Lithium ion (1+)

Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar31.793cal/mol*KReviewChase, 1998Data last reviewed in December, 1983

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) • Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°39.4 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°39.5kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°39.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°31.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
39.4 (+2.5,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Argon = (Lithium ion (1+) • Argon)

By formula: Li+ + Ar = (Li+ • Ar)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kcal/molAVGN/AAverage of 4 out of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°7.cal/mol*KDTMcKnight and Sawina, 1973gas phase; ΔrS approximate; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
1.4294.IMobCassidy and Elford, 1985gas phase; M
1.9319.DTKeller, Beyer, et al., 1973gas phase; LOW E/N; M
2.6215.DTMcKnight and Sawina, 1973gas phase; ΔrS approximate; M

Lithium ion (1+) + Benzene = (Lithium ion (1+) • Benzene)

By formula: Li+ + C6H6 = (Li+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°38.5 ± 3.2kcal/molCIDTAmicangelo and Armentrout, 2000RCD
ΔrH°37.9kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°36.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°27.5cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°29.7kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) • Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°36.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°38.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°38.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°30.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Ammonia = (Lithium ion (1+) • Ammonia)

By formula: Li+ + H3N = (Li+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°39.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°38.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°23.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°32.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Formaldehyde = (Lithium ion (1+) • Formaldehyde)

By formula: Li+ + CH2O = (Li+ • CH2O)

Quantity Value Units Method Reference Comment
ΔrH°36.0kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°36.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°28.2kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) • Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ • CHN)

Quantity Value Units Method Reference Comment
ΔrH°36.4kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°36.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°28.kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylamine, N,N-dimethyl- = (Lithium ion (1+) • Methylamine, N,N-dimethyl-)

By formula: Li+ + C3H9N = (Li+ • C3H9N)

Quantity Value Units Method Reference Comment
ΔrH°42.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°40.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
ΔrS°28.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°33.kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

(Lithium ion (1+) • 3Water) + Water = (Lithium ion (1+) • 4Water)

By formula: (Li+ • 3H2O) + H2O = (Li+ • 4H2O)

Quantity Value Units Method Reference Comment
ΔrH°16.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°16.4kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°15. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°29.9cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
7.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) • 4Water) + Water = (Lithium ion (1+) • 5Water)

By formula: (Li+ • 4H2O) + H2O = (Li+ • 5H2O)

Quantity Value Units Method Reference Comment
ΔrH°13.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°13.9kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
ΔrH°12. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°31.4cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
ΔrS°23.cal/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.5300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) • Dimethylamine)

By formula: Li+ + C2H7N = (Li+ • C2H7N)

Quantity Value Units Method Reference Comment
ΔrH°42.2kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°34.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methylamine = (Lithium ion (1+) • Methylamine)

By formula: Li+ + CH5N = (Li+ • CH5N)

Quantity Value Units Method Reference Comment
ΔrH°41.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrS°26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°33.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) • 2Water) + Water = (Lithium ion (1+) • 3Water)

By formula: (Li+ • 2H2O) + H2O = (Li+ • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°22.5 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°17. ± 3.kcal/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
ΔrH°20.7kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.cal/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
ΔrS°24.9cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
10.0300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

Lithium ion (1+) + helium = (Lithium ion (1+) • helium)

By formula: Li+ + He = (Li+ • He)

Quantity Value Units Method Reference Comment
ΔrH°1.71kcal/molIMobGatland, 1984gas phase; M
ΔrH°1.64kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°1.69kcal/molIMobViehland, 1984gas phase; M
ΔrH°1.09kcal/molIMobMason and Sharp, 1958gas phase; M
ΔrH°3.16kcal/molIMobTakebe, 1983gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
-3.7309.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Water = (Lithium ion (1+) • Water)

By formula: Li+ + H2O = (Li+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°32.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°34.kcal/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
ΔrS°23.cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) • 5Water) + Water = (Lithium ion (1+) • 6Water)

By formula: (Li+ • 5H2O) + H2O = (Li+ • 6H2O)

Quantity Value Units Method Reference Comment
ΔrH°14.3 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°12.1kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°32.0cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) • Water) + Water = (Lithium ion (1+) • 2Water)

By formula: (Li+ • H2O) + H2O = (Li+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°27.0 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°25.8kcal/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.1cal/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Lithium ion (1+) + Pyridine = (Lithium ion (1+) • Pyridine)

By formula: Li+ + C5H5N = (Li+ • C5H5N)

