Cobalt ion (1+)

Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
S°gas,1 bar42.624cal/mol*KReviewChase, 1998Data last reviewed in June, 1984

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

(Cobalt ion (1+) • 2Methane) + Methane = (Cobalt ion (1+) • 3Methane)

By formula: (Co+ • 2CH4) + CH4 = (Co+ • 3CH4)

Quantity Value Units Method Reference Comment
ΔrH°11.kcal/molSIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°20.cal/mol*KN/AKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
9.8 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.7477.SIDTKemper, Bushnell, et al., 1993gas phase; Entropy change calculated or estimated; M

Cobalt ion (1+) + Hydrogen = (Cobalt ion (1+) • Hydrogen)

By formula: Co+ + H2 = (Co+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 1.kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(O K)=18.2 kcal/mol, ΔrS(300 K)=20.6 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°22.0cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(O K)=18.2 kcal/mol, ΔrS(300 K)=20.6 cal/mol*K; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
17.5 (+2.3,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M

Cobalt ion (1+) + Methane = (Cobalt ion (1+) • Methane)

By formula: Co+ + CH4 = (Co+ • CH4)

Quantity Value Units Method Reference Comment
ΔrS°19.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(530 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
21.5 (+1.6,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M
21.5 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
22.5 (+0.5,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(530 K); M

(Cobalt ion (1+) • Benzene) + Benzene = (Cobalt ion (1+) • 2Benzene)

By formula: (Co+ • C6H6) + C6H6 = (Co+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°39.9 ± 3.3kcal/molCIDTMeyer, Khan, et al., 1995RCD
Quantity Value Units Method Reference Comment
ΔrS°27.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(490 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
39.9 (+3.2,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M
27.0 (+1.0,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(490 K); M

Cobalt ion (1+) + Ethane = (Cobalt ion (1+) • Ethane)

By formula: Co+ + C2H6 = (Co+ • C2H6)

Quantity Value Units Method Reference Comment
ΔrS°22.3cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, ΔrS(500 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
23.9 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
28.0 (+1.6,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)CH4, ΔrS(500 K); M

(Cobalt ion (1+) • 2helium) + helium = (Cobalt ion (1+) • 3helium)

By formula: (Co+ • 2He) + He = (Co+ • 3He)

Quantity Value Units Method Reference Comment
ΔrH°1.3 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 1.22 kcal/mol, ΔrS(100 K) = 11.1 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°11.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 1.22 kcal/mol, ΔrS(100 K) = 11.1 cal/mol*K; M

(Cobalt ion (1+) • neon) + neon = (Cobalt ion (1+) • 2neon)

By formula: (Co+ • Ne) + Ne = (Co+ • 2Ne)

Quantity Value Units Method Reference Comment
ΔrH°2.0 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; ΔrH90 K) = 1.95 kcal/mol, ΔrS(100 K) = 12.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°11.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; ΔrH90 K) = 1.95 kcal/mol, ΔrS(100 K) = 12.5 cal/mol*K; M

(Cobalt ion (1+) • helium) + helium = (Cobalt ion (1+) • 2helium)

By formula: (Co+ • He) + He = (Co+ • 2He)

Quantity Value Units Method Reference Comment
ΔrH°3.7 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 3.41 kcal/mol, ΔrS(100 K) = 19.1 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°19.6cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 3.41 kcal/mol, ΔrS(100 K) = 19.1 cal/mol*K; M

Cobalt ion (1+) + Carbon monoxide = (Cobalt ion (1+) • Carbon monoxide)

By formula: Co+ + CO = (Co+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°41.6 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°39. ± 3.kcal/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
41.5 (+1.6,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
39.0 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + neon = (Cobalt ion (1+) • neon)

By formula: Co+ + Ne = (Co+ • Ne)

Quantity Value Units Method Reference Comment
ΔrH°2.5 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 2.18 kcal/mol, ΔrS(100 K) = 14.0 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°15.4cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 2.18 kcal/mol, ΔrS(100 K) = 14.0 cal/mol*K; M

Cobalt ion (1+) + helium = (Cobalt ion (1+) • helium)

By formula: Co+ + He = (Co+ • He)

Quantity Value Units Method Reference Comment
ΔrH°3.6 ± 0.1kcal/molSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 3.02 kcal/mol, ΔrS(100 K) = 14.7 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°17.1cal/mol*KSIDTKemper, Hsu, et al., 1991gas phase; ΔrH(0 K) = 3.02 kcal/mol, ΔrS(100 K) = 14.7 cal/mol*K; M

