Silane, dichlorodiethyl-
- Formula: C4H10Cl2Si
- Molecular weight: 157.114
- IUPAC Standard InChIKey: BYLOHCRAPOSXLY-UHFFFAOYSA-N
- CAS Registry Number: 1719-53-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Dichlorodiethylsilane; Diethyldichlorosilane; UN 1767; Diethyldichlorosilicon
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Phase change data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tc | 595.8 | K | N/A | Stepanov, 1972 | Uncertainty assigned by TRC = 0.6 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 30.20 | atm | N/A | Stepanov, 1972 | Uncertainty assigned by TRC = 0.1099 atm; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 2.20 | mol/l | N/A | Stepanov, 1972 | Uncertainty assigned by TRC = 0.02 mol/l; TRC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
9.37 | 336. | I | Jenkins and Chambers, 1954 | Based on data from 321. to 401. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference |
---|---|---|---|---|
321.3 to 400.8 | 4.19631 | 1483. | -50. | Jenkins and Chambers, 1954 |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.141 | 174.10 | Nagiev, Dzhafarov, et al., 1969 | DH |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
12.30 | 174.10 | Nagiev, Dzhafarov, et al., 1969 | DH |
Gas Chromatography
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | SE-30 | 140. | 831. | Kirichenko, Markov, et al., 1975 | Ar; Column length: 1. m |
Packed | SE-30 | 70. | 809. | Kirichenko, Markov, et al., 1975 | Ar; Column length: 1. m |
Packed | Polymethylsiloxane, (PMS-20000) | 50. | 822.6 | Ainshtein and Shulyatieva, 1972 | He, Chromosorb W; Column length: 2. m |
Packed | SE-30 | 60. | 813. | Garzó, Fekete, et al., 1967 | N2, Chromosorb W; Column length: 2. m |
References
Go To: Top, Phase change data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stepanov, 1972
Stepanov, N.G.,
Some physical properties of methyltrichlorosilane and diethyldichlorosilane on the saturation line and near the critical region,
Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 464. [all data]
Jenkins and Chambers, 1954
Jenkins, Arthur C.; Chambers, George F.,
Vapor Pressures of Silicon Compounds,
Ind. Eng. Chem., 1954, 46, 11, 2367-2369, https://doi.org/10.1021/ie50539a043
. [all data]
Nagiev, Dzhafarov, et al., 1969
Nagiev, M.F.; Dzhafarov, O.I.; Karasharli, K.A.; Kostryukov, V.N.,
Thermodynamic study of ethylchlorosilane in the range 13-300K,
Dokl. Akad. Nauk, 1969, SSSR 184(3), 648-649. [all data]
Kirichenko, Markov, et al., 1975
Kirichenko, É.A.; Markov, B.A.; Kochetov, V.A.; Kuznetsova, T.I.,
Chromatographic retention indices of alkylchlorosilanes,
Zh. Anal. Khim., 1975, 30, 6, 1038-1040. [all data]
Ainshtein and Shulyatieva, 1972
Ainshtein, A.A.; Shulyatieva, T.I.,
Retention indices of alkyl- and arylchlorosilanes,
Zh. Anal. Khim., 1972, 27, 816-821. [all data]
Garzó, Fekete, et al., 1967
Garzó, G.; Fekete, J.; Blazsó, M.,
Determination of the gas chromatographic retention indices of various organometallic compounds,
Acta Chim. Acad. Sci. Hung., 1967, 51, 4, 359-369. [all data]
Notes
Go To: Top, Phase change data, Gas Chromatography, References
- Symbols used in this document:
Pc Critical pressure Tc Critical temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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