Vanadium anion


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

V- + Hydrogen cation = HV

By formula: V- + H+ = HV

Quantity Value Units Method Reference Comment
Δr339.7 ± 3.4kcal/molG+TSSallans, Lane, et al., 1985gas phase
Δr340.9 ± 3.7kcal/molAcidFeigerle, Corderman, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Δr332.0 ± 3.0kcal/molIMRBSallans, Lane, et al., 1985gas phase
Δr333.1 ± 5.2kcal/molH-TSFeigerle, Corderman, et al., 1981gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

V- + Benzene, fluoro- = (V- • Benzene, fluoro-)

By formula: V- + C6H5F = (V- • C6H5F)

Quantity Value Units Method Reference Comment
Δr14.4 ± 3.8kcal/molN/AJudai, Hirano, et al., 1997gas phase

(V- • Benzene, fluoro-) + Benzene = (V- • Benzene • Benzene, fluoro-)

By formula: (V- • C6H5F) + C6H6 = (V- • C6H6 • C6H5F)

Quantity Value Units Method Reference Comment
Δr3. ± 15.kcal/molN/AJudai, Hirano, et al., 1997gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S., Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH, J. Am. Chem. Soc., 1985, 107, 4379. [all data]

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C., Binding Energies and Structure of Transition Metal Negative Ions, J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289 . [all data]

Judai, Hirano, et al., 1997
Judai, K.; Hirano, M.; Kawamata, H.; Yabushita, S.; Nakajima, A.; Kaya, K., Formation of Vanadium-Arene Complex Anions and Their Photoelectron Spectroscopy, Chem. Phys. Lett., 1997, 270, 1-2, 23, https://doi.org/10.1016/S0009-2614(97)00336-9 . [all data]


Notes

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