(Cobalt ion (1+) • Methane) + Hydrogen = (Cobalt ion (1+) • Hydrogen • Methane)

By formula: (Co+ • CH4) + H2 = (Co+ • H2 • CH4)

Quantity Value Units Method Reference Comment
ΔrS°22.9cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
17.4 (+0.8,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) • Hydrogen) + Methane = (Cobalt ion (1+) • Methane • Hydrogen)

By formula: (Co+ • H2) + CH4 = (Co+ • CH4 • H2)

Quantity Value Units Method Reference Comment
ΔrS°21.8cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.6 (+1.2,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+)2H2, ΔrS(440 K); Kemper, Bushnell, et al., 1993, 2; M

(Cobalt ion (1+) • Hydrogen) + Hydrogen = (Cobalt ion (1+) • 2Hydrogen)

By formula: (Co+ • H2) + H2 = (Co+ • 2H2)

Quantity Value Units Method Reference Comment
ΔrH°18.0 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=17.0 kcal/mol, ΔrS(300 K)=24.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°24.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=17.0 kcal/mol, ΔrS(300 K)=24.5 cal/mol*K; M

(Cobalt ion (1+) • 2Hydrogen) + Hydrogen = (Cobalt ion (1+) • 3Hydrogen)

By formula: (Co+ • 2H2) + H2 = (Co+ • 3H2)

Quantity Value Units Method Reference Comment
ΔrH°10.6 ± 0.4kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=20.5 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°20.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=20.5 cal/mol*K; M

(Cobalt ion (1+) • 3Hydrogen) + Hydrogen = (Cobalt ion (1+) • 4Hydrogen)

By formula: (Co+ • 3H2) + H2 = (Co+ • 4H2)

Quantity Value Units Method Reference Comment
ΔrH°10.4 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=25.2 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°24.2cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=9.6 kcal/mol, ΔrS(300 K)=25.2 cal/mol*K; M

(Cobalt ion (1+) • 4Hydrogen) + Hydrogen = (Cobalt ion (1+) • 5Hydrogen)

By formula: (Co+ • 4H2) + H2 = (Co+ • 5H2)

Quantity Value Units Method Reference Comment
ΔrH°5.2 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=4.3 kcal/mol, ΔrS(300 K)=21.9 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°22.5cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=4.3 kcal/mol, ΔrS(300 K)=21.9 cal/mol*K; M

(Cobalt ion (1+) • 5Hydrogen) + Hydrogen = (Cobalt ion (1+) • 6Hydrogen)

By formula: (Co+ • 5H2) + H2 = (Co+ • 6H2)

Quantity Value Units Method Reference Comment
ΔrH°4.7 ± 0.6kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=4.0 kcal/mol, ΔrS(300 K)=23.8 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°23.7cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=4.0 kcal/mol, ΔrS(300 K)=23.8 cal/mol*K; M

(Cobalt ion (1+) • 6Hydrogen) + Hydrogen = (Cobalt ion (1+) • 7Hydrogen)

By formula: (Co+ • 6H2) + H2 = (Co+ • 7H2)

Quantity Value Units Method Reference Comment
ΔrH°1.5 ± 0.7kcal/molSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=0.8 kcal/mol; ΔrS(300 K)=18.0 cal/mol*K; M
Quantity Value Units Method Reference Comment
ΔrS°18.0cal/mol*KSIDTKemper, Bushnell, et al., 1993, 2gas phase; ΔrH(0 K)=0.8 kcal/mol; ΔrS(300 K)=18.0 cal/mol*K; M

(Cobalt ion (1+) • Methane) + Methane = (Cobalt ion (1+) • 2Methane)

By formula: (Co+ • CH4) + CH4 = (Co+ • 2CH4)

Quantity Value Units Method Reference Comment
ΔrS°26.1cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(500 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.9 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
24.8 (+1.0,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(500 K); M

Cobalt ion (1+) + Ethylene = (Cobalt ion (1+) • Ethylene)

By formula: Co+ + C2H4 = (Co+ • C2H4)

Quantity Value Units Method Reference Comment
ΔrH°44.5 ± 2.2kcal/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
42.8 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
6.5 (+3.0,-0.) CIDHaynes and Armentrout, 1994gas phase; ΔrH>=, guided ion beam CID; M

(Cobalt ion (1+) • Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 2Carbon monoxide)

By formula: (Co+ • CO) + CO = (Co+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°36.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
36.4 (+2.1,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M
32.9 (+4.8,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • Methane) + Ethane = (Cobalt ion (1+) • Ethane • Methane)

By formula: (Co+ • CH4) + C2H6 = (Co+ • C2H6 • CH4)

