Cobalt ion (1+)

Formula: Co⁺
Molecular weight: 58.932646
IUPAC Standard InChI: InChI=1S/Co/q+1
IUPAC Standard InChIKey: BFVNPAKTAJENJQ-UHFFFAOYSA-N
CAS Registry Number: 16610-75-6
Chemical structure:
This structure is also available as a 2d Mol file
Other names: Cobalt cation
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- Reaction thermochemistry data: reactions 51 to 73
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Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Quantity	Value	Units	Method	Reference	Comment
S°_{gas,1 bar}	178.34	J/mol*K	Review	Chase, 1998	Data last reviewed in June, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, References, Notes

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

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Reactions 1 to 50

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2CH₄) + CH₄ = (Co⁺ • 3CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	46.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	84.	J/mol*K	N/A	Kemper, Bushnell, et al., 1993	gas phase; Entropy change calculated or estimated; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
41. (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
3.	477.	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Entropy change calculated or estimated; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + H₂ = (Co⁺ • H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	82. ± 4.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(O K)=76.1 kJ/mol, Δ_rS(300 K)=86.2 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	92.0	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(O K)=76.1 kJ/mol, Δ_rS(300 K)=86.2 J/mol*K; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
73.2 (+9.6,-0.)		CID	Haynes and Armentrout, 1996	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CH₄ = (Co⁺ • CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	82.8	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	Method	Reference	Comment
90.0 (+6.7,-0.)	CID	Haynes and Armentrout, 1996	gas phase; guided ion beam CID; M
90.0 (+5.9,-0.)	CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
94. (+2.,-0.)	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • C₆H₆) + C₆H₆ = (Co⁺ • 2C₆H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	167. ± 14.	kJ/mol	CIDT	Meyer, Khan, et al., 1995	RCD
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	116.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
167. (+13.,-0.)		CID	Meyer, Khan, et al., 1995	gas phase; guided ion beam CID; M
113. (+4.2,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₂H₆ = (Co⁺ • C₂H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	93.3	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)CH4, Δ_rS(500 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
100. (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
117. (+6.7,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)CH4, Δ_rS(500 K); M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2He) + He = (Co⁺ • 3He)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	5.5 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 5.10 kJ/mol, Δ_rS(100 K) = 46.4 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	48.5	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 5.10 kJ/mol, Δ_rS(100 K) = 46.4 J/mol*K; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • Ne) + Ne = (Co⁺ • 2Ne)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.2 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH90 K) = 8.16 kJ/mol, Δ_rS(100 K) = 52.3 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	48.5	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH90 K) = 8.16 kJ/mol, Δ_rS(100 K) = 52.3 J/mol*K; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • He) + He = (Co⁺ • 2He)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.4 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 14.3 kJ/mol, Δ_rS(100 K) = 79.9 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	82.0	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 14.3 kJ/mol, Δ_rS(100 K) = 79.9 J/mol*K; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CO = (Co⁺ • CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	174. ± 7.1	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD
Δ_rH°	160. ± 10.	kJ/mol	MKER	Carpenter, van Koppen, et al., 1995	gas phase; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
174. (+6.7,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M
163. (+20.,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + Ne = (Co⁺ • Ne)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.5 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 9.12 kJ/mol, Δ_rS(100 K) = 58.6 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	64.4	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 9.12 kJ/mol, Δ_rS(100 K) = 58.6 J/mol*K; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + He = (Co⁺ • He)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.9 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 12.6 kJ/mol, Δ_rS(100 K) = 61.5 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	71.5	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 12.6 kJ/mol, Δ_rS(100 K) = 61.5 J/mol*K; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • CH₄) + H₂ = (Co⁺ • H₂ • CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	95.8	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
73. (+3.,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • H₂) + CH₄ = (Co⁺ • CH₄ • H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	91.2	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
94.6 (+5.0,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • H₂) + H₂ = (Co⁺ • 2H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	75. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=71.1 kJ/mol, Δ_rS(300 K)=103. J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	103.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=71.1 kJ/mol, Δ_rS(300 K)=103. J/mol*K; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2H₂) + H₂ = (Co⁺ • 3H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	44. ± 2.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=85.8 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	85.8	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=85.8 J/mol*K; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3H₂) + H₂ = (Co⁺ • 4H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	44. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=105. J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	101.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=105. J/mol*K; M