Quantity Value Units Method Reference Comment
ΔrH°43.2 ± 3.5kcal/molCIDTAmunugama and Rodgers, 2000RCD
ΔrH°44.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + neon = (Lithium ion (1+) • neon)

By formula: Li+ + Ne = (Li+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°2.63kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°2.84kcal/molIMobViehland, 1984gas phase; M
ΔrH°3.34kcal/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Xenon = (Lithium ion (1+) • Xenon)

By formula: Li+ + Xe = (Li+ • Xe)

Quantity Value Units Method Reference Comment
ΔrH°12.3kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°12.6kcal/molIMobViehland, 1984gas phase; M
ΔrH°20.8kcal/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Krypton = (Lithium ion (1+) • Krypton)

By formula: Li+ + Kr = (Li+ • Kr)

Quantity Value Units Method Reference Comment
ΔrH°10.6kcal/molSCATTERINGGislason, 1984gas phase; M
ΔrH°9.2kcal/molIMobViehland, 1984gas phase; M
ΔrH°16.4kcal/molIMobTakebe, 1983gas phase; M

(Lithium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 3Dimethyl ether)

By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°21.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
26.3 (+1.4,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 4Dimethyl ether)

By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.3 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.8 (+1.6,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 2Dimethyl ether)

By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°28.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
31.1 (+0.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Acetaldehyde = (Lithium ion (1+) • Acetaldehyde)

By formula: Li+ + C2H4O = (Li+ • C2H4O)

Quantity Value Units Method Reference Comment
ΔrH°41.3kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) • 2Ammonia) + Ammonia = (Lithium ion (1+) • 3Ammonia)

By formula: (Li+ • 2H3N) + H3N = (Li+ • 3H3N)

Quantity Value Units Method Reference Comment
ΔrH°21.0kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°25.3cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 3Ammonia) + Ammonia = (Lithium ion (1+) • 4Ammonia)

By formula: (Li+ • 3H3N) + H3N = (Li+ • 4H3N)

Quantity Value Units Method Reference Comment
ΔrH°16.5kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°32.6cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 4Ammonia) + Ammonia = (Lithium ion (1+) • 5Ammonia)

By formula: (Li+ • 4H3N) + H3N = (Li+ • 5H3N)

Quantity Value Units Method Reference Comment
ΔrH°11.1kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°28.0cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • 5Ammonia) + Ammonia = (Lithium ion (1+) • 6Ammonia)

By formula: (Li+ • 5H3N) + H3N = (Li+ • 6H3N)

Quantity Value Units Method Reference Comment
ΔrH°9.3kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°25.3cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) • Ammonia) + Ammonia = (Lithium ion (1+) • 2Ammonia)

By formula: (Li+ • H3N) + H3N = (Li+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°33.1kcal/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.7cal/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Lithium ion (1+) + Propane, 2-fluoro- = (Lithium ion (1+) • Propane, 2-fluoro-)

By formula: Li+ + C3H7F = (Li+ • C3H7F)

Quantity Value Units Method Reference Comment
ΔrH°35.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) • Cyclohexane)

By formula: Li+ + C6H12 = (Li+ • C6H12)

Quantity Value Units Method Reference Comment
ΔrH°24.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propene = (Lithium ion (1+) • Propene)

By formula: Li+ + C3H6 = (Li+ • C3H6)

Quantity Value Units Method Reference Comment
ΔrH°23.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1-Propene, 2-methyl- = (Lithium ion (1+) • 1-Propene, 2-methyl-)

By formula: Li+ + C4H8 = (Li+ • C4H8)

Quantity Value Units Method Reference Comment
ΔrH°28.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Ethane, fluoro- = (Lithium ion (1+) • Ethane, fluoro-)

By formula: Li+ + C2H5F = (Li+ • C2H5F)

Quantity Value Units Method Reference Comment
ΔrH°34.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl fluoride = (Lithium ion (1+) • Methyl fluoride)

By formula: Li+ + CH3F = (Li+ • CH3F)

Quantity Value Units Method Reference Comment
ΔrH°31.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetic acid = (Lithium ion (1+) • Acetic acid)

By formula: Li+ + C2H4O2 = (Li+ • C2H4O2)

Quantity Value Units Method Reference Comment
ΔrH°41.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetone = (Lithium ion (1+) • Acetone)

By formula: Li+ + C3H6O = (Li+ • C3H6O)

Quantity Value Units Method Reference Comment
ΔrH°44.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propyne = (Lithium ion (1+) • Propyne)

By formula: Li+ + C3H4 = (Li+ • C3H4)

Quantity Value Units Method Reference Comment
ΔrH°28.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Difluoromethane = (Lithium ion (1+) • Difluoromethane)

