bis(2-fluoro-2,2-dinitroethoxy)methane
- Formula: C5H6F2N4O10
- Molecular weight: 320.1187
- CAS Registry Number: 17003-79-1
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -202.92 ± 0.43 | kcal/mol | Ccb | Kustova, Kirpichev, et al., 1981 | Reanalyzed by Cox and Pilcher, 1970, Original value = -203.1 ± 0.41 kcal/mol |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -557.91 ± 0.31 | kcal/mol | Ccb | Kustova, Kirpichev, et al., 1981 | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | -178.8 | kcal/mol | Ccb | Fedoroff and Shefield, 1975 | Insufficient ancillary data to correct to current CODATA ΔfH values |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 20.3 | 344. | Minier and Behrens, 1997 | Based on data from 323. to 365. K. |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kustova, Kirpichev, et al., 1981
Kustova, L.V.; Kirpichev, E.P.; Rubtsov, Yu.I.; Avdonin, V.V.; Korepin, A.G.; Eremenko, L.T.,
Standard enthalpies of formation of certain nitro compounds,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981, 1830-1836. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Fedoroff and Shefield, 1975
Fedoroff, B.T.; Shefield, O.E.,
Table 1. Standard heats of formation and heats of detonation of common explosives
in Encyclopedia of Explosives and Related Items, Part 2700 Volume 7, Picatinny Arsenal, Dover, NJ., 1975, 41-42. [all data]
Minier and Behrens, 1997
Minier, Leanna M.G.; Behrens, Richard,
Thermal decomposition mechanisms of bis(2-fluoro-2,2-dinitroethyl) formal (FEFO) and bis(2-fluoro-2,2-dinitroethyl) difluoroformal (DFF) from simultaneous thermogravimetric modulated beam mass spectrometry (STMBMS) measurements,
Propellants Explos. Pyrotech., 1997, 22, 1, 23-33, https://doi.org/10.1002/prep.19970220107
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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