Silane, dichlorodiethyl-
- Formula: C4H10Cl2Si
- Molecular weight: 157.114
- IUPAC Standard InChIKey: BYLOHCRAPOSXLY-UHFFFAOYSA-N
- CAS Registry Number: 1719-53-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Dichlorodiethylsilane; Diethyldichlorosilane; UN 1767; Diethyldichlorosilicon
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°liquid | 82.72 | cal/mol*K | N/A | Nagiev, Dzhafarov, et al., 1969 |
Constant pressure heat capacity of liquid
Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
51.31 | 298.16 | Nagiev, Dzhafarov, et al., 1969 | T = 13 to 298.16 K. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tc | 595.8 | K | N/A | Stepanov, 1972 | Uncertainty assigned by TRC = 0.6 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 30.20 | atm | N/A | Stepanov, 1972 | Uncertainty assigned by TRC = 0.1099 atm; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 2.20 | mol/l | N/A | Stepanov, 1972 | Uncertainty assigned by TRC = 0.02 mol/l; TRC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
9.37 | 336. | I | Jenkins and Chambers, 1954 | Based on data from 321. to 401. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference |
---|---|---|---|---|
321.3 to 400.8 | 4.19631 | 1483. | -50. | Jenkins and Chambers, 1954 |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.141 | 174.10 | Nagiev, Dzhafarov, et al., 1969 | DH |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
12.30 | 174.10 | Nagiev, Dzhafarov, et al., 1969 | DH |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | RADIAN CORP |
NIST MS number | 76121 |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | SE-30 | 140. | 831. | Kirichenko, Markov, et al., 1975 | Ar; Column length: 1. m |
Packed | SE-30 | 70. | 809. | Kirichenko, Markov, et al., 1975 | Ar; Column length: 1. m |
Packed | Polymethylsiloxane, (PMS-20000) | 50. | 822.6 | Ainshtein and Shulyatieva, 1972 | He, Chromosorb W; Column length: 2. m |
Packed | SE-30 | 60. | 813. | Garzó, Fekete, et al., 1967 | N2, Chromosorb W; Column length: 2. m |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nagiev, Dzhafarov, et al., 1969
Nagiev, M.F.; Dzhafarov, O.I.; Karasharli, K.A.; Kostryukov, V.N.,
Thermodynamic study of ethylchlorosilane in the range 13-300K,
Dokl. Akad. Nauk, 1969, SSSR 184(3), 648-649. [all data]
Stepanov, 1972
Stepanov, N.G.,
Some physical properties of methyltrichlorosilane and diethyldichlorosilane on the saturation line and near the critical region,
Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 464. [all data]
Jenkins and Chambers, 1954
Jenkins, Arthur C.; Chambers, George F.,
Vapor Pressures of Silicon Compounds,
Ind. Eng. Chem., 1954, 46, 11, 2367-2369, https://doi.org/10.1021/ie50539a043
. [all data]
Kirichenko, Markov, et al., 1975
Kirichenko, É.A.; Markov, B.A.; Kochetov, V.A.; Kuznetsova, T.I.,
Chromatographic retention indices of alkylchlorosilanes,
Zh. Anal. Khim., 1975, 30, 6, 1038-1040. [all data]
Ainshtein and Shulyatieva, 1972
Ainshtein, A.A.; Shulyatieva, T.I.,
Retention indices of alkyl- and arylchlorosilanes,
Zh. Anal. Khim., 1972, 27, 816-821. [all data]
Garzó, Fekete, et al., 1967
Garzó, G.; Fekete, J.; Blazsó, M.,
Determination of the gas chromatographic retention indices of various organometallic compounds,
Acta Chim. Acad. Sci. Hung., 1967, 51, 4, 359-369. [all data]
Notes
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- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure S°liquid Entropy of liquid at standard conditions Tc Critical temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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