2,2,4,4,6,6-Hexamethyl-8,8-diphenyl-[1,3,5,7,2,4,6,8]cyclotetrasiloxane
- Formula: C18H28O4Si4
- Molecular weight: 420.7545
- IUPAC Standard InChIKey: BOIFXPDTOHPTOD-UHFFFAOYSA-N
- CAS Registry Number: 1693-44-3
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: 2,2,4,4,6,6-hexamethyl-8,8-diphenylcyclotetrasiloxane; 1,1,3,3,5,5-Hexamethyl-7,7-diphenylcyclotetrasiloxane
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Ttriple | 304.96 | K | N/A | Mekhtiev and Karasharli, 1981 | Uncertainty assigned by TRC = 0.02 K; TRC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
42.731 | 304.96 | Mekhtiev and Karasharli, 1981 | DH |
42.731 | 305.09 | Mekhtiev, Karasharli, et al., 1975 | DH |
42.73 | 305. | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
140.1 | 304.96 | Mekhtiev and Karasharli, 1981 | DH |
140.1 | 305.09 | Mekhtiev, Karasharli, et al., 1975 | DH |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Methyl Silicone | 1883. | Fujimoto, Ohtani, et al., 1990 | 25. m/0.25 mm/0.1 μm, He, 5. K/min; Tstart: 40. C; Tend: 350. C |
References
Go To: Top, Phase change data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mekhtiev and Karasharli, 1981
Mekhtiev, S.A.; Karasharli, K.A.,
Analysis of the results of thermodynamic studies of a series of organosilicon compounds,
Azerb. Khim. Zhur., 1981, (5), 85-88. [all data]
Mekhtiev, Karasharli, et al., 1975
Mekhtiev, S.A.; Karasharli, K.A.; Dzhafarov, O.I.,
The true heat capacity of 1,1,3,3,5,5-hexamethyl-7,7-diphenylcyclotetrasiloxane in the temperature range 13 to 320 K,
Zhur. Fiz. Khim., 1975, 49, 259. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Fujimoto, Ohtani, et al., 1990
Fujimoto, S.; Ohtani, H.; Yamagiwa, K.; Tsuge, S.,
Study on retention behavior of cyclic siloxanes by high resolution pyrolysis-gas chromatography with a fused silica capillary column,
J. Hi. Res. Chromatogr., 1990, 13, 6, 397-404, https://doi.org/10.1002/jhrc.1240130603
. [all data]
Notes
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- Symbols used in this document:
Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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