kJ/mol | CIDT | Rodgers, 2001, 2 | RCD |
By formula: Li+ + C6H12 = (Li+ • C6H12)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 100. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
By formula: Li+ + C7H8NO4S = (Li+ • C7H8NO4S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 198. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C7H8OS = (Li+ • C7H8OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 230. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C7H8O = (Li+ • C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 185. ± 19. | kJ/mol | CIDT | Amunugama and Rodgers, 2003 | RCD |
By formula: (Li+ • C7H8O) + C7H8O = (Li+ • 2C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 121. ± 4. | kJ/mol | CIDT | Amunugama and Rodgers, 2003 | RCD |
By formula: Li+ + C7H8O2S = (Li+ • C7H8O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 213. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C7H8O3S = (Li+ • C7H8O3S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 206. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C7H8 = (Li+ • C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 183. ± 17. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 3 | RCD |
By formula: (Li+ • C7H8) + C7H8 = (Li+ • 2C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 116. ± 3. | kJ/mol | CIDT | Amunugama and Rodgers, 2002, 3 | RCD |
By formula: Li+ + C8H10O2S = (Li+ • C8H10O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 216. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C8H16O4 = (Li+ • C8H16O4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 252. ± 13. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Li+ + C12H10OS = (Li+ • C12H10OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 234. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + C12H10O2S = (Li+ • C12H10O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 218. | kJ/mol | CIDC | Buncel, Decouzon, et al., 1997 | RCD |
By formula: Li+ + H2O = (Li+ • H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 135. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 140. | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; interpolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 96. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; interpolated; M |
By formula: (Li+ • H2O) + H2O = (Li+ • 2H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 113. ± 10. | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 108. | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 88.3 | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
By formula: (Li+ • 2H2O) + H2O = (Li+ • 3H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 94.1 ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 70. ± 10. | kJ/mol | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray; M |
ΔrH° | 86.6 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 96. | J/mol*K | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray; M |
ΔrS° | 104. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
41.8 | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray; M |
By formula: (Li+ • 3H2O) + H2O = (Li+ • 4H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69.9 ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 68.6 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrH° | 60. ± 10. | kJ/mol | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 125. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrS° | 96. | J/mol*K | N/A | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
33. | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electrospray, Entropy change calculated or estimated; M |
By formula: (Li+ • 4H2O) + H2O = (Li+ • 5H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.9 ± 4.2 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 58.2 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrH° | 50. ± 10. | kJ/mol | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electospray, Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 131. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
ΔrS° | 96. | J/mol*K | N/A | Blades, Jayaweera, et al., 1990 | gas phase; electospray, Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
23. | 300. | HPMS | Blades, Jayaweera, et al., 1990 | gas phase; electospray, Entropy change calculated or estimated; M |
By formula: (Li+ • 5H2O) + H2O = (Li+ • 6H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.8 ± 5.0 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
ΔrH° | 50.6 | kJ/mol | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 134. | J/mol*K | HPMS | Dzidic and Kebarle, 1970 | gas phase; M |
By formula: Li+ + H2 = (Li+ • H2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 27. ± 19. | kJ/mol | EI | Wu, 1979 | gas phase; M |
By formula: Li+ + H3N = (Li+ • H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 164. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
ΔrH° | 161. | kJ/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 96. | J/mol*K | N/A | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 134. | kJ/mol | ICR | Woodin and Beauchamp, 1978 | gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M |
By formula: (Li+ • H3N) + H3N = (Li+ • 2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 138. | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 124. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Li+ • 2H3N) + H3N = (Li+ • 3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.9 | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 106. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Li+ • 3H3N) + H3N = (Li+ • 4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69.0 | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 136. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Li+ • 4H3N) + H3N = (Li+ • 5H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 46.4 | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 117. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: (Li+ • 5H3N) + H3N = (Li+ • 6H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39. | kJ/mol | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 106. | J/mol*K | HPMS | Castleman, Holland, et al., 1978 | gas phase; M |
By formula: Li+ + He = (Li+ • He)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.15 | kJ/mol | IMob | Gatland, 1984 | gas phase; M |
ΔrH° | 6.86 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 7.07 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 4.56 | kJ/mol | IMob | Mason and Sharp, 1958 | gas phase; M |
ΔrH° | 13.2 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
-15. | 309. | DT | Colonna-Romano and Keller, 1976 | gas phase; low E/N; M |
By formula: Li+ + Kr = (Li+ • Kr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 44.4 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 38. | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 68.6 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: Li+ + N2 = (Li+ • N2)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
23. | 318. | DT | Gatland, Colonna-Romano, et al., 1975 | gas phase; low E/N; M |
