Cobalt ion (1+)
- Formula: Co+
- Molecular weight: 58.932646
- IUPAC Standard InChIKey: BFVNPAKTAJENJQ-UHFFFAOYSA-N
- CAS Registry Number: 16610-75-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Cobalt cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50
- Ion clustering data
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 51 to 73
By formula: (Co+ • 2Co) + Co = (Co+ • 3Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
205. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 3Co) + Co = (Co+ • 4Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
274. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 4Co) + Co = (Co+ • 5Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
319. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 5Co) + Co = (Co+ • 6Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
283. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 6Co) + Co = (Co+ • 7Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
303. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 7Co) + Co = (Co+ • 8Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
283. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 8Co) + Co = (Co+ • 9Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
285. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • Co) + Co = (Co+ • 2Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
201. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + D2 = (Co+ • D2)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
71.5 (+6.7,-0.) | CID | Haynes and Armentrout, 1996 | gas phase; guided ion beam CID; M |
By formula: Co+ + C3H8 = (Co+ • C3H8)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
129. (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: Co+ + Co = (Co+ • Co)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
267. | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: (Co+ • 2C2H6) + C2H6 = (Co+ • 3C2H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50. | kJ/mol | SIDT | Kemper, Bushnell, et al., 1993 | gas phase; ΔrH<; M |
By formula: (Co+ • 2H3N) + H3N = (Co+ • 3H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 64.0 ± 5.9 | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Co+ • 3H3N) + H3N = (Co+ • 4H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 49.0 ± 5.9 | kJ/mol | CIDT | Walter and Armentrout, 1998 | RCD |
By formula: (Co+ • C2H4) + C2H4 = (Co+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 152. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Co+ • C4H5N) + C4H5N = (Co+ • 2C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 194. | kJ/mol | RAK | Gapeev and Yang, 2000 | RCD |
By formula: Co+ + CH2 = (Co+ • CH2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 318. ± 5.0 | kJ/mol | CIDT | Haynes and Armentrout, 1994 | RCD |
By formula: Co+ + C5H5N = (Co+ • C5H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 247. ± 13. | kJ/mol | CIDT | Rodgers, Stanley, et al., 2000 | RCD |
By formula: Co+ + C4H4N2 = (Co+ • C4H4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 245. ± 13. | kJ/mol | CIDT | Amunugama and Rodgers, 2001 | RCD |
By formula: Co+ + C5H5N5 = (Co+ • C5H5N5)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 293. ± 10. | kJ/mol | CIDT | Rodgers and Armentrout, 2002 | RCD |
By formula: Co+ + CH4O = (Co+ • CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 148. ± 7.9 | kJ/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Co+ + Ar = (Co+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 49.4 | kJ/mol | PDis | Asher, Bellert, et al., 1994 | RCD |
By formula: Co+ + C4H5N = (Co+ • C4H5N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >280. | kJ/mol | RAK | Gapeev and Yang, 2000 | RCD |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L.,
Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]
Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B.,
Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy,
Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7
. [all data]
Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T.,
Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters,
J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016
. [all data]
Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B.,
Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD,
J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c
. [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B.,
Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes,
J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z
. [all data]
Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N.,
Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results,
J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d
. [all data]
Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B.,
Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers,
Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022
. [all data]
Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R.,
Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923
. [all data]
Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T.,
Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory,
J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i
. [all data]
Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B.,
Influence of d orbital occupation on the binding of metal ions to adenine,
J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Asher, Bellert, et al., 1994
Asher, R.L.; Bellert, D.; Buthelezi, T.; Brucat, P.J.,
The Bond Strength of Ni2+,
Chem. Phys. Lett., 1994, 224, 5-6, 529, https://doi.org/10.1016/0009-2614(94)00574-5
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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