( Cobalt ion (1+) • 4) + = ( • 5)

By formula: (Co⁺ • 4H₂) + H₂ = (Co⁺ • 5H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	22. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=18. kJ/mol, Δ_rS(300 K)=91.6 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	94.1	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=18. kJ/mol, Δ_rS(300 K)=91.6 J/mol*K; M

( Cobalt ion (1+) • 5) + = ( • 6)

By formula: (Co⁺ • 5H₂) + H₂ = (Co⁺ • 6H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=17. kJ/mol, Δ_rS(300 K)=99.6 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	99.2	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=17. kJ/mol, Δ_rS(300 K)=99.6 J/mol*K; M

( Cobalt ion (1+) • 6) + = ( • 7)

By formula: (Co⁺ • 6H₂) + H₂ = (Co⁺ • 7H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	6. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=3. kJ/mol; Δ_rS(300 K)=75.3 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	75.3	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=3. kJ/mol; Δ_rS(300 K)=75.3 J/mol*K; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • CH₄) + CH₄ = (Co⁺ • 2CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	109.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(500 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
95.8 (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
104. (+4.2,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(500 K); M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₂H₄ = (Co⁺ • C₂H₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	186. ± 9.2	kJ/mol	CIDT	Sievers, Jarvis, et al., 1998	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
179. (+7.1,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
27. (+13.,-0.)		CID	Haynes and Armentrout, 1994	gas phase; Δ_rH>=, guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • CO) + CO = (Co⁺ • 2CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	153. ± 9.2	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
152. (+8.8,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M
138. (+20.,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • CH₄) + C₂H₆ = (Co⁺ • C₂H₆ • CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	108.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2CH4, Δ_rS(480 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
119. (+5.4,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2CH4, Δ_rS(480 K); M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + H₂O = (Co⁺ • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	160. ± 10.	kJ/mol	CID	Magnera, David, et al., 1989	gas phase; M
Δ_rH°	168.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
161. (+5.9,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • H₂O) + H₂ = (Co⁺ • H₂ • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	103.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
83. (+3.,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • H₂O) + CH₄ = (Co⁺ • CH₄ • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	113.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(525 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
108. (+3.,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(525 K); M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • C₂H₆) + CH₄ = (Co⁺ • CH₄ • C₂H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	110.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
102. (+4.6,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₃H₆ = (Co⁺ • C₃H₆)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
180. (+7.1,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
180. (+6.7,-0.)		CID	Haynes and Armentrout, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • H₂O) + H₂O = (Co⁺ • 2H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	175.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
162. (+7.1,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₂H₂ = (Co⁺ • C₂H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	180. ± 7.9	kJ/mol	IRMPD	Surya, Ranatunga, et al., 1997	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
27. (+13.,-0.)		CID	Armentrout and Kickel, 1994	gas phase; Δ_rH >=, guided ion beam CID; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2CO) + CO = (Co⁺ • 3CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	82. ± 12.	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
82. (+12.,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3CO) + CO = (Co⁺ • 4CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	74.9 ± 5.9	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
75.3 (+5.9,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 4) + = ( • 5)

By formula: (Co⁺ • 4CO) + CO = (Co⁺ • 5CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	74.9 ± 5.0	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
75.3 (+5.0,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₆H₆ = (Co⁺ • C₆H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	256. ± 11.	kJ/mol	CIDT	Meyer, Khan, et al., 1995	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
256. (+10.,-0.)		CID	Meyer, Khan, et al., 1995	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • H₃N) + H₃N = (Co⁺ • 2H₃N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	248. ± 13.	kJ/mol	CIDT	Walter and Armentrout, 1998	RCD
Δ_rH°	256.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + H₃N = (Co⁺ • H₃N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	218. ± 15.	kJ/mol	CIDT	Walter and Armentrout, 1998	RCD
Δ_rH°	246.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CH₃ = (Co⁺ • CH₃)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	204. ± 13.	kJ/mol	CIDT	Fisher, Sunderlin, et al., 1989	RCD
Δ_rH°	205. ± 15.	kJ/mol	CIDT	Georgiadis, Fisher, et al., 1989	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CS = (Co⁺ • CS)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	258. ± 33.	kJ/mol	CIDT	Rue, Armentrout, et al., 2001	RCD
Δ_rH°	240. ± 9.2	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2H₂O) + H₂O = (Co⁺ • 3H₂O)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
64.9 (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3H₂O) + H₂O = (Co⁺ • 4H₂O)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
58.2 (+5.9,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₃H₄ = (Co⁺ • C₃H₄)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
79.1 (+8.8,-0.)		CID	Haynes and Armentrout, 1994	gas phase; Δ_rH>=, guided ion beam CID; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3CH₄) + CH₄ = (Co⁺ • 4CH₄)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
67.8 (+5.9,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 10) + = ( • 11)