By formula: (Li+ • N2) + N2 = (Li+ • 2N2)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
18. | 318. | DT | Gatland, Colonna-Romano, et al., 1975 | gas phase; low E/N; M |
By formula: Li+ + Ne = (Li+ • Ne)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.0 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 11.9 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 14.0 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
By formula: Li+ + O2 = (Li+ • O2)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
18. | 319. | DT | Colonna-Romano and Keller, 1976 | gas phase; low E/N; M |
By formula: Li+ + Xe = (Li+ • Xe)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51.5 | kJ/mol | SCATTERING | Gislason, 1984 | gas phase; M |
ΔrH° | 52.7 | kJ/mol | IMob | Viehland, 1984 | gas phase; M |
ΔrH° | 87.0 | kJ/mol | IMob | Takebe, 1983 | gas phase; M |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
McKnight and Sawina, 1973
McKnight, L.G.; Sawina, J.M.,
Equilibrium Constants and Binding Energies of Alkali Metal Ions with Inert Gases,
Bull. Am. Phys. Soc., 1973, 18, 804. [all data]
Cassidy and Elford, 1985
Cassidy, R.A.; Elford, M.T.,
The Mobility of Li+ Ions in Helium and Argon,
Aust. J. Phys., 1985, 38, 4, 587, https://doi.org/10.1071/PH850587
. [all data]
Keller, Beyer, et al., 1973
Keller, C.E.; Beyer, R.A.; Colonna-Romano, L.M.,
Clustering of Ar to Li+ and a Comparison of Drift - Tube Models,
Phys. Rev. A, 1973, 8, 3, 1446, https://doi.org/10.1103/PhysRevA.8.1446
. [all data]
Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L.,
Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids,
J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024
. [all data]
Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P.,
Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n,
J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013
. [all data]
Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L.,
Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases,
J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Herreros, Gal, et al., 1999
Herreros, M.; Gal, J.-F.; Maria, P.-C.; Decouzon, M.,
Gas-Phase Basicity of Simple Amides Toward Proton and Lithium Cation: An Experimental and Theoretical Study,
Eur. J. Mass Spectrom., 1999, 5, 1, 259, https://doi.org/10.1255/ejms.282
. [all data]
Walter, Sievers, et al., 1998
Walter, D.; Sievers, M.R.; Armentrout, P.B.,
Alkali Ion Carbonyls: Sequential Bond Energies of Li+(CO)x (x=1-3), Na+(CO)x (x=1, 2), and K+(CO),
Int. J. Mass Spectrom., 1998, 175, 1-2, 93, https://doi.org/10.1016/S0168-1176(98)00109-8
. [all data]
Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr.,
Thermochemical data on Ggs-phase ion-molecule association and clustering reactions,
J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]
Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L.,
Quoted in Keesee and Castleman, 1986, 1986. [all data]
Buncel, Decouzon, et al., 1997
Buncel, E.; Decouzon, M.; Formento, A.; Gal, J.-F.; Herreros, M.; Li, L.; Maria, P.-C.,
Lithium-Cation and Proton Affinities of Sulfoxides and Sulfones: A Fourier Transform Ion Cyclotron Resonance Study,
J. Am. Soc. Mass Spectrom., 1997, 8, 3, 262, https://doi.org/10.1016/S1044-0305(96)00255-3
. [all data]
More, Gledening, et al., 1996
More, M.B.; Gledening, E.D.; Ray, D.; Feller, D.; Armentrout, P.B.,
Cation-Ether Complexes in the Gas Phase: Bond Dissociation Energies and Equilibrium Structures of Li+[O(CH3)2]x, x=1-4,
J. Phys. Chem., 1996, 100, 5, 1605, https://doi.org/10.1021/jp9523175
. [all data]
Amunugama and Rodgers, 2000
Amunugama, R.; Rodgers, M.T.,
Absolute Alkali Metal Ion Binding Affinities of Several Azines Determined by Threshold Collision-Induced Dissociation and Ab Initio Theory,
Int. J. Mass Spectrom., 2000, 195/196, 439, https://doi.org/10.1016/S1387-3806(99)00145-1
. [all data]
Huang and Rodgers, 2002
Huang, H.; Rodgers, M.T.,
Sigma versus Pi interactions in alkali metal ion binding to azoles: Threshold collision-induced dissociation and ab initio theory studies,
J. Phys. Chem. A, 2002, 106, 16, 4277, https://doi.org/10.1021/jp013630b
. [all data]
Rodgers, 2001
Rodgers, M.T.,
Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Aminopyridines,
J. Phys. Chem. A, 2001, 105, 35, 8145, https://doi.org/10.1021/jp011555z
. [all data]
Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T.,
Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies,
J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a
. [all data]
Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T.,
The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies,
J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584
. [all data]
Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B.,
Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory,
J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f
. [all data]
Rodgers, 2001, 2
Rodgers, M.T.,
Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Methylpyridines,
J. Phys. Chem. A, 2001, 105, 11, 2374, https://doi.org/10.1021/jp004055z
. [all data]
Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T.,
Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies,
Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4
. [all data]
Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T.,
Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies,
J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b
. [all data]
Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P.,
Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry,
J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360
. [all data]
Wu, 1979
Wu, C.H.,
Binding Energies of LiH2 and LiH2+ and the Ionization Potential of LiH2,
J. Chem. Phys., 1979, 71, 2, 783, https://doi.org/10.1063/1.438367
. [all data]
Castleman, Holland, et al., 1978
Castleman, A.W.; Holland, P.M.; Lindsay, D.M.; Peterson, K.I.,
The Properties of Clusters in the Gas Phase. 2. Ammonia about Metal Ions,
J. Am. Chem. Soc., 1978, 100, 19, 6039, https://doi.org/10.1021/ja00487a011
. [all data]
Gatland, 1984
Gatland, I.R.,
Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]
Gislason, 1984
Gislason, E.A.,
Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]
Viehland, 1984
Viehland, L.A.,
Interaction Potentials for Li+ - Rare - Gas Systems,
Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3
. [all data]
Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W.,
Mobility of gaseous lons in weak electric fields,
Ann. Phys., 1958, 4, 3, 233, https://doi.org/10.1016/0003-4916(58)90049-6
. [all data]
Takebe, 1983
Takebe, M.,
The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves,
J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763
. [all data]
Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E.,
The Clustering of O2 and He to Li+,
J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522
. [all data]
Gatland, Colonna-Romano, et al., 1975
Gatland, I.R.; Colonna-Romano, L.M.; Keller, G.E.,
Single and Double Clustering of Nitrogen to Li+,
Phys. Rev. A, 1975, 12, 5, 1885, https://doi.org/10.1103/PhysRevA.12.1885
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.