By formula: Li+ + CH2F2 = (Li+ • CH2F2)

Quantity Value Units Method Reference Comment
ΔrH°26.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) • Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ • C2H6S)

Quantity Value Units Method Reference Comment
ΔrH°32.8kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-bromo- = (Lithium ion (1+) • Propane, 2-bromo-)

By formula: Li+ + C3H7Br = (Li+ • C3H7Br)

Quantity Value Units Method Reference Comment
ΔrH°30.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-iodo- = (Lithium ion (1+) • Propane, 2-iodo-)

By formula: Li+ + C3H7I = (Li+ • C3H7I)

Quantity Value Units Method Reference Comment
ΔrH°29.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ • C3H7NO)

Quantity Value Units Method Reference Comment
ΔrH°50.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Chloromethane = (Lithium ion (1+) • Chloromethane)

By formula: Li+ + CH3Cl = (Li+ • CH3Cl)

Quantity Value Units Method Reference Comment
ΔrH°25.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetonitrile = (Lithium ion (1+) • Acetonitrile)

By formula: Li+ + C2H3N = (Li+ • C2H3N)

Quantity Value Units Method Reference Comment
ΔrH°43.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) • Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ • CH2Cl2)

Quantity Value Units Method Reference Comment
ΔrH°29.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Propane, 2-chloro- = (Lithium ion (1+) • Propane, 2-chloro-)

By formula: Li+ + C3H7Cl = (Li+ • C3H7Cl)

Quantity Value Units Method Reference Comment
ΔrH°30.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetic acid, methyl ester = (Lithium ion (1+) • Acetic acid, methyl ester)

By formula: Li+ + C3H6O2 = (Li+ • C3H6O2)

Quantity Value Units Method Reference Comment
ΔrH°44.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) • Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ • CH3NO2)

Quantity Value Units Method Reference Comment
ΔrH°39.5kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

More, Gledening, et al., 1996
More, M.B.; Gledening, E.D.; Ray, D.; Feller, D.; Armentrout, P.B., Cation-Ether Complexes in the Gas Phase: Bond Dissociation Energies and Equilibrium Structures of Li+[O(CH3)2]x, x=1-4, J. Phys. Chem., 1996, 100, 5, 1605, https://doi.org/10.1021/jp9523175 . [all data]

McKnight and Sawina, 1973
McKnight, L.G.; Sawina, J.M., Equilibrium Constants and Binding Energies of Alkali Metal Ions with Inert Gases, Bull. Am. Phys. Soc., 1973, 18, 804. [all data]

Cassidy and Elford, 1985
Cassidy, R.A.; Elford, M.T., The Mobility of Li+ Ions in Helium and Argon, Aust. J. Phys., 1985, 38, 4, 587, https://doi.org/10.1071/PH850587 . [all data]

Keller, Beyer, et al., 1973
Keller, C.E.; Beyer, R.A.; Colonna-Romano, L.M., Clustering of Ar to Li+ and a Comparison of Drift - Tube Models, Phys. Rev. A, 1973, 8, 3, 1446, https://doi.org/10.1103/PhysRevA.8.1446 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P., Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry, J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360 . [all data]

Gatland, 1984
Gatland, I.R., Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Gislason, 1984
Gislason, E.A., Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Viehland, 1984
Viehland, L.A., Interaction Potentials for Li+ - Rare - Gas Systems, Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3 . [all data]

Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W., Mobility of gaseous lons in weak electric fields, Ann. Phys., 1958, 4, 3, 233, https://doi.org/10.1016/0003-4916(58)90049-6 . [all data]

Takebe, 1983
Takebe, M., The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves, J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763 . [all data]

Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E., The Clustering of O2 and He to Li+, J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522 . [all data]

Amunugama and Rodgers, 2000
Amunugama, R.; Rodgers, M.T., Absolute Alkali Metal Ion Binding Affinities of Several Azines Determined by Threshold Collision-Induced Dissociation and Ab Initio Theory, Int. J. Mass Spectrom., 2000, 195/196, 439, https://doi.org/10.1016/S1387-3806(99)00145-1 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L., Quoted in Keesee and Castleman, 1986, 1986. [all data]

Castleman, Holland, et al., 1978
Castleman, A.W.; Holland, P.M.; Lindsay, D.M.; Peterson, K.I., The Properties of Clusters in the Gas Phase. 2. Ammonia about Metal Ions, J. Am. Chem. Soc., 1978, 100, 19, 6039, https://doi.org/10.1021/ja00487a011 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References