By formula: (Co⁺ • 10Co) + Co = (Co⁺ • 11Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
329.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 11) + = ( • 12)

By formula: (Co⁺ • 11Co) + Co = (Co⁺ • 12Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
351.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 12) + = ( • 13)

By formula: (Co⁺ • 12Co) + Co = (Co⁺ • 13Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
303.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 13) + = ( • 14)

By formula: (Co⁺ • 13Co) + Co = (Co⁺ • 14Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
380.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 14) + = ( • 15)

By formula: (Co⁺ • 14Co) + Co = (Co⁺ • 15Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
355.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 15) + = ( • 16)

By formula: (Co⁺ • 15Co) + Co = (Co⁺ • 16Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
346.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 16) + = ( • 17)

By formula: (Co⁺ • 16Co) + Co = (Co⁺ • 17Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
371.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 9) + = ( • 10)

By formula: (Co⁺ • 9Co) + Co = (Co⁺ • 10Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
314.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + Ar = (Co⁺ • Ar)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	49.4	kJ/mol	PDis	Asher, Bellert, et al., 1994	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CH₂ = (Co⁺ • CH₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	318. ± 5.0	kJ/mol	CIDT	Haynes and Armentrout, 1994	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CH₃ = (Co⁺ • CH₃)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	204. ± 13.	kJ/mol	CIDT	Fisher, Sunderlin, et al., 1989	RCD
Δ_rH°	205. ± 15.	kJ/mol	CIDT	Georgiadis, Fisher, et al., 1989	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CH₄O = (Co⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	148. ± 7.9	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CH₄ = (Co⁺ • CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	82.8	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	Method	Reference	Comment
90.0 (+6.7,-0.)	CID	Haynes and Armentrout, 1996	gas phase; guided ion beam CID; M
90.0 (+5.9,-0.)	CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
94. (+2.,-0.)	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • CH₄) + CH₄ = (Co⁺ • 2CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	109.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(500 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
95.8 (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
104. (+4.2,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(500 K); M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2CH₄) + CH₄ = (Co⁺ • 3CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	46.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	84.	J/mol*K	N/A	Kemper, Bushnell, et al., 1993	gas phase; Entropy change calculated or estimated; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
41. (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Free energy of reaction

Δ_rG° (kJ/mol)	T (K)	Method	Reference	Comment
3.	477.	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Entropy change calculated or estimated; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3CH₄) + CH₄ = (Co⁺ • 4CH₄)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
67.8 (+5.9,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • CH₄) + C₂H₆ = (Co⁺ • C₂H₆ • CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	108.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2CH4, Δ_rS(480 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
119. (+5.4,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2CH4, Δ_rS(480 K); M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • CH₄) + H₂ = (Co⁺ • H₂ • CH₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	95.8	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
73. (+3.,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+).2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CO = (Co⁺ • CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	174. ± 7.1	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD
Δ_rH°	160. ± 10.	kJ/mol	MKER	Carpenter, van Koppen, et al., 1995	gas phase; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
174. (+6.7,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M
163. (+20.,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • CO) + CO = (Co⁺ • 2CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	153. ± 9.2	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
152. (+8.8,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M
138. (+20.,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2CO) + CO = (Co⁺ • 3CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	82. ± 12.	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
82. (+12.,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3CO) + CO = (Co⁺ • 4CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	74.9 ± 5.9	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
75.3 (+5.9,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 4) + = ( • 5)