Quantity Value Units Method Reference Comment
ΔrS°25.9cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, ΔrS(480 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
28.4 (+1.3,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; switching reaction(Co+).2CH4, ΔrS(480 K); M

Cobalt ion (1+) + Water = (Cobalt ion (1+) • Water)

By formula: Co+ + H2O = (Co+ • H2O)

Quantity Value Units Method Reference Comment
ΔrH°37. ± 3.kcal/molCIDMagnera, David, et al., 1989gas phase; M
ΔrH°40.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
38.5 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • Water) + Hydrogen = (Cobalt ion (1+) • Hydrogen • Water)

By formula: (Co+ • H2O) + H2 = (Co+ • H2 • H2O)

Quantity Value Units Method Reference Comment
ΔrS°24.7cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(530 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
19.8 (+0.6,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(530 K); M

(Cobalt ion (1+) • Water) + Methane = (Cobalt ion (1+) • Methane • Water)

By formula: (Co+ • H2O) + CH4 = (Co+ • CH4 • H2O)

Quantity Value Units Method Reference Comment
ΔrS°27.0cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(525 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
25.9 (+0.7,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(525 K); M

(Cobalt ion (1+) • Ethane) + Methane = (Cobalt ion (1+) • Methane • Ethane)

By formula: (Co+ • C2H6) + CH4 = (Co+ • CH4 • C2H6)

Quantity Value Units Method Reference Comment
ΔrS°26.4cal/mol*KSIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(490 K); M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
24.4 (+1.1,-0.) SIDTKemper, Bushnell, et al., 1993gas phase; ΔrS(490 K); M

Cobalt ion (1+) + Propene = (Cobalt ion (1+) • Propene)

By formula: Co+ + C3H6 = (Co+ • C3H6)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
43.0 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M
43.1 (+1.6,-0.) CIDHaynes and Armentrout, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • Water) + Water = (Cobalt ion (1+) • 2Water)

By formula: (Co+ • H2O) + H2O = (Co+ • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°41.9kcal/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
38.7 (+1.7,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Acetylene = (Cobalt ion (1+) • Acetylene)

By formula: Co+ + C2H2 = (Co+ • C2H2)

Quantity Value Units Method Reference Comment
ΔrH°43.0 ± 1.9kcal/molIRMPDSurya, Ranatunga, et al., 1997RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
6.5 (+3.1,-0.) CIDArmentrout and Kickel, 1994gas phase; ΔrH >=, guided ion beam CID; M

(Cobalt ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 3Carbon monoxide)

By formula: (Co+ • 2CO) + CO = (Co+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°19.6 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
19.6 (+2.8,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 3Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 4Carbon monoxide)

By formula: (Co+ • 3CO) + CO = (Co+ • 4CO)

Quantity Value Units Method Reference Comment
ΔrH°17.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.4,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 4Carbon monoxide) + Carbon monoxide = (Cobalt ion (1+) • 5Carbon monoxide)

By formula: (Co+ • 4CO) + CO = (Co+ • 5CO)

Quantity Value Units Method Reference Comment
ΔrH°17.9 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
18.0 (+1.2,-0.) CIDGoebel, Haynes, et al., 1995gas phase; guided ion beam CID; M

Cobalt ion (1+) + Benzene = (Cobalt ion (1+) • Benzene)

By formula: Co+ + C6H6 = (Co+ • C6H6)

Quantity Value Units Method Reference Comment
ΔrH°61.2 ± 2.6kcal/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
61.1 (+2.5,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Cobalt ion (1+) • Ammonia) + Ammonia = (Cobalt ion (1+) • 2Ammonia)

By formula: (Co+ • H3N) + H3N = (Co+ • 2H3N)

Quantity Value Units Method Reference Comment
ΔrH°59.3 ± 3.1kcal/molCIDTWalter and Armentrout, 1998RCD
ΔrH°61.1kcal/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Ammonia = (Cobalt ion (1+) • Ammonia)

By formula: Co+ + H3N = (Co+ • H3N)

Quantity Value Units Method Reference Comment
ΔrH°52.1 ± 3.6kcal/molCIDTWalter and Armentrout, 1998RCD
ΔrH°58.8kcal/molCIDMarinelli and Squires, 1989gas phase; M

Cobalt ion (1+) + Methyl radical = (Cobalt ion (1+) • Methyl radical)

By formula: Co+ + CH3 = (Co+ • CH3)

Quantity Value Units Method Reference Comment
ΔrH°48.8 ± 3.0kcal/molCIDTFisher, Sunderlin, et al., 1989RCD
ΔrH°49.1 ± 3.5kcal/molCIDTGeorgiadis, Fisher, et al., 1989RCD

