Silane, dichlorodiethyl-


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid82.72cal/mol*KN/ANagiev, Dzhafarov, et al., 1969 

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
51.31298.16Nagiev, Dzhafarov, et al., 1969T = 13 to 298.16 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tc595.8KN/AStepanov, 1972Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Pc30.20atmN/AStepanov, 1972Uncertainty assigned by TRC = 0.1099 atm; TRC
Quantity Value Units Method Reference Comment
ρc2.20mol/lN/AStepanov, 1972Uncertainty assigned by TRC = 0.02 mol/l; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
9.37336.IJenkins and Chambers, 1954Based on data from 321. to 401. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference
321.3 to 400.84.196311483.-50.Jenkins and Chambers, 1954

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.141174.10Nagiev, Dzhafarov, et al., 1969DH

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
12.30174.10Nagiev, Dzhafarov, et al., 1969DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin RADIAN CORP
NIST MS number 76121

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedSE-30140.831.Kirichenko, Markov, et al., 1975Ar; Column length: 1. m
PackedSE-3070.809.Kirichenko, Markov, et al., 1975Ar; Column length: 1. m
PackedPolymethylsiloxane, (PMS-20000)50.822.6Ainshtein and Shulyatieva, 1972He, Chromosorb W; Column length: 2. m
PackedSE-3060.813.Garzó, Fekete, et al., 1967N2, Chromosorb W; Column length: 2. m

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nagiev, Dzhafarov, et al., 1969
Nagiev, M.F.; Dzhafarov, O.I.; Karasharli, K.A.; Kostryukov, V.N., Thermodynamic study of ethylchlorosilane in the range 13-300K, Dokl. Akad. Nauk, 1969, SSSR 184(3), 648-649. [all data]

Stepanov, 1972
Stepanov, N.G., Some physical properties of methyltrichlorosilane and diethyldichlorosilane on the saturation line and near the critical region, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 464. [all data]

Jenkins and Chambers, 1954
Jenkins, Arthur C.; Chambers, George F., Vapor Pressures of Silicon Compounds, Ind. Eng. Chem., 1954, 46, 11, 2367-2369, https://doi.org/10.1021/ie50539a043 . [all data]

Kirichenko, Markov, et al., 1975
Kirichenko, É.A.; Markov, B.A.; Kochetov, V.A.; Kuznetsova, T.I., Chromatographic retention indices of alkylchlorosilanes, Zh. Anal. Khim., 1975, 30, 6, 1038-1040. [all data]

Ainshtein and Shulyatieva, 1972
Ainshtein, A.A.; Shulyatieva, T.I., Retention indices of alkyl- and arylchlorosilanes, Zh. Anal. Khim., 1972, 27, 816-821. [all data]

Garzó, Fekete, et al., 1967
Garzó, G.; Fekete, J.; Blazsó, M., Determination of the gas chromatographic retention indices of various organometallic compounds, Acta Chim. Acad. Sci. Hung., 1967, 51, 4, 359-369. [all data]


Notes

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