By formula: (Co⁺ • 4CO) + CO = (Co⁺ • 5CO)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	74.9 ± 5.0	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
75.3 (+5.0,-0.)		CID	Goebel, Haynes, et al., 1995	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + CS = (Co⁺ • CS)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	258. ± 33.	kJ/mol	CIDT	Rue, Armentrout, et al., 2001	RCD
Δ_rH°	240. ± 9.2	kJ/mol	CIDT	Rodgers and Armentrout, 2000	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₂H₂ = (Co⁺ • C₂H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	180. ± 7.9	kJ/mol	IRMPD	Surya, Ranatunga, et al., 1997	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
27. (+13.,-0.)		CID	Armentrout and Kickel, 1994	gas phase; Δ_rH >=, guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₂H₄ = (Co⁺ • C₂H₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	186. ± 9.2	kJ/mol	CIDT	Sievers, Jarvis, et al., 1998	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
179. (+7.1,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
27. (+13.,-0.)		CID	Haynes and Armentrout, 1994	gas phase; Δ_rH>=, guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • C₂H₄) + C₂H₄ = (Co⁺ • 2C₂H₄)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	152. ± 14.	kJ/mol	CIDT	Sievers, Jarvis, et al., 1998	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₂H₆ = (Co⁺ • C₂H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	93.3	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)CH4, Δ_rS(500 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
100. (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
117. (+6.7,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)CH4, Δ_rS(500 K); M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • C₂H₆) + CH₄ = (Co⁺ • CH₄ • C₂H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	110.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
102. (+4.6,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2C₂H₆) + C₂H₆ = (Co⁺ • 3C₂H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	50.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rH<; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₃H₄ = (Co⁺ • C₃H₄)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
79.1 (+8.8,-0.)		CID	Haynes and Armentrout, 1994	gas phase; Δ_rH>=, guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₃H₆ = (Co⁺ • C₃H₆)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
180. (+7.1,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M
180. (+6.7,-0.)		CID	Haynes and Armentrout, 1994	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₃H₈ = (Co⁺ • C₃H₈)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
129. (+5.9,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₄H₄N₂ = (Co⁺ • C₄H₄N₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	245. ± 13.	kJ/mol	CIDT	Amunugama and Rodgers, 2001	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₄H₅N = (Co⁺ • C₄H₅N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	>280.	kJ/mol	RAK	Gapeev and Yang, 2000	RCD

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • C₄H₅N) + C₄H₅N = (Co⁺ • 2C₄H₅N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	194.	kJ/mol	RAK	Gapeev and Yang, 2000	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₅H₅N = (Co⁺ • C₅H₅N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	247. ± 13.	kJ/mol	CIDT	Rodgers, Stanley, et al., 2000	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₅H₅N₅ = (Co⁺ • C₅H₅N₅)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	293. ± 10.	kJ/mol	CIDT	Rodgers and Armentrout, 2002	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + C₆H₆ = (Co⁺ • C₆H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	256. ± 11.	kJ/mol	CIDT	Meyer, Khan, et al., 1995	RCD

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
256. (+10.,-0.)		CID	Meyer, Khan, et al., 1995	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • C₆H₆) + C₆H₆ = (Co⁺ • 2C₆H₆)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	167. ± 14.	kJ/mol	CIDT	Meyer, Khan, et al., 1995	RCD
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	116.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
167. (+13.,-0.)		CID	Meyer, Khan, et al., 1995	gas phase; guided ion beam CID; M
113. (+4.2,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(490 K); M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + Co = (Co⁺ • Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
267.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • Co) + Co = (Co⁺ • 2Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
201.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2Co) + Co = (Co⁺ • 3Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
205.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3Co) + Co = (Co⁺ • 4Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
274.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 4) + = ( • 5)

By formula: (Co⁺ • 4Co) + Co = (Co⁺ • 5Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
319.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 5) + = ( • 6)

By formula: (Co⁺ • 5Co) + Co = (Co⁺ • 6Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
283.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 6) + = ( • 7)

By formula: (Co⁺ • 6Co) + Co = (Co⁺ • 7Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
303.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 7) + = ( • 8)

By formula: (Co⁺ • 7Co) + Co = (Co⁺ • 8Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
283.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 8) + = ( • 9)

By formula: (Co⁺ • 8Co) + Co = (Co⁺ • 9Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
285.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 9) + = ( • 10)

By formula: (Co⁺ • 9Co) + Co = (Co⁺ • 10Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
314.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 10) + = ( • 11)