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) • Carbon monosulfide)

By formula: Co+ + CS = (Co+ • CS)

Quantity Value Units Method Reference Comment
ΔrH°61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001RCD
ΔrH°57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cobalt ion (1+) • 2Water) + Water = (Cobalt ion (1+) • 3Water)

By formula: (Co+ • 2H2O) + H2O = (Co+ • 3H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
15.5 (+1.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 3Water) + Water = (Cobalt ion (1+) • 4Water)

By formula: (Co+ • 3H2O) + H2O = (Co+ • 4H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
13.9 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Propyne = (Cobalt ion (1+) • Propyne)

By formula: Co+ + C3H4 = (Co+ • C3H4)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
18.9 (+2.1,-0.) CIDHaynes and Armentrout, 1994gas phase; ΔrH>=, guided ion beam CID; M

(Cobalt ion (1+) • 3Methane) + Methane = (Cobalt ion (1+) • 4Methane)

By formula: (Co+ • 3CH4) + CH4 = (Co+ • 4CH4)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.2 (+1.4,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 10cobalt) + cobalt = (Cobalt ion (1+) • 11cobalt)

By formula: (Co+ • 10Co) + Co = (Co+ • 11Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
78.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 11cobalt) + cobalt = (Cobalt ion (1+) • 12cobalt)

By formula: (Co+ • 11Co) + Co = (Co+ • 12Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
83.9 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 12cobalt) + cobalt = (Cobalt ion (1+) • 13cobalt)

By formula: (Co+ • 12Co) + Co = (Co+ • 13Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
72.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 13cobalt) + cobalt = (Cobalt ion (1+) • 14cobalt)

By formula: (Co+ • 13Co) + Co = (Co+ • 14Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
90.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 14cobalt) + cobalt = (Cobalt ion (1+) • 15cobalt)

By formula: (Co+ • 14Co) + Co = (Co+ • 15Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 15cobalt) + cobalt = (Cobalt ion (1+) • 16cobalt)

By formula: (Co+ • 15Co) + Co = (Co+ • 16Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
82.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 16cobalt) + cobalt = (Cobalt ion (1+) • 17cobalt)

By formula: (Co+ • 16Co) + Co = (Co+ • 17Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
88.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 9cobalt) + cobalt = (Cobalt ion (1+) • 10cobalt)

By formula: (Co+ • 9Co) + Co = (Co+ • 10Co)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
75.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T., Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters, J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Kemper, Bushnell, et al., 1993, 2
Kemper, P.R.; Bushnell, J.; Von Helden, G.; Bowers, M.T., Co+(H2)n Clusters: Binding Energies and Molecular Parameters, J. Chem Phys., 1993, 97, 1, 52, https://doi.org/10.1021/j100103a012 . [all data]

Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B., Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy, Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Kemper, Hsu, et al., 1991
Kemper, P.R.; Hsu, M.T.; Bowers, M.T., Transition - Metal Ion - Rare Gas Clusters: Bond Strengths and Molecular Parameters for Co+(He/Ne)n, Ni+(He/Ne)n, and Cr+(He/Ne/Ar), J. Phys. Chem., 1991, 95, 26, 10600, https://doi.org/10.1021/j100179a022 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Goebel, Haynes, et al., 1995
Goebel, S.; Haynes, C.L.; Khan, F.A.; Armentrout, P.B., Collision-Induced Dissociation Studies of Co(CO)x, x = 1-5: Sequential Bond Energies and the Heat of Formation of Co(CO)4, J. Am. Chem. Soc., 1995, 117, 26, 6994, https://doi.org/10.1021/ja00131a023 . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Fisher, Sunderlin, et al., 1989
Fisher, E.R.; Sunderlin, L.S.; Armentrout, P.B., Guided Ion Beam Studies of the Reactions of CO+ and Ni+ with CH3X (X=Cl, Br, I). Implications for the Metal-Methyl Ion Bond Energies, J. Phys. Chem., 1989, 93, 21, 7375, https://doi.org/10.1021/j100358a026 . [all data]

Georgiadis, Fisher, et al., 1989
Georgiadis, R.; Fisher, E.R.; Armentrout, P.B., Neutral and Ionic Metal-Hydrogen and Metal-Carbon Bond Energies: Reactions of Co+, Ni+, and Cu+ with Ethane, Propane, Methylpropane, and Dimethylpropane, J. Am. Chem. Soc., 1989, 111, 12, 4251, https://doi.org/10.1021/ja00194a016 . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References