Vanadium anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas110.77 ± 0.57kcal/molR-EAFeigerle, Corderman, et al., 1981B
Quantity Value Units Method Reference Comment
gas,1 bar43.843cal/mol*KReviewChase, 1998Data last reviewed in March, 1984

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

V- + Hydrogen cation = HV

By formula: V- + H+ = HV

Quantity Value Units Method Reference Comment
Δr339.7 ± 3.4kcal/molG+TSSallans, Lane, et al., 1985gas phase
Δr340.9 ± 3.7kcal/molAcidFeigerle, Corderman, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Δr332.0 ± 3.0kcal/molIMRBSallans, Lane, et al., 1985gas phase
Δr333.1 ± 5.2kcal/molH-TSFeigerle, Corderman, et al., 1981gas phase

(V- • Benzene, fluoro-) + Benzene = (V- • Benzene • Benzene, fluoro-)

By formula: (V- • C6H5F) + C6H6 = (V- • C6H6 • C6H5F)

Quantity Value Units Method Reference Comment
Δr3. ± 15.kcal/molN/AJudai, Hirano, et al., 1997gas phase

V- + Benzene, fluoro- = (V- • Benzene, fluoro-)

By formula: V- + C6H5F = (V- • C6H5F)

Quantity Value Units Method Reference Comment
Δr14.4 ± 3.8kcal/molN/AJudai, Hirano, et al., 1997gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

V- + Hydrogen cation = HV

By formula: V- + H+ = HV

Quantity Value Units Method Reference Comment
Δr339.7 ± 3.4kcal/molG+TSSallans, Lane, et al., 1985gas phase
Δr340.9 ± 3.7kcal/molAcidFeigerle, Corderman, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Δr332.0 ± 3.0kcal/molIMRBSallans, Lane, et al., 1985gas phase
Δr333.1 ± 5.2kcal/molH-TSFeigerle, Corderman, et al., 1981gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Feigerle, Corderman, et al., 1981
Feigerle, C.S.; Corderman, R.R.; Bobashev, S.V.; Lineberger, W.C., Binding Energies and Structure of Transition Metal Negative Ions, J. Chem. Phys., 1981, 74, 3, 1580, https://doi.org/10.1063/1.441289 . [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S., Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH, J. Am. Chem. Soc., 1985, 107, 4379. [all data]

Judai, Hirano, et al., 1997
Judai, K.; Hirano, M.; Kawamata, H.; Yabushita, S.; Nakajima, A.; Kaya, K., Formation of Vanadium-Arene Complex Anions and Their Photoelectron Spectroscopy, Chem. Phys. Lett., 1997, 270, 1-2, 23, https://doi.org/10.1016/S0009-2614(97)00336-9 . [all data]


Notes

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