By formula: (Co⁺ • 10Co) + Co = (Co⁺ • 11Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
329.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 11) + = ( • 12)

By formula: (Co⁺ • 11Co) + Co = (Co⁺ • 12Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
351.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 12) + = ( • 13)

By formula: (Co⁺ • 12Co) + Co = (Co⁺ • 13Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
303.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 13) + = ( • 14)

By formula: (Co⁺ • 13Co) + Co = (Co⁺ • 14Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
380.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 14) + = ( • 15)

By formula: (Co⁺ • 14Co) + Co = (Co⁺ • 15Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
355.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 15) + = ( • 16)

By formula: (Co⁺ • 15Co) + Co = (Co⁺ • 16Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
346.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 16) + = ( • 17)

By formula: (Co⁺ • 16Co) + Co = (Co⁺ • 17Co)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
371.		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + D₂ = (Co⁺ • D₂)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
71.5 (+6.7,-0.)		CID	Haynes and Armentrout, 1996	gas phase; guided ion beam CID; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + H₂O = (Co⁺ • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	160. ± 10.	kJ/mol	CID	Magnera, David, et al., 1989	gas phase; M
Δ_rH°	168.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
161. (+5.9,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • H₂O) + CH₄ = (Co⁺ • CH₄ • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	113.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(525 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
108. (+3.,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(525 K); M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • H₂O) + H₂O = (Co⁺ • 2H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	175.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
162. (+7.1,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2H₂O) + H₂O = (Co⁺ • 3H₂O)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
64.9 (+5.0,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3H₂O) + H₂O = (Co⁺ • 4H₂O)

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
58.2 (+5.9,-0.)		CID	Armentrout and Kickel, 1994	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • H₂O) + H₂ = (Co⁺ • H₂ • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	103.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
83. (+3.,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; Δ_rS(530 K); M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + H₂ = (Co⁺ • H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	82. ± 4.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(O K)=76.1 kJ/mol, Δ_rS(300 K)=86.2 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	92.0	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(O K)=76.1 kJ/mol, Δ_rS(300 K)=86.2 J/mol*K; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
73.2 (+9.6,-0.)		CID	Haynes and Armentrout, 1996	gas phase; guided ion beam CID; M

( Cobalt ion (1+) • ) + = ( • • )

By formula: (Co⁺ • H₂) + CH₄ = (Co⁺ • CH₄ • H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	91.2	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

Δ_rH° (kJ/mol)	T (K)	Method	Reference	Comment
94.6 (+5.0,-0.)		SIDT	Kemper, Bushnell, et al., 1993	gas phase; switching reaction(Co+)2H2, Δ_rS(440 K); Kemper, Bushnell, et al., 1993, 2; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • H₂) + H₂ = (Co⁺ • 2H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	75. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=71.1 kJ/mol, Δ_rS(300 K)=103. J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	103.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=71.1 kJ/mol, Δ_rS(300 K)=103. J/mol*K; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2H₂) + H₂ = (Co⁺ • 3H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	44. ± 2.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=85.8 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	85.8	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=85.8 J/mol*K; M

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3H₂) + H₂ = (Co⁺ • 4H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	44. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=105. J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	101.	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=40. kJ/mol, Δ_rS(300 K)=105. J/mol*K; M

( Cobalt ion (1+) • 4) + = ( • 5)

By formula: (Co⁺ • 4H₂) + H₂ = (Co⁺ • 5H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	22. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=18. kJ/mol, Δ_rS(300 K)=91.6 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	94.1	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=18. kJ/mol, Δ_rS(300 K)=91.6 J/mol*K; M

( Cobalt ion (1+) • 5) + = ( • 6)

By formula: (Co⁺ • 5H₂) + H₂ = (Co⁺ • 6H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=17. kJ/mol, Δ_rS(300 K)=99.6 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	99.2	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=17. kJ/mol, Δ_rS(300 K)=99.6 J/mol*K; M

( Cobalt ion (1+) • 6) + = ( • 7)

