tris(1,1,1-trifluoropentane-2,4-dionato-O,O')ruthenium


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltasub129.9 ± 1.0kJ/molMERibeiro da Silva, Monte, et al., 2001 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
131.4 ± 4.6346. - 467.MEMorozova, Zherikova, et al., 2009 
126.8 ± 1.0360.MERibeiro da Silva, Monte, et al., 2001Based on data from 350. - 369. K.
90.0 ± 3.0383. - 423.N/ABykov, Morozova, et al., 1996 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Monte, et al., 2001
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Giera, Edward, Thermodynamic study of the sublimation of crystalline tris(1,1,1-trifluoro-2,4-pentanedionate)ruthenium(III) and tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionate)ruthenium(III), The Journal of Chemical Thermodynamics, 2001, 33, 4, 369-376, https://doi.org/10.1006/jcht.2000.0734 . [all data]

Morozova, Zherikova, et al., 2009
Morozova, N.B.; Zherikova, K.V.; Semyannikov, P.P.; Trubin, S.V.; Igumenov, I.K., Study of temperature dependencies of saturated vapor pressure of ruthenium(III) beta-diketonate derivatives, J Therm Anal Calorim, 2009, 98, 2, 395-399, https://doi.org/10.1007/s10973-009-0309-8 . [all data]

Bykov, Morozova, et al., 1996
Bykov, A.F.; Morozova, N.B.; Igumenov, I.K.; Sysoev, S.V., Investigation of thermal properties of ruthenium(III) «BETA»-diketonate precursors for preparation of RuO2 films by CVD, Journal of Thermal Analysis, 1996, 46, 6, 1551-1565, https://doi.org/10.1007/BF01980761 . [all data]


Notes

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