By formula: (Co⁺ • 6H₂) + H₂ = (Co⁺ • 7H₂)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	6. ± 3.	kJ/mol	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=3. kJ/mol; Δ_rS(300 K)=75.3 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	75.3	J/mol*K	SIDT	Kemper, Bushnell, et al., 1993, 2	gas phase; Δ_rH(0 K)=3. kJ/mol; Δ_rS(300 K)=75.3 J/mol*K; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + H₃N = (Co⁺ • H₃N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	218. ± 15.	kJ/mol	CIDT	Walter and Armentrout, 1998	RCD
Δ_rH°	246.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • H₃N) + H₃N = (Co⁺ • 2H₃N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	248. ± 13.	kJ/mol	CIDT	Walter and Armentrout, 1998	RCD
Δ_rH°	256.	kJ/mol	CID	Marinelli and Squires, 1989	gas phase; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2H₃N) + H₃N = (Co⁺ • 3H₃N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	64.0 ± 5.9	kJ/mol	CIDT	Walter and Armentrout, 1998	RCD

( Cobalt ion (1+) • 3) + = ( • 4)

By formula: (Co⁺ • 3H₃N) + H₃N = (Co⁺ • 4H₃N)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	49.0 ± 5.9	kJ/mol	CIDT	Walter and Armentrout, 1998	RCD

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + He = (Co⁺ • He)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.9 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 12.6 kJ/mol, Δ_rS(100 K) = 61.5 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	71.5	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 12.6 kJ/mol, Δ_rS(100 K) = 61.5 J/mol*K; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • He) + He = (Co⁺ • 2He)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.4 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 14.3 kJ/mol, Δ_rS(100 K) = 79.9 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	82.0	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 14.3 kJ/mol, Δ_rS(100 K) = 79.9 J/mol*K; M

( Cobalt ion (1+) • 2) + = ( • 3)

By formula: (Co⁺ • 2He) + He = (Co⁺ • 3He)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	5.5 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 5.10 kJ/mol, Δ_rS(100 K) = 46.4 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	48.5	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 5.10 kJ/mol, Δ_rS(100 K) = 46.4 J/mol*K; M

Cobalt ion (1+) + = ( • )

By formula: Co⁺ + Ne = (Co⁺ • Ne)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.5 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 9.12 kJ/mol, Δ_rS(100 K) = 58.6 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	64.4	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH(0 K) = 9.12 kJ/mol, Δ_rS(100 K) = 58.6 J/mol*K; M

( Cobalt ion (1+) • ) + = ( • 2)

By formula: (Co⁺ • Ne) + Ne = (Co⁺ • 2Ne)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.2 ± 0.4	kJ/mol	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH90 K) = 8.16 kJ/mol, Δ_rS(100 K) = 52.3 J/mol*K; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	48.5	J/mol*K	SIDT	Kemper, Hsu, et al., 1991	gas phase; Δ_rH90 K) = 8.16 kJ/mol, Δ_rS(100 K) = 52.3 J/mol*K; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T., Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters, J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Kemper, Bushnell, et al., 1993, 2
Kemper, P.R.; Bushnell, J.; Von Helden, G.; Bowers, M.T., Co+(H2)n Clusters: Binding Energies and Molecular Parameters, J. Chem Phys., 1993, 97, 1, 52, https://doi.org/10.1021/j100103a012 . [all data]

Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B., Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy, Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T., Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar), J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Goebel, Haynes, et al., 1995
Goebel, S.; Haynes, C.L.; Khan, F.A.; Armentrout, P.B., Collision-Induced Dissociation Studies of Co(CO)x, x = 1-5: Sequential Bond Energies and the Heat of Formation of Co(CO)4, J. Am. Chem. Soc., 1995, 117, 26, 6994, https://doi.org/10.1021/ja00131a023 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B., Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies, J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026 . [all data]

Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B., Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane, J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016 . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]

Asher, Bellert, et al., 1994
Asher, R.L.; Bellert, D.; Buthelezi, T.; Brucat, P.J., The Bond Strength of Ni2+, Chem. Phys. Lett., 1994, 224, 5-6, 529, https://doi.org/10.1016/0009-2614(94)00574-5 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

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Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References

Symbols used in this document:

S°_{gas,1 bar}	Entropy of gas at standard conditions (1 bar)
T	Temperature
Δ_rG°	Free energy of reaction at standard conditions
Δ_rH°	Enthalpy of reaction at standard conditions
Δ_rS°	Entropy of reaction at standard conditions

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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